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AGENCY:
Research and Special Programs Administration (RSPA), DOT.
ACTION:
Notice of proposed rulemaking (NPRM).
SUMMARY:
RSPA is proposing to amend the Hazardous Materials Regulations (HMR) to maintain alignment with international standards by incorporating various amendments, including changes to proper shipping names, hazard classes, packing groups, special provisions, packaging authorizations, air transport quantity limitations and vessel stowage requirements. Because of recent changes to the International Maritime Dangerous Goods Code (IMDG Code), the International Civil Aviation Organization's Technical Instructions for the Safe Transport of Dangerous Goods by Air (ICAO Technical Instructions), and the United Nations Recommendations on the Transport of Dangerous Goods (UN Recommendations), these revisions are necessary to facilitate the transport of hazardous materials in international commerce.
DATES:
Comments must be received by August 23, 2004.
ADDRESSES:
Address your comments to the Dockets Management System, U.S. Department of Transportation, 400 Seventh St., SW., Room PL 402, Washington, DC 20590.
Comments.
You may submit comments identified by the docket number (RSPA-04-17036) by any of the following methods:
Federal eRulemaking Portal:http://www.regulations.gov.
Follow the online instructions for submitting comments.
Web site:http://dms.dot.gov.
Follow the instructions for submitting comments on the DOT electronic docket site.
Fax: 1-202-493-2251.
Mail: Docket Management System; U.S. Department of Transportation, 400 Seventh Street, SW., Nassif Building, Room PL-402, Washington, DC 20590-001.
Hand Delivery: To the Docket Management System; Room PL-402 on the plaza level of the Nassif Building, 400 Seventh Street, SW., Washington, DC between 9 a.m. and 5 p.m., Monday through Friday, except Federal holidays.
Instructions:
All submissions must include the agency name and docket number or Regulatory Identification Number (RIN) for this notice. For detailed instructions on submitting comments and additional information on the rulemaking process,
see
the Public Participation heading of the
SUPPLEMENTARY INFORMATION
section of this document. Note that all comments received will be posted without change to
http://dms.dot.gov
including any personal information provided. Please
see
the Privacy Act heading under
SUPPLEMENTARY INFORMATION.
Docket:
For access to the docket to read background documents or comments received, go to
http://dms.dot.gov
at any time or to the Docket Management System (
seeADDRESSES
).
FOR FURTHER INFORMATION CONTACT:
Charles Betts, Office of Hazardous Materials Standards, telephone (202) 366-8553, or Shane Kelley, International Standards, telephone (202) 366-0656, Research and Special Programs Administration, U.S. Department of Transportation, 400 Seventh Street, SW., Washington, DC 20590-0001.
SUPPLEMENTARY INFORMATION:
Contents
I. Background
II. Overview of Proposed Changes in this NPRM
III. Overview of Amendments Not Being Considered for Adoption in this NPRM
D. Regulatory Flexibility Act, Executive Order 13272, and DOT Regulatory Policies and Procedures
E. Paperwork Reduction Act
F. Regulatory Identifier Number (RIN)
G. Unfunded Mandates Reform Act
H. Environmental Assessment
I. Privacy Act
I. Background
On December 21, 1990, RSPA (we) published a final rule (Docket HM-181; 55 FR 52402) based on the UN Recommendations, which comprehensively revised the Hazardous Materials Regulations (HMR), 49 CFR parts 171 to 180, for harmonization with international standards. Since publication of the 1990 final rule, we have issued five additional international harmonization final rules (Dockets HM-215A, 59 FR 67390; HM-215B, 62 FR 24690; HM-215C, 64 FR 10742; HM-215D, 66 FR 33316; and HM-215E, 68 FR 44992). The rules provided additional harmonization with international transportation requirements by more fully aligning the HMR with the corresponding biennial updates of the UN Recommendations, the IMDG Code and the ICAO Technical Instructions.
The UN Recommendations are not regulations, but rather are recommendations issued by the UN Committee of Experts on the Transport of Dangerous Goods (TDG) and on the Globally Harmonized System of Classification and Labeling (GHS). These recommendations are amended and updated biennially by the UN Committee of Experts. They serve as the basis for National, regional, and international modal regulations; specifically, the IMDG Code issued by the International Maritime Organization (IMO), and the ICAO Technical Instructions issued by the ICAO. In 49 CFR 171.12, the HMR authorize domestic transportation of hazardous materials shipments prepared in accordance with the IMDG Code if all or part of the transportation is by vessel, subject to certain conditions and limitations. In § 171.11, subject to certain conditions and limitations, the HMR authorize the offering, acceptance and transport of hazardous materials by aircraft, and by motor vehicle either before or after being transported by aircraft, provided the shipment is in accordance with the ICAO Technical Instructions.
The continually increasing amount of hazardous materials transported in international commerce warrants the harmonization of domestic and international requirements to the greatest extent possible. Harmonization serves to facilitate international transportation and at the same time ensures the safety of people, property and the environment. While the intent of the harmonization rulemakings is to align the HMR with international standards, we review and consider each amendment on its own merit. Each amendment is considered on the basis of the overall impact on transportation safety and the economic implications associated with its adoption into the HMR. Our goal is to harmonize without sacrificing the current HMR level of safety and without imposing undue burdens on the regulated public. In our efforts to continue to align the HMR with international requirements, this notice of proposed rulemaking (NPRM) proposes changes to the HMR based on the Thirteenth Revised Edition of the
( printed page 34725)
UN Recommendations, Amendment 32 to the IMDG Code, and the 2005-2006 ICAO Technical Instructions, which become effective January 1, 2005. Petitions for rulemaking concerning harmonization with international standards and the facilitation of international transportation are also addressed in this NPRM and serve as the basis of certain proposed amendments. Other proposed amendments are based on feedback from the regulated industry, other DOT modal administrations and our initiative. Also included are various proposed editorial clarifications. Unless otherwise stated, the proposed revisions are for harmonization with international standards.
II. Overview of Proposed Changes in This NPRM
Proposed amendments to the HMR in this NPRM include, but are not limited to the following:
Amendments to the Hazardous Materials Table (HMT) which would add, revise or remove certain proper shipping names, hazard classes, packing groups, special provisions, packaging authorizations, bulk packaging requirements, passenger and cargo aircraft maximum quantity limitations and vessel stowage provisions.
Amendments to the List of Marine Pollutants.
Revisions and additions of special provisions.
Removal of the air eligibility marking requirement.
Addition of a “KEEP AWAY FROM HEAT” marking requirement for packages offered for transportation by air.
Amendment to require that aerosol cans that are carried aboard an aircraft in accordance with § 175.10(a)(4) have their release devices protected by a cap or other suitable means.
A grandfather provision to allow the shipment of materials classified as corrosive to steel or aluminum under ASTM G 31-72.
A provision to require that the word “overpack” be marked on overpacks to indicate that this marking implies that inside packages comply with prescribed specifications.
An amendment to the criteria for classification of materials that are corrosive to metals.
Revision of the limited quantity provisions for Class 6.1, PG II materials and other hazard classes of materials to take into account materials with a subsidiary hazard of 6.1, PG II.
Amendments to the packaging requirements for materials classified as Division 6.1, Packing Group I, Hazard Zone A or Hazard Zone B.
Revision of the organic peroxide packaging requirements in order to have one consolidated packaging section for organic peroxides. The revised section will include three separate tables for organic peroxides authorized for transport in non-bulk packagings, IBCs, and bulk packagings other than IBCs, respectively. Additionally, the packaging tables will be updated through the amendments to the organic peroxide requirements that will add, revise, or delete certain entries in the organic peroxide tables.
III. Overview of Amendments Not Being Considered for Adoption in This NPRM
This NPRM proposes changes to the HMR based on amendments to the Thirteenth Revised Edition of the UN Recommendations, Amendment 32 to the IMDG Code, and the 2005-2006 ICAO Technical Instructions, which become effective January 1, 2005. However, we are not proposing to adopt all of the amendments to those documents into the HMR. In many cases, amendments to the international regulation have not been adopted because of the framework or structure of the HMR. In several cases, we are handling certain amendments in separate rulemakings. For example, all amendments related to infectious substances are being handled under Docket HM-226A. In some instances, such as the amendment to ICAO TI to allow certain oxygen generators aboard passenger carrying aircraft, we do not believe the amendment to be in the interest of public safety.
If we have inadvertently omitted an amendment in this NPRM, we will attempt to include the omission in the final rule. However, our options for making changes in a final rule are limited by requirements of the Administrative Procedures Act. In some instances, we can adopt a provision inadvertently omitted from the NPRM if it is clearly within the scope of changes proposed in the notice, does not require substantive changes from the international standard on which it is based, and imposes minimal or no cost impacts on persons subject to the requirement. Otherwise, in order to provide opportunity for notice and comment the change must be proposed in an NPRM.
One of the goals of this rulemaking is to continue to maintain consistency between the HMR and the international requirements. We are not striving to “match-up” the HMR with the international regulations but rather striving to remove potential barriers to international transportation.
Below is a listing of those significant amendments to the international regulations that we are not proposing to adopt into the HMR with a brief explanation why:
Requirements for infectious substances and genetically modified micro-organisms;
(Amendments to the HMR related to infectious substances will be addressed in a future rulemaking under Docket HM-226A. Several other Federal agencies regulate genetically modified micro-organisms; thus we do not plan to adopt provisions for their transport in the HMR.)
Compressed gas cylinders;
(Amendments to the HMR related to compressed gas cylinders will be addressed in a future rulemaking under Docket HM-220E.)
Environmentally hazardous substances;
(Delay in action pending further amendments to the international regulations.)
Hazardous materials security;
(Amendments to the HMR related to the UN Model Regulation's hazardous materials security requirements were promulgated in a rulemaking under the HM-232 Docket series.)
Requirements for radioactive materials;
(Amendments to the HMR related to Class 7 (radioactive) materials are being addressed in a rulemaking under the HM-230 Docket series.)
Non-specification bulk packagings;
(We are not adopting the new requirements in the UN Recommendations for non-specification bulk packagings including the additional inspection, testing and marking requirements. We are unsure about the cost impacts of imposing these additional amendments and, therefore, are not proposing to adopt any additional amendments at this time.)
The reference to EN 10028-3, Part 3 for defining steel grain size relevant to the definition of fine grain steel;
(We do not believe there is a need to adopt the European standard EN 10028-3, Part 3 because this standard is equivalent to ASTM E 112-96 (IBR,
see
§ 171.7 of this subchapter). In addition, the ASTM standard is currently referenced in the HMR and is more commonly used and recognized in the U.S.)
Bulk authorization for UN0331, UN0332 and UN3375;
(For several years, we have authorized, under exemption, the transport of certain blasting agents in bulk packagings. We are currently
( printed page 34726)
reviewing those exemptions to determine if they should be included in the HMR. The amendments in the UN Recommendations related to the bulk authorizations for UN0331, UN0332 and UN3375 will be included in that review.)
The removal of wooden barrel requirements;
(The removal of the wooden barrel requirements (2C1 and 2C2) may be considered in a future rulemaking.)
The 24-hour gasket relaxation requirement;
(A requirement that removable head packagings for liquids not be drop tested until at least 24 hours after filling and closing to allow for any possible gasket relaxation was adopted in the thirteenth revised edition of the UN Model Regulations. We have conducted testing in coordination with drum manufacturers and have determined that this requirement is not substantiated by the results of the tests conducted. Therefore, we are not adopting into the HMR amendments relative to the 24-hour gasket relaxation requirement. We also opposed this requirement when it was considered by the UN TDG Sub-Committee.)
Authorization to transport protective breathing equipment (PBE's) with an oxygen generator as cargo onboard a passenger-carrying aircraft.
(We do not believe that oxygen generators should be transported aboard passenger carrying aircraft. Therefore, we are not adopting the ICAO amendment that would allow oxygen generators in protective breathing equipment to be transported in passenger carrying aircraft.)
IV. Section-by-Section Review
Part 171
Section 171.7
Paragraph (a)(3) (incorporation by reference materials) would be updated to include the most recent edition of the ICAO Technical Instructions, the IMDG Code and the UN Recommendations. The updated editions of these standards become effective January 1, 2005. Additionally, the International Maritime Organization (IMO) recommends authorizing a one-year transition period, with a delayed compliance date of January 1, 2006, for the use of the updated edition (Amendment 32) of the IMDG Code.
The standards would be updated as follows:
The ICAO Technical Instructions, 2005-2006 Edition.
The IMDG Code, Amendment 32.
The UN Recommendations, Thirteenth Edition.
The UN Manual of Tests and Criteria, 4th Revised Edition.
Paragraph (b) (list of informational materials not requiring incorporation by reference) would be revised by adding an additional reference for a new method for determining the size of an emergency-relief device for portable tanks transporting organic peroxides. This revision is based on a petition for rulemaking numbered P-1428. The petition was submitted by Mr. Lynne Harris for the Organic Peroxides Producers Safety Division of the Society of the Plastics Industry, Inc.
The reference would be added as follows:
The Society of the Plastics Industry, Inc., Organic Peroxide Producers Safety Division,
1801 K Street, NW., Suite 600K, Washington, DC 20006-1301. Example of a Test Method for Venting Sizing: OPPSD/SPI Methodology.
Section 171.8
The definition for “salvage packaging” would be revised to include the term “non-conforming.” The term “non-conforming” was added to the definition by the UN Committee of Experts in December 2000. In addition to situations involving damaged, defective or leaking packages of dangerous goods, occasionally an undamaged primary container is found to be tested to a performance level which is less than that required for the specific substance it contains (
e.g., a drum tested to PG II standards containing a PG I substance). In other instances, the primary container is found to be a non-performance tested packaging containing a regulated substance. In these situations, it may not be safe or practical to transfer the material to the correct packaging to continue on to the consignee. Therefore, the use of salvage packaging to contain “non-conforming” packages will minimize the risk to those handling the package during its transport back to the shipper or to an appropriate disposal location.
Section 171.11
Paragraph (d)(15) would be revised to clarify that the limitations therein also apply to oxygen generators contained in personal breathing equipment. In addition, paragraph (d)(17) would be revised to indicate that an organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in § 173.225 of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d) of this subchapter.
Section 171.12
In § 171.12, paragraph (b)(20) would be revised to indicate that an organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in § 173.225 of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d) of this subchapter.
Section 171.12a
Paragraph (a) would be revised to clarify the requirements for the return to Canada of bulk packagings that correspond to DOT or UN Specification. Paragraph (b)(9)(ii) would be revised to indicate that the shipping certification must be completed for shipments from Canada that enter the U.S. Paragraph (b)(18) would be revised to indicate that an organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in § 173.225 of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d) of this subchapter.
Section 171.14
Paragraphs (d) and (d)(1) would be revised to authorize a delayed implementation date for the proposed amendments in this NPRM. We are proposing an effective date of October 1, 2004, and a voluntary compliance date of January 1, 2005, to correspond with the effective implementation dates of the 2005-2006 ICAO Technical Instructions and Amendment 32 of the IMDG Code. This authorization would allow shippers to prepare their international shipments in accordance with international standards that will become effective on January 1, 2005. We are also, proposing to authorize a delayed compliance date of January 1, 2006, which is comparable to the transitional provisions provided in the final rule published under Docket HM-215E. The delayed mandatory compliance date would offer sufficient time to implement the new requirements.
Paragraph (d)(2) would be revised to authorize certain intermixing of old and new requirements.
Part 172
Section 172.101
In the regulatory text preceding the Hazardous Materials Table, we are proposing the following changes:
Paragraph (c)(11) and the corresponding note to paragraph (c)(11) would be amended to revise a section reference. The reference to § 173.225(c)
( printed page 34727)
in the first sentence would be revised to read § 173.225(b) and the reference to § 173.225(c)(2) in the note to paragraph (c)(11) would be revised to read § 173.225(b)(2).
Paragraph (d)(4) would be revised by adding a statement indicating that when the abbreviation “Comb liq.” is found in the “Hazard class of division” column of the Hazardous Materials Table (column 3), the material falls into the “Combustible liquid” hazard class.
Paragraph (i)(3) of this section would be revised to specify that Column 7 of the Hazardous Materials Table contains additional bulk packaging authorizations and limitations for the use of UN portable tanks.
Section 172.101 The Hazardous Materials Table (HMT). We are proposing to make various amendments to the HMT. Readers should review all changes for a complete understanding of the proposed Table amendments. The HMT is being reprinted in its entirety due to the numerous changes. Proposed amendments to the HMT for the purpose of harmonizing with international standards, unless otherwise stated, include, but are not limited to the following:
We propose to revise several entries by adding the qualifying word “liquid.” This action is consistent with the revisions to proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. Affected entries would be as follows:
UN1392 Alkaline earth metal amalgam
UN1420 Potassium metal alloys
UN1422 Potassium sodium alloys
UN1701 Xylyl bromide
UN1742 Boron trifluoride acetic acid complex
UN1743 Boron trifluoride propionic acid complex
UN2235 Chlorobenzyl chlorides
UN2236 3-Chloro-4-methylphenyl isocyanate
UN2306 Nitrobenzotrifluorides
UN2445 Lithium alkyls
UN2552 Hexafluoroacetone hydrate
UN2937 alpha-Methylbenzyl alcohol
UN3276 Nitriles, toxic, n.o.s.
UN3278 Organophosphorus compound, toxic, n.o.s.
UN3280 Organoarsenic compound, n.o.s.
UN3282 Organometallic compound, toxic, n.o.s.
UN3281 Metal carbonyls, n.o.s.
We propose to revise several entries by adding the qualifying word “solid.” This action is consistent with the revisions to proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. Affected entries would be as follows:
UN1445 Barium chlorate
UN1447 Barium perchlorate
UN1459 Chlorate and magnesium chloride mixture
UN1470 Lead perchlorate
UN1578 Chloronitrobenzenes
UN1579 4-Chloro-o-toluidine hydrochloride
UN1650 beta-Naphthylamine
UN1680 Potassium cyanide
UN1689 Sodium cyanide
UN1690 Sodium fluoride
UN1697 Chloroacetophenone
UN1709 2,4-Toluylenediamine
UN1812 Potassium fluoride
UN1843 Ammonium dinitro-o-cresolate
UN2074 Acrylamide
UN2239 Chlorotoluidines
UN2261 Xylenols
UN2446 Nitrocresols
UN2662 Hydroquinone
UN3283 Selenium compound, n.o.s.
We propose to revise several entries by removing the qualifying word “solid.” This action would provide consistency with the Thirteenth Revised Edition of the UN Recommendations and enable us to remove all corresponding solution entries. The affected entries would be as follows:
UN1489 Potassium perchlorate, solid
UN1598 Dinitro-o-cresol,
solid
UN1638 Mercury iodide,
solid
UN1740 Hydrogendifluorides, n.o.s.
solid
UN2439 Sodium hydrogendifluoride,
solid
We propose to delete several entries. This action would remove from the HMR the solution form of entries that are not identified as solutions in the Thirteenth Revised Edition of the UN Recommendations. The deleted entries would be as follows:
UN1489 Potassium perchlorate, solution
UN1598 Dinitro-o-cresol,
solution
UN1638 Mercury iodide,
solution
UN1740 Hydrogendifluorides, n.o.s.
solutions
UN2439 Sodium hydrogendifluoride
solution
We propose to revise the proper shipping name “Butadienes, stabilized,” UN1010 to read “Butadienes, stabilizedor
Butadienes and hydrocarbon mixture, stabilized,
containing more than 40% butadienes.
”
We propose to revise the proper shipping name “Potassium hydrogendifluoride,solid,
” UN1811 to read “Potassium hydrogendifluoride, solid.”
We propose to revise the proper shipping name “Refrigerating machines,containing non-flammable, non-toxic, liquefied gas or ammonia solution (UN2672),” UN2857 to read “Refrigerating machines
containing non-flammable, non-toxic gases or ammonia solutions (UN2672).
”
Four references to IB52 and four references to T23 would be removed from column 7 of the HMT. This change is necessary because IB52 and T23 would be relocated to § 173.225. The affected entries would be:
UN3109 Organic peroxide type F, liquid
UN3110 Organic peroxide type F, solid
UN3119 Organic peroxide type F, liquid, temperature controlled
UN3120 Organic peroxide type F, solid, temperature controlled
IP5 would be removed from column 7 of the HMT for the following UN numbers:
UN1791 Hypochlorite solution
UN2014 Hydrogen peroxide, aqueous solution with not less than 20% but not more than 60% hydrogen peroxide (
stabilized as necessary).
UN3149 Hydrogen peroxide and peroxyacetic acid mixture with acid(s), water and not more than 5% peroxyacetic acid.
We propose to delete several entries. This action is consistent with the deletion of proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations that we are proposing to adopt into the HMR. The entries identified by corresponding “UN” numbers are:
UN2003 Metal alkyls, water-reactive, n.o.s.
or
Metal aryls, water-reactive, n.o.s.
UN3049 Metal alkyl halides, water-reactive, n.o.s.
or
Metal aryl halides, water-reactive, n.o.s.
UN3050 Metal alkyl hydrides, water-reactive, n.o.s.
or
Metal aryl hydrides, water-reactive, n.o.s.
UN3207 Organometallic compound
or
Compound solution
or
Compound dispersion, water-reactive, flammable, n.o.s.
We propose to add the following new entries. Many of these entries are the liquid or solid form of entries that are already listed in the HMT. This action is consistent with the addition of proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. Affected entries would be as follows:
We propose to add the following new generic entries for materials that are poisonous by inhalation. These new names will replace the existing generic entries in the HMT. This action is consistent with the addition of proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. Affected entries would be as follows:
UN3381 Toxic by inhalation liquid, n.o.s.
with an inhalation toxicity lower than or equal to 200 ml/m 3and saturated vapor concentration greater than or equal to 500 LC50.
UN3382 Toxic by inhalation liquid, n.o.s.
with an inhalation toxicity lower than or equal to 1000 ml/m 3and saturated vapor concentration greater than or equal to 10 LC50.
UN3383 Toxic by inhalation liquid, flammable, n.o.s.
with an inhalation toxicity lower than or equal to 200 ml/m3and saturated vapor concentration greater than or equal to 500 LC50.
UN3384 Toxic by inhalation liquid, flammable, n.o.s.
with an inhalation toxicity lower than or equal to 1000 ml/m 3and saturated vapor concentration greater than or equal to 10 LC50.
UN3385 Toxic by inhalation liquid, water-reactive, n.o.s.
with an inhalation toxicity lower than or equal to 200 ml/m 3and saturated vapor concentration greater than or equal to 500 LC50.
UN3386 Toxic by inhalation liquid, water-reactive, n.o.s.
with an inhalation toxicity lower than or equal to 1000 ml/m 3and saturated vapor concentration greater than or equal to 10 LC50.
UN3387 Toxic by inhalation liquid, oxidizing, n.o.s.
with an inhalation toxicity lower than or equal to 200 ml/m 3and saturated vapor concentration greater than or equal to 500 LC50.
UN3388 Toxic by inhalation liquid, oxidizing, n.o.s.
with an inhalation toxicity lower than or equal to 1000 ml/m 333333and saturated vapor concentration greater than or equal to 10 LC50.
UN3389 Toxic by inhalation liquid, corrosive, n.o.s.
with an inhalation toxicity lower than or equal to 200 ml/m 3and saturated vapor concentration greater than or equal to 500 LC50.
UN3390 Toxic by inhalation liquid, corrosive, n.o.s.
with an inhalation toxicity lower than or equal to 1000 ml/m 3and saturated vapor concentration greater than or equal to 10 LC50.
We propose to add the following new generic entries for organometallic substances. We are not proposing to adopt the “Flowchart scheme for organometallic substances” because we believe that it is intuitive based on the hazard class precedence system in the HMR. This action is consistent with the addition of proper shipping names that were incorporated into the Thirteenth Revised Edition of the UN Recommendations. Affected entries would be as follows:
In addition, we would continue to allow the following specific Organometallic proper shipping names: UN1366, UN1370, UN2005, UN2445, UN3051, UN3052, UN3053, and UN3076. However, we anticipate removing these entries from the HMT by January 1, 2007.
The U.N. Recommendations have adopted a rationalized approach for the assignment of UN portable tank instructions for solid materials. Based on that rationalized approach, we are making several changes to UN portable tank authorizations in the HMR. These proposals are summarized as follows. For a more specific identification of the affected shipping descriptions, refer to theUN report
located in the public Docket.
For Division 4.1, Packing Group I materials, the use of UN portable tanks would not be authorized.
For Division 4.3 materials with a subsidiary class of 6.1, in Packing Group I, the use of portable tanks would not be authorized.
For materials of Divisions 4.1, 4.2, 4.3, 5.1, 6.1, and Classes 8 and 9, in Packing Group II, Special Provisions T3 would be specified.
For Division 4.2, Packing Group I materials, T21 and TP7 would be specified.
For Division 4.3, Packing Group I materials, T9 and TP7 would be specified.
For Division 5.1, Packing Group I materials, the use of UN portable tanks would not be authorized.
For Division 6.1 and Class 8, Packing Group I materials, T6 would be specified.
For materials of Divisions 4.1, 4.2, 4.3, 5.1, 6.1, and Classes 8 and 9, in Packing Group III, Special Provisions T1 would be specified.
Several entries in the HMT would be revised by amending column 9B to
( printed page 34729)
read “forbidden” so that the materials would no longer be authorized for transport aboard cargo aircraft. The entries are being revised because they meet the criteria of either Zone C or Zone D inhalation toxicity. All other Zone C and Zone D toxic by inhalation materials listed in the HMR are currently already forbidden from transport aboard passenger and cargo aircraft (these materials are already forbidden from transport aboard passenger aircraft). The entries to be revised include:
Zone C:
UN2204 Carbonyl sulfide
UN1023 Coal gas, compressed
UN1064 Methyl mercaptan
UN1048 Hydrogen bromide, anhydrous
UN1079 Sulfur dioxide
Zone D:
UN1005 Ammonia, anhydrous
UN3318 Ammonia solution,
relative density less than 0.880 at 15 degrees C in water, with more than 50 percent ammonia
UN1040 Ethylene oxide
or
Ethylene oxide with nitrogen
up to a total pressure of 1MPa (10 bar) at 50 degrees C
UN1040 Ethylene oxide or Ethylene oxide with nitrogen
up to a total pressure of 1MPa (10 bar) at 50 degrees C
UN2191 Sulfuryl fluoride
Also,
see
§ 172.102 for additional HMT amendments.
Appendix B to § 172.101
In Appendix B to § 172.101, List of Marine Pollutants, we are proposing to remove the entries “Isoamyl mercaptan” “Pentanethiols” and “Tetrachlorophenol.” We are propo sing to revise the entry “2, 6-Di-tert-Butylphenol” and we are proposing to add the entry “Chloropicrin.”
Section 172.102
We are proposing to amend § 172.102, Special Provisions, as follows:
Several entries in the HMT would be revised by adding special provisions A3, A6, A7, A9, A10, N3, and N36 to align this section with the equivalent special provisions in the ICAO Technical Instructions (13, 2, 5, 4, 7, 21, and 3 respectively). We propose to remove the “A” special provisions for several entries because we have determined that the materials to which the provisions apply are currently not authorized for transportation on either passenger or cargo aircraft.
The following entries would be revised by adding special provision A3:
UN1154 Diethylamine
UN1788 Hydrobromic acid,
not more than 49% strength
UN1789 Hydrochloric acid
UN2031 Nitric acid,
other than red fuming, with more than 70% nitric acid
The following entries would be revised by adding special provision A9:
UN1449 Barium peroxide
UN1452 Calcium chlorate
UN3212 Hypochlorites, inorganic, n.o.s.
The following entries would be revised by adding special provision A10:
UN1828 Sulphur chlorides
UN2401 Piperidine
The following entry would be revised by adding special provision N3:
UN2817 Ammonium hydrogendifluoride solution
The following entries would be revised by adding special provision N36:
UN1184 Ethylene dichloride
UN1732 Antimony pentafluoride
UN1777 Fluorosulphonic acid
UN2699 Trifluoroacetic acid
The following entries would be revised by removing certain “A” special provisions since the materials themselves are forbidden for transportation aboard passenger and cargo aircraft:
UN1744 Bromine
or
Bromine solutions (remove A3, A6)
UN2484 tert-Butyl isocyanate (remove A7)
UN2485 n-Butyl isocyanate (remove A7)
UN1752 Chloroacetyl chloride (remove A3, A6, A7)
UN1754 Chlorosulfonic acid
(with or without sulfur trioxide)
(remove A3, A6, A10)
UN2382 Dimethylhydrazine, symmetrical (remove A7)
UN1182 Ethyl chloroformate (remove A3, A6, A7)
UN2481 Ethyl isocyanate (remove A7)
UN2014 Hydrogen peroxide, aqueous solutions
with more than 40 percent but not more than 60 percent hydrogen peroxide
(stabilized as necessary) (remove A3, A6)
UN2015 Hydrogen peroxide, stabilized
or
Hydrogen peroxide aqueous solutions,
( printed page 34730)
stabilized
with more than 60 percent hydrogen peroxide
(remove A3, A6)
NA9206 Methyl phosphonic dichloride (remove A3)
UN2534 Methylchlorosilane (remove A2, A3, A7)
UN2304 Naphthalene, molten (remove A1)
UN1670 Perchloromethyl mercaptan (remove A3, A7)
UN1810 Phosphorus oxychloride (remove A7)
UN2740 n-Propyl chloroformate (remove A3, A6, A7)
UN1829 Sulfur trioxide, stabilized (remove A7)
UN1831 Sulfuric acid, fuming
with 30 percent or more free sulfur trioxide
(remove A3, A6, A7)
Paragraph (b)(3) of this section would be amended to specify that a “B” code refers to a special provision that applies only to certain bulk packaging requirements and that, unless otherwise stated, would not apply to UN portable tanks or IBCs.
Paragraph (b)(4) of this section would be amended to specify that a code containing the letters “IB” or “IP” refers to a special provision that applies only to transportation in IBCs.
Paragraph (b)(8) would be redesignated (b)(9) and a new paragraph (b)(8) would be added to specify that a code containing the letters “TP” refers to a special provision that is in addition to those provided by the portable tank instructions or the requirements in part 178.
Special Provision 47 would be revised to include an additional exception currently in the UN Model Regulations specifying that a leakproofness test is not required when the liquids are fully absorbed in solid material contained in sealed bags.
Special Provision 135 would be revised to expand the applicability of the proper shipping names “Vehicle, flammable liquid powered” and “Vehicle, flammable gas powered” to include hybrid electric vehicles.
Special Provision 137 would be revised to expand the exception for “Cotton, dry.”
Special Provision 143 would be removed and relocated to § 173.219 so that the limitations on the types of hazardous materials authorized apply to both self-inflating and non-self-inflating life-saving appliances.
Special Provision 153 would be relocated to new paragraph (k) in § 173.115 and revised to include amended classification criteria for aerosols containing flammable constituents consistent with criteria in the UN Model Regulations. The revised criteria would include methods for the classification of aerosols based on the percentage of flammable components.
New Special Provision 163 would be added to specify that Ammonium Nitrate Emulsions would be required to satisfactorily pass Test Series 8 of the UN Manual of Tests and Criteria, Part I, Section 18.
New Special Provision 164 would be added to specify that an approval is required for “Desensitized explosives, liquid, n.o.s.” and “Desensitized explosives, solid, n.o.s.”
New Special Provision 165 would be added to the Calcium hypochlorite PG II and the PG III entries for UN1748 and UN2880 to specify the danger of exothermic decomposition and require shading from direct sunlight and sources of heat during transportation.
New Special Provision 166 would be added to the PG II entry for calcium hypochlorite, UN2880 and UN1748 to indicate that calcium hypochlorite in the non-friable tablet form may be transported as a PG III material.
New Special Provision 167 would be added to the proposed new entry for “Hydrogen in a metal hydride storage system” to specify that such storage systems shall always be considered as containing hydrogen.
New Special Provision 170 would be added to the newly proposed Organometallic substances entries (UN3391, UN3392, UN3393, and UN3394). The special provision would require air to be eliminated from the vapor space by nitrogen or other means.
New Special Provision 171 would be added to the UN2880 PG III entry. Since UN2880 also covers mixtures of hydrated calcium hypochlorite in any concentration, some formulations in other than tablet form (e.g., in granular form) may meet the criteria for classification in Division 5.1, Packing Group III when subjected to the relevant test in the UN Manual of Tests and Criteria. The PG III entry for calcium hypochlorite would only be authorized when the material is offered in the non-friable tablet form or for granular or powered mixtures. This entry would not be authorized for the pure form of calcium hypochlorite hydrated. We also recognize that some formulations, when tested, do not meet the criteria for classification in Division 5.1. In light of this, we believe that a new Special Provision 171 should be added to the UN2880, PG III entry in the HMT to allow for the possibility to classify powered or granular mixtures of hydrated calcium hypochlorite in Packing Group III when data indicates that the mixture meets the criteria for assignment to PG III.
Special Provision A11 is currently assigned to UN 2983, Ethylene oxide and Propylene oxide mixtures and UN 1411, Lithium aluminum hydride, ethereal. In the ICAO Technical Instructions these substances are only authorized for transport in metal cylinders. A11 states “For combination packagings, when metal inner packagings are permitted, only specification cylinders constructed of metals which are compatible with the hazardous material may be used.” Therefore, to align with ICAO Particular Packing Requirement Number 8, Special Provision A11 would be amended to read “Only specification cylinders constructed of metals which are compatible with the hazardous material may be used.”
Consistent with ICAO, we are adding a proper shipping name to the HMT for “Receptacles, small containing gas, 2.2 with a subsidiary of 5.1.” A new “A” code (A14) would be added to prohibit material from being transported as a limited quantity or consumer commodity in accordance with § 173.306 aboard an aircraft. This new “A” code would also be added to the following additional shipping names: “Oxygen, compressed”, Carbon dioxide and oxygen mixtures”, “Nitrous oxide”, “Compressed gas oxidizing”, and “Liquefied gas, oxidizing.”
For consistency, the authorization in Special Provision B69 to allow dry sodium or potassium cyanide in siftproof, water-resistant fiberboard IBCs would be relocated to new Special Provision IP20.
Paragraph (c)(4) of this section would be amended by relocating “Table 2.—Organic Peroxide IBC Code (IB52)” to paragraph (e) of § 173.225 and renaming it the “Organic Peroxide IBC Table.” Table 3.—IP Codes would then be redesignated Table 2.—IP Codes. The wording of paragraph (c)(4) would be revised to indicate that Table 3.—IP Codes had been redesignated Table 2.—IP Codes. All references to IB52 in the HMR would be removed and replaced with “Organic Peroxide IBC Table” or “§ 173.225(e),” as applicable.
Paragraph (c)(7) would be amended by relocating the Portable Tank Code T50 Table to § 173.313 and renaming it “UN Portable Tank Table for Liquefied Compressed Gases.” The T50 Table and
( printed page 34731)
its description would be removed from paragraph (c)(7)(iv) and replaced with a statement indicating that the new “UN Portable Tank Table for Liquefied Compressed Gases” is found in § 173.313. All references to T50 in the HMR would be removed and replaced with “UN Portable Tank Table for Liquefied Compressed Gases in § 173.313”. In addition, paragraph (c)(7) would be amended by relocating Portable Tank Code T23 to paragraph (g) of § 173.225 and renaming it the “Organic Peroxide Portable Tank Table.” Portable Tank Code T23 and its description found in paragraph (c)(7)(iii) would be removed and paragraphs (c)(7)(iv)-(c)(7)(vii) would be redesignated (c)(7)(iii)-(c)(7)(vi), respectively. All references to T23 in the HMR would be removed and replaced with “Organic Peroxide Portable Tank Table” or “§ 173.225(g),” as applicable.
New paragraph (c)(8) would be added to provide an introduction to the “TP” codes (i.e., portable tank special provisions). The existing paragraph (c)(8) would be redesignated paragraph (c)(9).
New Special IBC Packing Provision IP13 would be added to specify that transportation by vessel in IBCs would be prohibited.
New Special IBC Packing Provision IP14 would be added to specify that air must be eliminated from the vapor space by nitrogen purging or other means.
New Special IBC Packing Provision IP20 would be added to specify that dry sodium cyanide and potassium cyanide are also permitted in siftproof, water-resistant, fiberboard IBCs when transported in closed freight containers or transport vehicles.
Portable tank Special Provision TP3 would be revised to include the maximum degree of filling (in %) for solids transported above their melting points.
Special Provision TP6 would be revised by removing the word “event” and replacing it with the “incident.”
Portable tank Special Provision TP9 would be removed from column (7) of the Hazardous Materials Table for all materials that reference a T code special provision. Special provision TP9 states that a material with TP9 in Column (7) may only be transported in a portable tank if approved by the Associate Administrator. A material that has been given a T code does not require approval and is not subject to Special Provision TP9.
Section 172.202
Paragraph (a)(5)(i) would be revised to clarify that for explosive articles the quantity shown on a shipping paper must be expressed in terms of the net mass of the article.
Section 172.203
Paragraph (f) would be revised by including the passenger and cargo aircraft limitation certification statement that is currently found in § 172.204. This would align the HMR with the ICAO TI (see 4.1.5.8.1(b) of the ICAO TI). In addition, in paragraph (o)(3), the reference to § 173.225(c)(2) would be amended to read § 173.225(b)(2). Paragraph (m)(2) would be revised to specify that the phrase “Poison Inhalation Hazard” or “Toxic Inhalation Hazard” is not required to be repeated if it otherwise appears in the shipping description. Finally, a new paragraph (i)(3) would be added to specify additional shipping paper description requirements for a hazardous material consigned under an “n.o.s.” entry when offered for transportation by vessel.
Section 172.204 and Section 172.321—Air Eligibility Marking
Under HM-215E (68 FR 44992), the air eligibility marking was adopted into the HMR as new § 172.321. Since publication of that final rule, the ICAO's Dangerous Goods Panel removed the air eligibility marking requirement. In lieu of this marking, ICAO adopted a requirement that the shipping paper certification statement include the statement “I declare that all of the applicable air transport requirements have been met” when a hazardous material is offered for air transportation. Additionally, the revised section provided examples of the applicable air transport requirements that must be met. Based on this action, we are proposing to revise the air eligibility marking requirement by making it optional rather than mandatory and adding the additional shipping paper certification statement for shipments going by aircraft. Therefore, we are proposing to revise § 172.204(c)(3) by requiring that the statement “I declare that all of the applicable air transport requirements have been met” be included on the shipping paper in addition to the current certification statement when a hazardous material is offered for air transportation. Additionally, the revised section would provide examples of the applicable air transport requirements that must be met and various section references. In order to allow shippers to expend stocks of preprinted shipping papers containing the previous certification statement, we are providing an additional ten month transitional provision for the new certification statement.
Section 172.317
A new § 172.317 would be added to require a “KEEP AWAY FROM HEAT” handling mark on packages containing self-reactive substances of Division 4.1 or organic peroxides of Division 5.2 when such packages are transported by air.
Part 173
Section 173.3
The definition for “salvage drums” would be revised to include the term “non-conforming.” The term “non-conforming” was added to the definition by the UN Committee of Experts in December 2000.
Section 173.24
For consistency with the UN Recommendations, paragraphs (g)(4) and (g)(5) would be revised to clarify the following:
(A) That IBCs ( subject to the requirements in § 173.24(g)) are permitted to be vented to reduce internal pressure; and
(B) That venting of IBCs is not conditional upon whether a bulk special provision is indicated for a particular hazardous material in the § 172.101 hazardous materials table.
In addition, paragraph (i) would be revised to clarify that other general requirements specific to air transportation apply and are found in § 173.27.
Section 173.25
Paragraph (a)(2) would be revised by removing the requirement to mark an overpack with the air eligibility marking. In addition, in paragraph (a)(4), we propose to require overpacks to be marked with the word “OVERPACK” or, alternatively, until October 1, 2007, with a statement indicating that inside packages comply with prescribed specifications. This is in response to adoption by the United Nations of the “OVERPACK” marking to indicate that packages within an overpack comply with prescribed specifications when specification markings on inside packagings within the overpack are not visible.
Section 173.27
Paragraph (i) would be revised to indicate that the air eligibility mark has been removed. This section would reference a new requirement for shippers to place the following statement at the end of the certification statement when a hazardous material is authorized for air transportation: “I declare that all applicable air transport requirements have been met.”
( printed page 34732)
Section 173.28
In paragraph (c)(2), we propose to delete the words “or a UN 1H1 plastic drum.” This would harmonize the HMR with the UN Model Regulations and remove a source of confusion within the regulated community regarding the reconditioning of a non-bulk packaging.
Section 173.115
In § 173.115, a new paragraph (k) would be added (
see
discussion under § 172.102, Special Provision 153).
Section 173.128
In paragraph (d)(1)(i), the section reference would be revised to read § 173.225(c). In addition, in paragraphs (d)(1)(ii) and (d)(1)(iii), the section reference would be revised to read § 173.225(b).
Section 173.132
In paragraph (b)(1), we propose to revise the definition of LD50
for acute oral toxicity to indicate that adult albino rats may be tested without regard to gender. The current definition for LD50
for acute oral toxicity in § 173.132(b)(1) is based on the Organization for Economic Co-Operation and Development (OECD) Test Guideline (TG) 401. The OECD has agreed to three test methods that will replace the current TG 401. The United Kingdom, Germany and the United States of America took the lead in the development of the three alternative tests that OECD has now adopted and published in the OECD Guidelines for the Testing of Chemicals. In a continuing attempt to improve the estimate of acute oral toxicity while reducing the number of animals used per test, three alternative TGs have been developed and implemented to replace TG 401. The three TGs are the Fixed Dose Procedure (FDP, TG 420), the Acute Toxic Class Method (ATCM, TG 423), and the Up-and-Down Procedure (UDP, TG 425). The proposed text would be consistent with the text in the 13th revised edition of the UN Model Regulations that was recently amended on the basis of a proposal from the United States.
Section 173.136
We propose to add a new paragraph (d) to provide a grandfather clause that will allow the shipment of materials classified as corrosive to steel or aluminum under ASTM G 31-72.
Section 173.137
In paragraph (c)(2), we propose to eliminate the references to ASTM G 31-72 as an acceptable test description and add a statement indicating an acceptable test is prescribed in the Manual of Tests and Criteria, Part III, Section 37.
Sections 173.150, 173.151, 173.152, 173.153 and 173.154
We are proposing to allow most Division 6.1, Packing Group II materials to be transported as a limited quantities. For Packing Group II materials, we are proposing to allow inner packagings not over 100 mL (3.38 ounces) each for liquids or 0.5 kg (1.1 pounds) each for solids to be transported as a limited quantity. However, consistent with the limited quantity authorization for Division 6.1, Packing Group III, we are not proposing a labeling exception for these materials. We are also not proposing to allow these materials to be shipped as a consumer commodity. In addition, we propose to revise the limited quantity sections for the other hazard classes of materials to take into account materials with a subsidiary hazard of 6.1 Packing Group II.
Section 173.185
In § 173.185, we propose to amend paragraphs (c)(3) and (e)(3), to specify that a cell, battery, lithium cell or battery and equipment containing a cell, battery or lithium cell or battery that was transported prior to the effective date of this rule and is of a type proven to meet the criteria of Class 9 by testing, in accordance with the tests prescribed in the UN Manual of Tests and Criteria, Third Revised Edition, 1999 would not be required to be retested.
Section 173.186
In § 173.186, in paragraph (e), we propose to amend the gross weight for 4G outer packages authorized for the transportation of strike-anywhere matches, to be consistent with the UN Model Regulations by increasing the weight from 27 kg (60 pounds) to 30 kg (66 pounds).
Section 173.187
We propose to revise § 173.187 to authorize certain solid hazardous materials to be transported in DOT specification cylinders other than Specification 8 and 3HT cylinders. This proposal would also remove the need for DOT Exemption “DOT-E 11548.”
Sections 173.211, 173.212, and 173.213
We propose to revise these sections to authorize certain solid hazardous materials to be transported in DOT specification cylinders other than Specification 8 and 3HT cylinders. This proposal would also remove the need for DOT Exemption “DOT-E 11548.”
Section 173.219
We propose to revise § 173.219 for consistency with the UN Model Regulations and the ICAO Technical Instructions. Included in the proposed revision is an allowance for self-inflating life-saving appliances to contain cartridges, power devices of Division 1.4S, for purposes of the self-inflating mechanism. In addition, we propose to provide an exception from regulation for life-saving appliances containing only carbon dioxide cylinders not exceeding 100 cm3
capacity, provided they are overpacked in rigid outer packagings with a maximum gross mass of 40 kg. Finally, the limitations currently found in Special Provision 143 would be relocated to § 173.219 (
see
preamble discussion under Special Provision 143).
Section 173.220
Paragraph (b)(2) would be amended to harmonize the requirements for transporting flammable gas powered vehicles by air with the requirements of Packing Instruction 900 of the ICAO Technical Instructions.
Section 173.224
Paragraph (b)(4) of this section would be amended to include the new references for § 173.225. The section reference to § 173.225(e) for the authorization of bulk packagings would be replaced with § 173.225(f) for IBCs and § 173.225(h) for other bulk packagings.
Section 173.225
This section would be amended to update the Organic Peroxide Table and eliminate special provisions IB52 and T23 from § 172.102(c). The purpose of the change is to consolidate the packaging requirements for organic peroxides into one section and to have separate tables for organic peroxides authorized for transport in non-bulk packagings, IBCs, and bulk packagings other than IBCs. The proposed changes are as follows:
Paragraph (a) would be revised by adding paragraphs (b) and (b)(6), which state that bulk packagings may require a lower control temperature than those specified for non-bulk packagings and that an organic peroxide not identified in either the Organic Peroxide Table, Organic Peroxide IBC Table, or Organic Peroxide Portable Tank Table must be approved under § 173.128(c).
Paragraph (b) would be revised to eliminate all IBC and other bulk packaging authorizations from column 6 of the Organic Peroxide Table. Various obsolete entries would also be removed.
( printed page 34733)
The current paragraph (b), “Organic Peroxide Table,” would be moved to paragraph (c) and the current paragraph (c), “New organic peroxides, formulations and samples,” would be moved to paragraph (b).
In the notes following the Organic Peroxide Table we propose to:
Revise note 22 to indicate that ethylbenzene with greater than or equal to 25% of dilutant type A would be acceptable.
Revise note 23 to indicate that methyl isobutyl keytone with greater than or equal to 19% of dilutant type A would be acceptable.
Add a new note 29 to identify materials which are not included in the UN Model Regulations and note that a Competent Authority approval is required for international transportation.
Remove Notes 9, 11, and 14 following the Organic Peroxide Table.
In addition, The Packing Method Table found in paragraph (d), would be revised by replacing the 200 kg maximum quantity for solids and combination packagings listed in OP8 with a 400 kg maximum quantity. Note 2, following the table, would be revised to allow 200 kg of solid material per box and up to 400 kg of material per authorized combination packaging. The note would also indicate that the outer packaging must be a box (4Cl, 4C2, 4D, 4F, 4G, 4H1, and 4H2) and each inner packaging must be of plastics or fiber with a maximum net mass of 25 kg. Paragraph (d)(3) would be clarified by revising the text to state that the maximum content acceptable for glass receptacles used as inner packagings of a combination packaging is 0.5 kg for solids or 0.5 L for liquids.
A new paragraph (e) would be added to include the new “Organic Peroxide IBC Table” that replaces the current “Table 2—Organic Peroxide IBC Code (IB52)” in § 172.102(c)(4). The new table would be revised to add an organic peroxide, “Dicyclohexylperoxydicarbonate, not more than 42% as a stable dispersion, in water.” In addition, the new Organic Peroxide IBC Table would identify, by technical name, those organic peroxides authorized for transportation in the IBCs that are specifically listed in the table.
A new paragraph (f) would be added to include the current IBC requirements contained in paragraph (e)(5) of this section. Paragraph (f) would also include requirements that are specific to organic peroxides packaged in IBCs.
A new paragraph (g) would be added to include the new “Organic Peroxide Portable Tank Table,” that replaces the current “Portable Tank Code T23” found in § 172.102(c)(7)(iii). The new table would be identical to the current table except that for UN 3109, in the entry for Pinanyl hydroperoxyde, 50% would be replaced by 56% and all references to self-reactive materials would be removed. In addition, the Organic Peroxide Portable Tank Table would provide certain portable tank requirements and identify, by technical name, those organic peroxides authorized for transportation in the bulk packagings listed in the new paragraph (h).
The current paragraph (e) would be redesignated as paragraph (h). Paragraph (h) would establish requirements that are specific to organic peroxides packaged in certain bulk packagings. Additionally, the new “Note to Paragraph (h)(3)(vi)” would be revised to include changes brought forth by petition for rulemaking P-1428. The petition proposed to amend the current paragraph (e)(3)(vi) and allow for a second but equally acceptable example of an emergency-relief device sizing method to be added to the HMR. We are in agreement with the petitioner and are proposing to add a statement to the new paragraph (h)(3)(vi) indicating that an additional example of an emergency-relief device sizing method can be found in the “American Institute of Chemical Engineers Process Safety Progress Journal, June 2002 issue (Vol. 21, No. 2)” as referenced in § 171.7(b).
The proposed changes to this section would alter the order of the paragraphs within this section and various citations would need to be changed. Also, paragraphs referencing IB52 or TP23 would be revised to indicate that those provisions no longer exist and the updated requirements are found in paragraph (e) and (g), respectively.
Sections 173.226 and 173.227
We propose to revise the packaging requirements of §§ 173.226 and 173.227 for materials poisonous by inhalation, Division 6.1, Packing Group I, Hazardous Zone A and Hazard Zone B. These amendments would: Reduce the hydrostatic test pressure of the inner drum in a drum-within-a-drum configuration authorized in § 173.226(b); standardize the minimum thickness requirements of the inner drums in the drum-within-a-drum configuration authorized in §§ 173.226(b) and 173.227(b); clarify the test requirements for inner packaging systems in § 173.226(b)(2)(iv); and in § 173.226(d) add a provision to authorize transportation of PIH materials in single packages when subjected to additional operational controls and approved by the Associate Administrator for Hazardous Materials Safety. Section 173.226(c)(2) would be reformatted for ease of understanding. We would also remove an expired transitional date from paragraph (a) that allows the transport of welded cylinders filled before October 1, 2003 for the purpose of reprocessing or disposal of cylinders's content until December 31, 2003.
Section 173.249
Paragraph (c) would be revised to be consistent with the current “Bromine” entry in the § 172.101 “Hazardous Material Table” that authorizes the use of a UN portable tank conforming to tank code T22.
Sections 173.306 and 173.307
To add clarity to the HMR, the text currently found in § 173.306(i) would be removed and replace with the text currently found in § 173.307(a)(5). Since § 173.306 is devoted exclusively to limited quantities of compressed gases, relocating § 173.307(a)(5) to § 173.306 would make the exception easier to find.
Section 173.313
A new § 173.313 would be added to serve as the new location for the Portable Tank Code T50 Table. The table would be renamed “UN Portable Tank Table for Liquefied Compressed Gases.” The table provides the maximum allowable working pressures, bottom opening requirements, pressure relief requirements and degree of filling requirements for liquefied compressed gases permitted for transport in portable tanks. The change would relocate these packaging requirements to Part 173, which is a more appropriate location, and make the special provisions less cumbersome. In addition, the new UN Portable Tank Table for Liquefied Compressed Gases would be amended by revising the Column 3 heading to read “Minimum design pressure (MAWP) (bar) * * *.” The values in column 3 are actually minimum values, however the title of the column is misleading because it uses the term “Maximum allowable working pressure (bar) * * *.”
Section 173.315
In paragraph (a), the reference to “portable tank provision T50 in § 172.102” would be revised to read “the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313”.
( printed page 34734)
Section 173.323
In this rule we are proposing to revise the combination packaging authorizations for Ethylene Oxide to be consistent with the UN Recommendations. Paragraphs (b)(1)-(b)(3) would be revised and consolidated for consistency with current international requirements for the transportation of ethylene oxide in combination packagings. Paragraphs (b)(1)-(b)(3) provide the current authorizations for glass, aluminum, and metal receptacles respectively. Amendments to this section include (1) specifying a 2.5 kg limit per outer package and removing the HMR limitation of 12 inner receptacles per outer package currently applied to aluminum and other metal receptacles, (2) removing the overpack restriction in (b)(2) which specifies a maximum of 10 boxes per overpack, (3) requiring a hot water bath test for all inner receptacles, (4) removing the pressure relief device and burst pressure requirements currently applied to metal receptacles, (5) applying the same outer package authorizations consistently to all inner packaging types and allowing any outer package authorized in § 172.201(b), and (6) requiring all inner packagings to be suitably cushioned (the top and bottom pad and perimeter liner requirement currently only applied to outer packages containing aluminum inner packagings would be removed). Though we are eliminating the option to utilize certain packaging authorizations for glass and aluminum inner packagings, we believe that this proposal will present little or no economic impact on the ethylene oxide industry because of the amount of materials that are transported in international commerce. If comments are received that contradict this understanding, RSPA may revise the final rule accordingly.
Part 175
Section 175.10
Consistent with an amendment to the ICAO TI, we are proposing to require that aerosol cans that are carried aboard an aircraft in accordance with § 175.10(a)(4) have their release devices protected by a cap or other suitable means. In addition, the ICAO Dangerous Goods Panel will convene a series of working groups to develop recommendations for consideration during the 20th session of the Dangerous Goods Panel to further review this issue. These recommendations may lead to additional amendments to the ICAO TI. Finally, we note that non-flammable gases (
e.g., nitrogen) other than carbon dioxide are used for the operation of mechanical limbs. Consistent with an amendment to the ICAO TI, we are proposing to provide an exception from the HMR for mechanical limbs that are powered by any Division 2.2 gas.
Section 175.85
In § 175.85, a new paragraph (j) would be added to specify the cargo location of a package bearing the “KEEP AWAY FROM HEAT” handling marking.
Part 176
Section 176.2
Certain definitions would be revised. The definition for “Explosive article” and “Explosive substance” would be revised to remove an incorrect reference. The definition for “Magazine” would be revised to include a compartment in the vessel. The definition for “Magazine” would also be revised to specify vessel storage location and accessibility. The term “Transport unit” would be revised to read “Cargo transport unit” to be consistent with Amendment 32 of the IMDG Code. In addition, in the definition “In containers or the like” the term “transport unit” would be removed and the term “cargo transport unit” would be added in its place.
Section 176.27
In this section, the words “transport unit” would be replaced with the words “transport vehicle” in each place they appear to be consistent with the removal of the term “transport unit” from the definitions in § 176.2.
Section 176.63
Paragraph (e) would be revised to align the definition of “Closed cargo transport unit” to be consistent with the definition in Amendment 32 of the IMDG Code.
Section 176.76
Paragraph (i) would be revised to clarify that for container ships, a distance equivalent to one container space athwartships (
i.e., in the direction of the breadth of the vessel) away from possible sources of ignition applied in any direction would satisfy the requirement that a cargo transport unit packed or loaded with flammable gas or flammable liquid having a flashpoint below +23 °C transported on deck be stowed “away from” possible ignition sources. This would be consistent with Amendment 32 of the IMDG Code. In addition, in paragraphs (h) and (i), the words “transport unit” would be removed and replaced with the words “cargo transport unit” in each place they appear to be consistent with Amendment 32 of the IMDG.
Section 176.83
Paragraph (l) would be revised to correct an error pertaining to the Segregation Table that set forth the general requirements for segregation of containers on board hatchless container vessels. In addition, throughout the section the words “transport units” would be removed and replaced with the words “cargo transport units” in each place they appear to be consistent with Amendment 32 of the IMDG. A new paragraph (m) would be added to specify the provisions for segregation groups.
Section 176.84
Paragraph (a) would be revised to specify the various chemical groups listed in the segregation table. In the paragraph (b) Table of Provision, we would add eleven new provisions (codes) for certain stowage and segregation requirements for hazardous materials that are transported by vessel. In addition, in paragraph (c)(2) Provisions for the stowage of Class 1 (explosive) materials, we would revise three notes. The terms “separated from” and “away from” in the codes are defined in § 176.83 of the HMR.
Code 133 would be added to the entries “Barium chlorate solution,” UN3405; “Barium perchlorate solution,” UN3406; and “Chlorate and magnesium chloride mixture solution,” UN3407, that requires the material to be stowed “separated from” sulfur.
Code 134 would be added to the entry “Aluminum alkyl halides, solid,” UN3461, that requires the material to be stowed “separated from” UN2716.
Code 135 would be added to the entries “Methylamine, aqueous solution,” UN1235 and “Trimethylamine, aqueous solutions,” UN1297, that requires the material to be stowed “separated from” mercury and mercury compounds.
Code 136 would be added to the entry “Tributylphosphane,” UN3254, that requires the material to be stowed “separated from” tetrachloride.
Code 137 would be added to the entries “Arsenic compounds, liquid, n.o.s.,” UN1556 and “Arsenic compounds, solid, n.o.s.,” UN1557, that requires arsenic sulphides to be stowed “separated from” acids.
Code 138 would be added to the entries for UN1448; UN1456; UN1479; UN1482; UN1490; UN1503; UN1515; UN3085; UN3087; UN3098; UN3099; UN3139; and UN3214, that requires the material to be stowed “separated from” peroxides.
( printed page 34735)
Code 139 would be added to the entry “1, 4-Butynediol,” UN2716, that requires the material to be stowed “separated from” mercury salts.
Code 140 would be added to the entry “1, 4-Butynediol,” UN2716, that requires the material to be stowed “separated from” UN3052 and UN3461.
Code 141 would be added to the entries for UN1732; UN1755; UN1806; UN1908; UN2433; UN2859; and UN2861, that requires the material to be stowed “away from” radioactive materials.
Code 142 would be added to the entries for UN1748; UN2208; and UN 2880, that requires packages in cargo transport units to be stowed so as to allow for adequate air circulation throughout the cargo.
Code 143 would be added to the entry for Organometallic Substance, Liquid, Pyrophoric, UN3392, prohibiting transportation on any vessel carrying explosives (except explosives in Division 1.4, Compatibility group S.
Note 19E would be revised to specify that materials under entries NA0331; UN0004; UN0222; UN0241; and UN0402 must be stowed “away from” explosives containing chlorates or perchlorates.
Note 22E would be revised to specify that materials under the entry “Explosive, blasting, type C,” must be stowed “away from” ammonium compounds and explosives containing ammonium compounds or salts.
Note 23E would be revised to specify that materials under entries UN0247; UN0395; UN0396; UN0397; UN0398; UN0399; UN0400; UN0449; and UN0450 must be “separated from” Division 1.4 and “separated longitudinally by an intervening complete compartment or hold from” Division 1.1, 1.2, 1.3, 1.5, and 1.6 except from explosives of compatibility group J.
Section 176.116
In paragraph (c), the words “transport units” would be revised to read “cargo transport units.” In addition, a new paragraph (f) would be added to specify the under deck stowage requirements of Class 1 (explosive) materials allocated stowage categories 09 and 10.
Sections 176.122 and 176.124
Sections 176.122 and 176.124 would be removed and reserved.
Section 176.128
In § 176.128, the section heading and section would be revised.
Section 176.132
Section 176.132 would be removed and reserved.
Section 176.133
Section 176.133 would be revised to clarify the construction and stowage location requirements for magazine stowage type C.
Section 176.136
Section 176.136 would be revised to clarify the special stowage requirements of Class 1 (explosive) materials. In addition, minor editorial revisions would be made.
Section 176.138
Paragraph (a) would be removed and reserved to be consistent with Amendment 32 of the IMDG Code. This paragraph currently requires Class 1 (explosive) material that is stowed on deck to be carried as close to the vessel's centerline as practicable. (
See
also proposed change to § 176.170.)
Section 176.142
Paragraph (a) would be revised to remove “Pyrophoric organometallic compound, water-reactive, n.o.s.” from the list of liquid hazardous materials of extreme flammability that may not be transported in a vessel carrying Class 1 (explosive) materials. Additionally, we propose to add to the above list the following new liquid entries:
“Organometallic substance , liquid, pyrophoric, water-reactive, UN3394” These proposed changes would be consistent with Amendment 32 of the IMDG Code.
Section 176.144
In this section, the words “transport unit” would be replaced with the words “cargo transport unit” in each place they appear to be consistent with the definition in Amendment 32 of the IMDG Code. Additional notes would be added to Table 176.144(a)—“Authorized Mixed Stowage For Explosives” to address additional exceptions for mixed stowage of Class 1 materials.
Section 176.146
In § 176.146, in paragraph (d)(1), the wording “transport units” would be revised to read “cargo transport units”.
Section 176.168
In § 176.168, in the title before the section heading, the wording “TRANSPORT UNITS AND SHIPBORNE BARGES” would be revised to read “CARGO TRANSPORT UNITS AND SHIPBORNE BARGES”.
Section 176.170
A new paragraph (b) would be added to prohibit freight containers loaded with Class 1 (explosive) materials, except for explosives in Division 1.4, from being stowed in the outermost row of containers. This proposed change would be consistent with Amendment 32 of the IMDG Code.
Section 176.174
Paragraphs (a) and (b) would be revised to remove the references to portable magazines. This proposed change would be consistent with Amendment 32 of the IMDG Code.
Section 176.600
In § 176.600, in paragraph (a), the wording “closed transport units” would be revised to read “closed cargo transport units”.
Part 178
Section 178.274
Paragraph (f)(v) would be revised to more clearly specify the rated flow capacity marking required to be placed on every UN portable tank's pressure relief device.
Section 178.275
Paragraph (i)(2) would be revised to more clearly specify the combined delivery capacity of UN portable tank's pressure relief systems.
Section 178.276
In paragraph (a)(4)(ii)(A), the reference to “portable tank special provision T50” would be revised to read “the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313.”
In addition, paragraph (d), the reference to “portable tank special provision T50 in § 172.102(c)(7)” would be revised to read “UN Portable Tank Table for Liquefied Compressed Gases in § 173.313.” Finally, in paragraph (e)(3), the reference to “portable tank special provision T50 in § 172.102” would be revised to read “the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313.”
Section 178.602
Paragraph (b) would be revised to clarify the requirements applicable to filling packaging other than bags in preparation for testing.
Section 178.603
Paragraph (c) would be revised to add a definition indicating that a minimum specific gravity for solutions of water and anti-freeze is 0.95 for testing at -18 °C (0 °F) or lower. Additionally, in paragraph (e), we propose to specify the drop test height for liquids in single packagings and for inner packagings of
( printed page 34736)
combination packagings, when the test is performed in water.
Section 178.810
Paragraph (b)(3) would be revised to specify that water/anti-freeze solutions with a minimum specific gravity of 0.95 for testing at -18 °C (0 °F) or lower are acceptable test liquids for use when conducting IBC drop tests. This is consistent with our amendment to § 178.603(c)(1) regarding the testing of non-bulk packages. We are also proposing to add a sentence to clarify that when conditioning is required by § 178.810(b), the conditioning specified in § 178.802 (which requires a higher temperature) does not apply.
Part 180
Section 180.350
Paragraph (c) would be revised to expand the definition of routine maintenance of IBCs to include flexible, plastic and textile IBCs.
Section 180.352
A new paragraph (d)(1)(v) would be added to this section. This paragraph would state that retests and inspections performed under paragraphs (d)(1)(i) and (ii) of this section may be used to satisfy the tests and inspections required by paragraph (b) of this section. This addition would incorporate changes made to the 12th revised edition of the Transport of Dangerous Goods Model Regulations into the HMR.
This proposed rule is not considered a significant regulatory action under section 3(f) of Executive Order 12866 and, therefore, was not reviewed by the Office of Management and Budget. This proposed rule is not considered a significant rule under the Regulatory Policies and Procedures of the Department of Transportation (44 FR 11034). Benefits resulting from the adoption of the amendments in this proposed rule include enhanced transportation safety resulting from the consistency of domestic and international hazard communications and continued access to foreign markets by domestic shippers of hazardous materials. This proposed rule applies to offerors and carriers of hazardous materials, such as chemical manufacturers, chemical users and suppliers, packaging manufacturers, distributors, battery manufacturers, radiopharmaceutical companies, and training companies.
The majority of amendments in this proposed rule should result in cost savings and ease the regulatory compliance burden for shippers engaged in domestic and international commerce, including trans-border shipments within North America. For example, cost savings will be realized by shippers and carriers as a result of the following:
Eliminating the air eligibility marking requirement.
Amendments allowing numerous Class 3, PG II materials with a Class 8 sub-risk and others to be transported as a limited quantity.
Allowing cylinders to be used for many more substances than currently authorized.
Allowing salvage packagings to be used for non-conforming packages; and generally minimizing differences between U.S. and international hazardous materials transportation regulations.
We would authorize a delayed effective date and a one-year transition period to allow for training of employees and to ease any burden on entities affected by the amendments. The total net increase in costs to businesses in implementing this rulemaking is considered to be minimal and a preliminary regulatory evaluation is available for review in the Docket.
This proposed rule has been analyzed in accordance with the principles and criteria contained in Executive Order 13132 (“Federalism”). This proposed rule preempts State, local and Indian tribe requirements but does not propose any regulation that has substantial direct effects on the States, the relationship between the national government and the States, or the distribution of power and responsibilities among the various levels of government. Therefore, the consultation and funding requirements of Executive Order 13132 do not apply.
The Federal hazardous material transportation law, 49 U.S.C. 5101-5127, contains an express preemption provision (49 U.S.C. 5125(b)) that preempts State, local, and Indian tribe requirements on certain covered subjects. Covered subjects are:
(1) The designation, description, and classification of hazardous materials;
(2) The packing, repacking, handling, labeling, marking, and placarding of hazardous materials;
(3) The preparation, execution, and use of shipping documents related to hazardous materials and requirements related to the number, contents, and placement of those documents;
(4) The written notification, recording, and reporting of the unintentional release in transportation of hazardous; or
(5) The design, manufacture, fabrication, marking, maintenance, recondition, repair, or testing of a packaging or container represented, marked, certified, or sold as qualified for use in transporting hazardous material.
This proposed rule addresses covered subject items (1), (2), (3), and (5) above and would preempt State, local, and Indian tribe requirements not meeting the “substantively the same” standard. This proposed rule is necessary to incorporate changes adopted in international standards, effective January 1, 2003. If the changes in this proposed rule are not adopted in the HMR, U.S. companies, including numerous small entities competing in foreign markets, would be at an economic disadvantage. These companies would be forced to comply with a dual system of regulations. The changes proposed in this rulemaking are intended to avoid this result. Federal hazardous materials transportation law provides at section 5125(b)(2) that, if DOT issues a regulation concerning any of the covered subjects, DOT must determine and publish in the
Federal Register
the effective date of Federal preemption. The effective date may not be earlier than the 90th day following the date of issuance of the final rule and not later than two years after the date of issuance. We propose that the effective date of Federal preemption be 90 days from the date of publication of a final rule in the
Federal Register
.
This proposed rule was analyzed in accordance with the principles and criteria contained in Executive Order 13175 (“Consultation and Coordination with Indian Tribal Governments”). Because this proposed rule does not have tribal implications, does not impose substantial direct compliance costs, and is required by statute, the funding and consultation requirements of Executive Order 13175 do not apply.
D. Regulatory Flexibility Act, Executive Order 13272, and DOT Procedures and Policies
The Regulatory Flexibility Act (5 U.S.C. 601et seq.) requires an agency to review regulations to assess their impact on small entities, unless the agency determines that a rule is not expected to have a significant impact on a substantial number of small entities. This proposed rule would serve to facilitate the transportation of hazardous
( printed page 34737)
materials in international commerce by providing consistency with international standards. This proposed rule applies to offerors and carriers of hazardous materials, some of whom are small entities, such as chemical users and suppliers, packaging manufacturers, distributors, battery manufacturers, and training companies.
As discussed above, under
Executive Order 12866,
the majority of amendments in this proposed rule should result in cost savings and ease the regulatory compliance burden for shippers engaged in domestic and international commerce, including trans-border shipments within North America.
Many companies will realize economic benefits as a result of the proposed amendments. If the changes proposed in this NPRM are not adopted, U.S. companies, including small entities competing in foreign markets, will be forced to comply with a dual system of regulations to their economic disadvantage. Therefore, I certify that these proposed amendments will not have a significant economic impact on a substantial number of small entities. This certification is subject to modification as a result of a review of comments received in response to this proposed rulemaking.
This proposed rule has been developed in accordance with Executive Order 13272 (“Proper Consideration of Small Entities in Agency Rulemaking”) and DOT's procedures and policies to promote compliance with the Regulatory Flexibility Act to ensure that potential impacts of draft rules on small entities are properly considered.
E. Paperwork Reduction Act
Under the Paperwork Reduction Act of 1995, no person is required to respond to a collection of information unless it displays a valid Office of Management and Budget (OMB) control number. Section 1320.8(d), title 5, Code of Federal Regulations requires that RSPA provide interested members of the public and affected agencies an opportunity to comment on information collection and recordkeeping requests. RSPA currently has two approved information collections affecting this proposed rule: OMB Control Number 2137-0557, “Approvals for Hazardous Materials” with 25,605 burden hours and $562,837.40 burden costs; and OMB Control Number 2137-0613, “Subsidiary Hazard Class & Number/Type of Packagings” with 63,309 burden hours and $216,705 burden costs.
There would be only minor editorial changes proposed under this rule. However, there is no net increase in burden for OMB Control Number 2137-0557 or OMB Control Number 2137-0613. We estimate that the proposed total information collection and recordkeeping burden as follows:
“Approvals for Hazardous Materials,” OMB Number 2137-0557:
Total Annual Number of Respondents:
3,523.
Total Annual Responses:
3,874.8.
Total Annual Burden Hours:
25,605.
Total Annual Burden Cost:
$562,837.40.
“Subsidiary Hazard Class & Number/Type of Packagings,” OMB Number 2137-0613:
Total Annual Number of Respondents:
250,000.
Total Annual Responses:
6,337,500.
Total Annual Burden Hours:
17,604.
Total Annual Burden Cost:
$216,705.
Total First Year Burden Hours:
45,705.
Total First Year Burden Cost:
$1,115,992.
Requests for a copy of this information collection should be directed to Deborah Boothe or T. Glenn Foster, Office of Hazardous Materials Standards (DHM-10), Research and Special Programs Administration, Room 8422, 400 Seventh Street, SW., Washington, DC 20590-0001, telephone (202) 366-8553. Written comments should be addressed to the Dockets Unit identified in the
ADDRESSES
section of this rulemaking. We should receive comments regarding information collection burdens prior to the close of the comment period identified in the
DATES
section of this rulemaking.
F. Regulatory Identifier Number (RIN)
A regulation identifier number (RIN) is assigned to each regulatory actionlisted in the Unified Agenda of Federal Regulations. The Regulatory Information Service Center publishes the Unified Agenda in April and October of each year. The RIN contained in the heading of this document can be used to cross-reference this action with the Unified Agenda.
G. Unfunded Mandates Reform Act
This final rule does not impose unfunded mandates under the Unfunded Mandates Reform Act of 1995. It does not result in costs of $120.7 million or more to either State, local or tribal governments, in the aggregate, or to the private sector, and is the least burdensome alternative that achieves the objective of the rule.
H. Environmental Assessment
The National Environmental Policy Act of 1969 (NEPA) requires Federal agencies to consider the consequences of major Federal actions and prepare a detailed statement on actions significantly affecting the quality of the human environment. We developed an assessment to determine the effects of these revisions on the environment and whether a more comprehensive environmental impact statement may be required. Our findings conclude that there are no significant environmental impacts associated with this proposed rule. Consistency in the regulations for the transportation of hazardous materials aids in the shipper's understanding of what is required and permits shippers to more easily comply with safety regulations and avoid the potential for environmental damage or contamination. For interested parties, an environmental assessment is available in the public docket.
I. Privacy Act
Anyone is able to search the electronic form of any written communications and comments received into any of our dockets by the name of the individual submitting the document (or signing the document, if submitted on behalf of an association, business, labor union, etc.). You may review DOT's complete Privacy Act Statement in the
Federal Register
published on April 11, 2000 (volume 65, number 70; pages 19477-78), or you may visit
http://dms.dot.gov.
2. In § 171.7, in the paragraph (a)(3) table, the following changes are made:
a. Under the entry “International Civil Aviation Organization (ICAO),” the existing entry is revised;
b. Under the entry “International Maritime Organization (IMO),” the entry “International Maritime Dangerous Goods (IMDG) Code, 2002 Consolidated Edition, as amended by Amendment 31 (English edition)” is revised;
c. Under the entry “United Nations,” the entry “UN Recommendations on the Transport of Dangerous Goods, Twelfth Revised Edition (2001)” is revised;
d. Under the entry “United Nations,” the entry “UN Recommendations on the Transport of Dangerous Goods, Manual of Tests and Criteria, Third Revised Edition (1999)” is revised; and
e. In Paragraph (b), under the entry “
The Society of the Plastics Industry, Inc., Organic Peroxide Producers Safety Division, 1275 K Street NW., Suite 400, Washington, DC 20005,” the entry “Example of a Test Method for Venting Sizing: OPPSD/SPI Methodology” would be added.
The revisions and additions would read as follows:
Salvage packaging
means a special packaging conforming to § 173.3 of this subchapter into which damaged, defective, leaking, or non-conforming hazardous materials packages, or hazardous materials that have spilled or leaked, are placed for purposes of transport for recovery or disposal.
* * * * *
4. In § 171.11, paragraphs (d)(15) and (d)(17) are revised to read as follows:
(15) A chemical oxygen generator, including when fitted in protective breathing equipment or other apparatus, is forbidden for transportation aboard a passenger-carrying aircraft and must be approved, classed, described and packaged in accordance with the requirements of this subchapter for transportation on cargo-only aircraft. A chemical oxygen generator that has been used or spent is also forbidden for transportation on aircraft.
* * * * *
(17) A self-reactive substance that is not identified by technical name in the Self-reactive Materials Table in § 173.224(b) of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.124(a)(2)(iii) of this subchapter. An organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in § 173.225 of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d) of this subchapter.
5. In § 171.12, paragraph (b)(20) is revised to read as follows:
(20) A self-reactive substance that is not identified by technical name in the Self-Reactive Materials Table in § 173.224(b) of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.124(a)(2)(iii) of this subchapter. An organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in § 173.225 of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d) of this subchapter.
* * * * *
6. In § 171.12a, paragraphs (a), (b)(9), and (b)(18) are revised to read as follows:
(a)
Scope and applicability.
This section sets forth provisions for the transportation by rail or highway of shipments of hazardous materials which conform to the regulations of the Government of Canada but which may differ from the requirements of this subchapter with regard to hazard communication, classification or packaging. Except as provided in paragraph (b)(5)(iv) of this section, the provisions apply only to shipments which originate in Canada and either terminate in the U.S. or transit the U.S. to a Canadian or foreign destination, and to the return to Canada of bulk packagings that meet the requirements of a DOT or UN Specification and other bulk packagings containing only residues of hazardous materials that were originally imported into the U.S. Reciprocal provisions, applicable to exports from the U.S., appear in the regulations of the Government of Canada.
(b) * * *
(9) For hazardous waste as defined in this subchapter—
(i) The word “Waste” must precede the proper shipping name on shipping papers and packages; and
(ii) The requirements of § 172.204 of this subchapter with respect to the shippers certification and § 172.205 of this subchapter with respect to hazardous waste manifests are applicable;
* * * * *
(18) A self-reactive substance that is not identified by technical name in the Self-reactive Materials Table in § 173.224(b) of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.124(a)(2)(iii) of this subchapter. An organic peroxide that is not identified by a technical name in any of the organic peroxide tables found in § 173.225 of this subchapter must be approved by the Associate Administrator in accordance with the requirements of § 173.128(d) of this subchapter.
* * * * *
7. In § 171.14, paragraphs (d) introductory text, (d)(1), and (d)(2) introductory text are revised to read as follows:
Transitional provisions for implementing certain requirements.
* * * * *
(d) A final rule published in the
Federal Register
on [INSERT PUBLICATION DATE OF FINAL RULE], effective October 1, 2004, resulted in revisions to this subchapter. During the transition period, until January 1, 2006, as provided in paragraph (d)(1) of this section, a person may elect to comply with either the applicable requirements of this subchapter in effect on December 31, 2005, or the requirements published in the [INSERT PUBLICATION DATE OF FINAL RULE] final rule.
(1)
Transition dates.
The effective date of the final rule published on [INSERT PUBLICATION DATE OF FINAL RULE] is October 1, 2004. A delayed compliance date of January 1, 2006 is authorized. On and after January 1, 2006, all applicable regulatory requirements adopted in the final rule in effect on October 1, 2004 must be met.
(2)
Intermixing old and new requirements.
Marking, labeling, placarding, and shipping paper descriptions must conform to either the old requirements of this subchapter in effect on September 30, 2004, or the new requirements of this subchapter in the final rule without intermixing communication elements, except that intermixing is permitted, during the applicable transition period, for packaging, hazard communication, and handling provisions, as follows:
* * * * *
PART 172—HAZARDOUS MATERIALS TABLE, SPECIAL PROVISIONS, HAZARDOUS MATERIALS COMMUNICATIONS, EMERGENCY RESPONSE INFORMATION, AND TRAINING REQUIREMENTS
8. The authority citation for part 172 continues to read as follows:
(11) Except for a material subject to or prohibited by § 173.21, 173.54, 173.56(d), 173.56(e), 173.224(c) or 173.225(b) of this subchapter, a material that is considered to be a hazardous waste or a sample of a material for which the hazard class is uncertain and must be determined by testing may be assigned a tentative proper shipping name, hazard class, identification number and packing group, if applicable, based on the shipper's tentative determination according to:
(i) Defining criteria in this subchapter;
(ii) The hazard precedence prescribed in § 173.2a of this subchapter;
(iii) The shipper's knowledge of the material;
(iv) In addition to paragraphs (c)(11)(i) through (iii) of this section, for a sample of a material other than a waste, the following must be met:
(A) Except when the word “Sample” already appears in the proper shipping
( printed page 34740)
name, the word “Sample” must appear as part of the proper shipping name or in association with the basic description on the shipping paper.
(B) When the proper shipping description for a sample is assigned a “G” in Column (1) of the § 172.101 Table, and the primary constituent(s) for which the tentative classification is based are not known, the provisions requiring a technical name for the constituent(s) do not apply; and
(C) A sample must be transported in a combination packaging that conforms to the requirements of this subchapter that are applicable to the tentative packing group assigned, and may not exceed a net mass of 2.5 kg (5.5 pounds) per package.
Note to Paragraph (c)(11):
For the transportation of self-reactive, organic peroxide and explosive samples,
see
§§ 173.224(c)(3), 173.225(b)(2) and 173.56(d) of this subchapter, respectively.
* * * * *
(d) * * *
(4) When an entry in this column reads “Comb liq”, the material is assigned to the hazard class “Combustible liquid.” Additionally, each reference to a Class 3 material is modified to read “Combustible liquid” when that material is reclassified in accordance with § 173.150 (e) or (f) of this subchapter or has a flash point above 60.5 °C (141 °F) but below 93 °C (200 °F).
* * * * *
(i) * * *
(3)
Bulk packaging.
Column 8C specifies the section in part 173 of this subchapter that prescribes packaging requirements for bulk packagings, subject to the limitations, requirements and additional authorizations of Column 7. A “None” in this column means bulk packagings are not authorized, except as may be provided by special provisions in Column 7. Additional authorizations and limitations for use of UN portable tanks are set forth in Column 7. For each reference in this column to a material that is a hazardous waste or a hazardous substance, and whose proper shipping name is preceded in Column 1 of the Table by the letter “A” or “W” and that is offered for transportation or transported by a mode in which its transportation is not otherwise subject to the requirements of this subchapter:
* * * * *
( printed page 34741)
§ 172.101 Hazardous Materials Table
Symbols
Hazardous materials descriptions and proper shipping names
Hazard class or Division
Identification Numbers
PG
Label Codes
Special provisions (§172.102)
(8) Packaging (§173.***)
(9) Quantity limitations
(10) Vessel stowage
Exceptions
Non-bulk
Bulk
Passenger aircraft/rail
Cargo air- craft only
Location
Other
(1)
(2)
(3)
(4)
(5)
(6)
(7)
(8A)
(8B)
(8C)
(9A)
(9B)
(10A)
(10B)
Accellerene, see
p-Nitrosodimethylaniline
Accumulators, electric, see
Batteries, wet
etc
Accumulators, pressurized, pneumatic or hydraulic (containing non-flamable gas), see
Articles pressurized, pneumatic
or
hydraulic (containing non-flamable gas)
Acetal
3
UN1088
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
E
Acetaldehyde
3
UN1089
I
3
A3, B16, T11, TP2, TP7
None
201
243
Forbidden
30 L
E
A
Acetaldehyde ammonia
9
UN1841
III
9
IB8, IP3, IP7, T1, TP33
155
204
240
200 kg
200 kg
A
34
Acetaldehyde oxime
3
UN2332
III
3
B1, IB3, T4, TP1
150
203
242
60 L
220 L
A
Acetic acid, glacial
or
Acetic acid solution,
with more than 80 percent acid, by mass
8
UN2789
II
8, 3
A3, A6, A7, A10, B2, IB2, T7, TP2
154
202
243
1 L
30 L
A
Acetic acid solution,
not less than 50 percent but not more than 80 percent acid, by mass
8
UN2790
II
8
A3, A6, A7, A10, B2, IB2, T7, TP2
154
202
242
1 L
30 L
A
Acetic acid solution,
with more than 10 percent and less than 50 percent acid, by mass
Ammonium nitrate,
with more than 0.2 percent combustible substances, including any organic substance calculated as carbon, to the exclusion of any other added substance
1.1D
UN0222
II
1.1D
None
62
None
Forbidden
Forbidden
10
19E
Ammonium nitrate,
with not more than 0.2% total combustible material, including any organic substance, calculated as carbon to the exclusion of any other added substance
5.1
UN1942
III
5.1
A1, A29, IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
48, 59, 60, 116
Ammonium nitrite
Forbidden
Ammonium perchlorate
1.1D
UN0402
II
1.1D
107
None
62
None
Forbidden
Forbidden
10
19E
Ammonium perchlorate
5.1
UN1442
II
5.1
107, A9, IB6, IP2, T3, TP33
152
212
242
5 kg
25 kg
E
58, 69
Ammonium permanganate
Forbidden
Ammonium persulfate
5.1
UN1444
III
5.1
A1, A29, IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
Ammonium picrate,
dry or wetted with less than 10 percent water, by mass
1.1D
UN0004
II
1.1D
None
62
None
Forbidden
Forbidden
10
5E, 19E
Ammonium picrate, wetted
with not less than 10 percent water, by mass
4.1
UN1310
I
4.1
23, A2, N41
None
211
None
0.5 kg
0.5 kg
D
28, 36
Ammonium polysulfide, solution
8
UN2818
II
8, 6.1
IB2, T7, TP2, TP13
154
202
243
1 L
30 L
B
12, 40, 52
III
8, 6.1
IB3, T4, TP1, TP13
154
203
241
5 L
60 L
B
12, 40, 52
Ammonium polyvanadate
6.1
UN2861
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
44, 89, 100, 141
Ammonium silicofluoride, see
Ammonium fluorosilicate
Ammonium sulfide solution
8
UN2683
II
8, 6.1, 3
IB1, T7, TP2, TP13
154
202
243
1 L
30 L
B
12, 22, 52, 100
Ammunition, blank, see
Cartridges for weapons, blank
Ammunition, illuminating
with or without burster, expelling charge or propelling charge
1.2G
UN0171
II
1.2G
62
None
Forbidden
Forbidden
03
Ammunition, illuminating
with or without burster, expelling charge or propelling charge
1.3G
UN0254
II
1.3G
62
None
Forbidden
Forbidden
03
Ammunition, illuminating
with or without burster, expelling charge or propelling charge
1.4G
UN0297
II
1.4G
62
None
Forbidden
75 kg
02
Ammunition, incendiary
liquid or gel, with burster, expelling charge or propelling charge
1.3J
UN0247
II
1.3J
62
None
Forbidden
Forbidden
04
23E
Ammunition, incendiary (water-activated contrivances) with burster, expelling charge or propelling charge, see
Contrivances, water-activated, etc.
Ammunition, incendiary, white phosphorus,
with burster, expelling charge or propelling charge
1.2H
UN0243
II
1.2H
62
None
Forbidden
Forbidden
08
8E, 14E, 15E, 17E
Ammunition, incendiary, white phosphorus,
with burster, expelling charge or propelling charge
1.3H
UN0244
II
1.3H
62
None
Forbidden
Forbidden
08
8E, 14E, 15E, 17E
Ammunition, incendiary
with or without burster, expelling charge, or propelling charge
1.2G
UN0009
II
1.2G
62
None
Forbidden
Forbidden
03
Ammunition, incendiary
with or without burster, expelling charge, or propelling charge
1.3G
UN0010
II
1.3G
62
None
Forbidden
Forbidden
03
Ammunition, incendiary
with or without burster, expelling charge or propelling charge
1.4G
UN0300
II
1.4G
62
None
Forbidden
75 kg
02
Ammunition, practice
1.4G
UN0362
II
1.4G
62
None
Forbidden
75 kg
02
Ammunition, practice
1.3G
UN0488
II
1.3G
62
None
Forbidden
Forbidden
03
Ammunition, proof
1.4G
UN0363
II
1.4G
62
None
Forbidden
75 kg
02
Ammunition, rocket, see
Warheads, rocket
etc
Ammunition, SA (small arms), see
Cartridges for weapons,
etc
Ammunition, smoke (water-activated contrivances), white phosphorus, with burster, expelling charge or propelling charge, see
Contrivances, water-activated,
etc. (UN 0248)
Ammunition, smoke (water-activated contrivances), without white phosphorus or phosphides, with burster, expelling charge or propelling charge, see
Contrivances, water-activated,
etc. (UN 0249)
Ammunition smoke, white phosphorus
with burster,expelling charge, or propelling charge
1.2H
UN0245
II
1.2H
62
None
Forbidden
Forbidden
08
8E, 14E, 15E, 17E
Ammunition, smoke, white phosphorus
with burster, expelling charge, or propelling charge
1.3H
UN0246
II
1.3H
62
None
Forbidden
Forbidden
08
8E, 14E, 15E, 17E
( printed page 34747)
Ammunition, smoke
with or without burster, expelling charge or propelling charge
1.2G
UN0015
II
1.2G
62
None
Forbidden
Forbidden
8E, 17E, 20E
Ammunition, smoke
with or without burster, expelling charge or propelling charge
1.3G
UN0016
II
1.3G
62
None
Forbidden
Forbidden
8E, 17E, 20E
Ammunition, smoke
with or without burster, expelling charge or propelling charge
1.4G
UN0303
II
1.4G
62
None
Forbidden
75 kg
7E, 8E, 14E, 15E, 17E
Ammunition, sporting, see
Cartridges for weapons,
etc. (UN 0012; UN 0328; UN 0339)
Ammunition, tear-producing, non-explosive,
without burster or expelling charge, non-fuzed
6.1
UN2017
II
6.1, 8
None
212
None
Forbidden
50 kg
E
13, 40
Ammunition, tear-producing
with burster, expelling charge or propelling charge
1.2G
UN0018
II
1.2G, 8, 6.1
62
None
Forbidden
Forbidden
8E, 17E, 20E
Ammunition, tear-producing
with burster, expelling charge or propelling charge
1.3G
UN0019
II
1.3G, 8, 6.1
62
None
Forbidden
Forbidden
8E, 17E, 20E
Ammunition, tear-producing
with burster, expelling charge or propelling charge
1.4G
UN0301
II
1.4G, 8, 6.1
62
None
Forbidden
75 kg
7E, 8E, 14E, 15E, 17E
Ammunition, toxic, non-explosive,
without burster or expelling charge, non-fuzed
6.1
UN2016
II
6.1
None
212
None
Forbidden
100 kg
E
13, 40
Ammunition, toxic (water-activated contrivances), with burster, expelling charge or propelling charge, see
Contrivances, water-activated,
etc
G
Ammunition, toxic
with burster, expelling charge, or propelling charge
1.2K
UN0020
II
1.2K, 6.1
62
None
Forbidden
Forbidden
08
8E, 14E, 15E, 17E
G
Ammunition, toxic
with burster, expelling charge, or propelling charge
1.3K
UN0021
II
1.3K, 6.1
62
None
Forbidden
Forbidden
08
8E, 14E, 15E, 17E
Amyl acetates
3
UN1104
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Amyl acid phosphate
8
UN2819
III
8
IB3, T4, TP1
154
203
241
5 L
60 L
A
Amyl butyrates
3
UN2620
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Amyl chlorides
3
UN1107
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
B
Amyl formates
3
UN1109
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Amyl mercaptans
3
UN1111
II
3
A3, A6, IB2, T4, TP1
None
202
242
5 L
60 L
B
95, 102
n-Amyl methyl ketone
3
UN1110
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Amyl nitrate
3
UN1112
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
40
Amyl nitrites
3
UN1113
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
E
40
Amylamines
3
UN1106
II
3, 8
IB2, T7, TP1
150
202
243
1 L
5 L
B
III
3, 8
B1, IB3, T4, TP1
150
203
242
5 L
60 L
A
Amyltrichlorosilane
8
UN1728
II
8
A7, B2, B6, IB2, N34, T7, TP2, TP13
None
202
242
Forbidden
30 L
C
40
Anhydrous ammonia,
see
Ammonia, anhydrous
Anhydrous hydrofluoric acid, see
Hydrogen fluoride, anhydrous
+
Aniline
6.1
UN1547
II
6.1
IB2, T7, TP2
153
202
243
5 L
60 L
A
40, 52
Aniline hydrochloride
6.1
UN1548
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
Aniline oil, see
Aniline
Anisidines
6.1
UN2431
III
6.1
IB3, T4, TP1
153
203
241
60 L
220 L
A
Anisole
3
UN2222
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Anisoyl chloride
8
UN1729
II
8
B2, B4, IB8, IP2, IP4, T3, TP33
154
212
240
15 kg
50 kg
A
Anti-freeze, liquid, see
Flammable liquids, n.o.s.
Antimonous chloride, see
Antimony trichloride
Antimony compounds, inorganic, liquid, n.o.s.
6.1
UN3141
III
6.1
35, IB3, T7, TP1, TP28
153
203
241
60 L
220 L
A
Antimony compounds, inorganic, solid, n.o.s.
6.1
UN1549
III
6.1
35, IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
Antimony lactate
6.1
UN1550
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
Antimony pentachloride, liquid
8
UN1730
II
8
B2, IB2, T7, TP2
None
202
242
1 L
30 L
C
40
Antimony pentachloride, solutions
8
UN1731
II
8
B2, IB2, T7, TP2
154
202
242
1 L
30 L
C
40
III
8
IB3, T4, TP1
154
203
241
5 L
60 L
C
40
Antimony pentafluoride
8
UN1732
II
8, 6.1
A3, A6, A7, A10, IB2, N3, N36, T7, TP2
None
202
243
Forbidden
30 L
D
44, 89, 100, 141
Antimony potassium tartrate
6.1
UN1551
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
( printed page 34748)
Antimony powder
6.1
UN2871
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
Antimony sulfide and a chlorate, mixtures of
Forbidden
Antimony sulfide, solid, see
Antimony compounds, inorganic, n.o.s.
Antimony trichloride, liquid
8
UN1733
II
8
B2, IB2
154
202
242
1 L
30 L
C
40
Antimony trichloride, solid
8
UN1733
II
8
IB8, IP2, IP4
154
212
240
15 kg
50 kg
A
40
Aqua ammonia, see
Ammonia solution,
etc
Argon, compressed
2.2
UN1006
2.2
306
302
314, 315
75 kg
150 kg
A
Argon, refrigerated liquid
(cryogenic liquid)
2.2
UN1951
2.2
T75, TP5
320
316
318
50 kg
500 kg
B
Arsenic
6.1
UN1558
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Arsenic acid, liquid
6.1
UN1553
I
6.1
T20, TP2, TP7, TP13
None
201
243
1 L
30 L
B
46
Arsenic acid, solid
6.1
UN1554
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Arsenic bromide
6.1
UN1555
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
12, 40
Arsenic chloride, see
Arsenic trichloride
Arsenic compounds, liquid, n.o.s.
inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s.
6.1
UN1556
I
6.1
T14, TP2, TP13, TP27
None
201
243
1 L
30 L
B
40, 137
II
6.1
IB2, T11, TP2, TP13, TP27
153
202
243
5 L
60 L
B
40, 137
III
6.1
IB3, T7, TP2, TP28
153
203
241
60 L
220 L
B
40, 137
Arsenic compounds, solid, n.o.s.
inorganic, including arsenates, n.o.s.; arsenites, n.o.s.; arsenic sulfides, n.o.s.; and organic compounds of arsenic, n.o.s.
6.1
UN1557
I
6.1
IB7, IP1, T6, TP33
None
211
242
5 kg
50 kg
A
137
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
137
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
137
Arsenic pentoxide
6.1
UN1559
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Arsenic sulfide and a chlorate, mixtures of
Forbidden
Arsenic trichloride
6.1
UN1560
I
6.1
2, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45
None
227
244
Forbidden
Forbidden
B
40
Arsenic trioxide
6.1
UN1561
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Arsenic, white, solid, see
Arsenic trioxide
Arsenical dust
6.1
UN1562
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Arsenical pesticides, liquid, flammable, toxic,
flash point less than 23 degrees C
3
UN2760
I
3, 6.1
T14, TP2, TP13, TP27
None
201
243
Forbidden
30 L
B
40
II
3, 6.1
IB2, T11, TP2, TP13, TP27
150
202
243
1 L
60 L
B
40
Arsenical pesticides, liquid, toxic
6.1
UN2994
I
6.1
T14, TP2, TP13, TP27
None
201
243
1 L
30 L
B
40
II
6.1
IB2, T11, TP2, TP13, TP27
153
202
243
5 L
60 L
B
40
III
6.1
IB3, T7, TP2, TP28
153
203
241
60 L
220 L
A
40
Arsenical pesticides, liquid, toxic, flammable,
flash point not less than 23 degrees C
6.1
UN2993
I
6.1, 3
T14, TP2, TP13, TP27
None
201
243
1 L
30 L
B
40
II
6.1, 3
IB2, T11, TP2, TP13, TP27
153
202
243
5 L
60 L
B
40
III
6.1, 3
B1, IB3, T7, TP2, TP28
153
203
242
60 L
220 L
A
40
Arsenical pesticides, solid, toxic
6.1
UN2759
I
6.1
IB7, IP1, T6, TP33
None
211
242
5 kg
50 kg
A
40
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
40
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
40
( printed page 34749)
Arsenious acid, solid, see
Arsenic trioxide
Arsenious and mercuric iodide solution, see
Arsenic compounds, liquid, n.o.s.
Arsine
2.3
UN2188
2.3, 2.1
1
None
192
245
Forbidden
Forbidden
D
40
Articles, explosive, extremely insensitive
or
Articles, EEI
1.6N
UN0486
II
1.6N
101
None
62
None
Forbidden
Forbidden
07
G
Articles, explosive, n.o.s.
1.4S
UN0349
II
1.4S
101
None
62
None
25 kg
100 kg
05
G
Articles, explosive, n.o.s.
1.4B
UN0350
II
1.4B
101
None
62
None
Forbidden
Forbidden
06
G
Articles, explosive, n.o.s.
1.4C
UN0351
II
1.4C
101
None
62
None
Forbidden
75 kg
06
G
Articles, explosive, n.o.s.
1.4D
UN0352
II
1.4D
101
None
62
None
Forbidden
75 kg
06
G
Articles, explosive, n.o.s.
1.4G
UN0353
II
1.4G
101
None
62
None
Forbidden
75 kg
06
G
Articles, explosive, n.o.s.
1.1L
UN0354
II
1.1L
101
None
62
None
Forbidden
Forbidden
08
8E, 14E, 15E, 17E
G
Articles, explosive, n.o.s.
1.2L
UN0355
II
1.2L
101
None
62
None
Forbidden
Forbidden
08
8E, 14E, 15E, 17E
G
Articles, explosive, n.o.s.
1.3L
UN0356
II
1.3L
101
None
62
None
Forbidden
Forbidden
08
8E, 14E, 15E, 17E
G
Articles, explosive, n.o.s.
1.1C
UN0462
II
1.1C
101
None
62
None
Forbidden
Forbidden
07
G
Articles, explosive, n.o.s.
1.1D
UN0463
II
1.1D
101
None
62
None
Forbidden
Forbidden
07
G
Articles, explosive, n.o.s.
1.1E
UN0464
II
1.1E
101
None
62
None
Forbidden
Forbidden
07
G
Articles, explosive, n.o.s.
1.1F
UN0465
II
1.1F
101
None
62
None
Forbidden
Forbidden
08
G
Articles, explosive, n.o.s.
1.2C
UN0466
II
1.2C
101
None
62
None
Forbidden
Forbidden
07
G
Articles, explosive, n.o.s.
1.2D
UN0467
II
1.2D
101
None
62
None
Forbidden
Forbidden
07
G
Articles, explosive, n.o.s.
1.2E
UN0468
II
1.2E
101
None
62
None
Forbidden
Forbidden
07
G
Articles, explosive, n.o.s.
1.2F
UN0469
II
1.2F
101
None
62
None
Forbidden
Forbidden
08
G
Articles, explosive, n.o.s.
1.3C
UN0470
II
1.3C
101
None
62
None
Forbidden
Forbidden
07
G
Articles, explosive, n.o.s.
1.4E
UN0471
II
1.4E
101
None
62
None
Forbidden
75 kg
06
G
Articles, explosive, n.o.s.
1.4F
UN0472
II
1.4F
101
None
62
None
Forbidden
Forbidden
08
Articles, pressurized pneumatic
or
hydraulic
containing non-flammable gas
2.2
UN3164
2.2
306
302, 304
None
No limit
No limit
A
Articles, pyrophoric
1.2L
UN0380
II
1.2L
None
62
None
Forbidden
Forbidden
08
8E, 14E, 15E, 17E
Articles, pyrotechnic
for technical purposes
1.1G
UN0428
II
1.1G
None
62
None
Forbidden
Forbidden
07
Articles, pyrotechnic
for technical purposes
1.2G
UN0429
II
1.2G
None
62
None
Forbidden
Forbidden
07
Articles, pyrotechnic
for technical purposes
1.3G
UN0430
II
1.3G
None
62
None
Forbidden
Forbidden
07
Articles, pyrotechnic
for technical purposes
1.4G
UN0431
II
1.4G
None
62
None
Forbidden
75 kg
06
Articles, pyrotechnic
for technical purposes
1.4S
UN0432
II
1.4S
None
62
None
25 kg
100 kg
05
D
Asbestos
9
NA2212
III
9
156, IB8, IP2, IP4
155
216
240
200 kg
200 kg
A
34, 40
Ascaridole (organic peroxide)
Forbidden
D
Asphalt,
at or above its flash point
3
NA1999
III
3
IB3, T1, TP3
150
203
247
Forbidden
Forbidden
D
D
Asphalt, cut back,
see
Tars, liquid,
etc
Automobile, motorcycle, tractor, other self-propelled vehicle, engine, or other mechanical apparatus, see
Vehicles
or
Battery
etc
A G
Aviation regulated liquid, n.o.s.
9
UN3334
9
A35
155
204
No limit
No limit
A
A G
Aviation regulated solid, n.o.s.
9
UN3335
9
A35
155
204
No limit
No limit
A
Azaurolic acid (salt of) (dry)
Forbidden
Azido guanidine picrate (dry)
Forbidden
5-Azido-1-hydroxy tetrazole
Forbidden
Azido hydroxy tetrazole (mercury and silver salts)
Forbidden
3-Azido-1,2-Propylene glycol dinitrate
Forbidden
Azidodithiocarbonic acid
Forbidden
Azidoethyl nitrate
Forbidden
1-Aziridinylphosphine oxide-(tris), see
Tris-(1-aziridinyl) phosphine oxide, solution
Azodicarbonamide
4.1
UN3242
II
4.1
38, IB8, T3, TP33
151
212
240
Forbidden
Forbidden
D
12, 52, 53, 74
Azotetrazole (dry)
Forbidden
Barium
4.3
UN1400
II
4.3
A19, IB7, IP2, T3, TP33
151
212
241
15 kg
50 kg
E
52
Barium alloys, pyrophoric
4.2
UN1854
I
4.2
T21, TP7, TP33
None
181
None
Forbidden
Forbidden
D
Barium azide,
dry or wetted with less than 50 percent water, by mass
1.1A
UN0224
II
1.1A, 6.1
111, 117
None
62
None
Forbidden
Forbidden
12
Barium azide, wetted
with not less than 50 percent water, by mass
4.1
UN1571
I
4.1, 6.1
162, A2
None
182
None
Forbidden
0.5 kg
D
28
Barium bromate
5.1
UN2719
II
5.1, 6.1
IB8, IP2, IP4, T3, TP33
152
212
242
5 kg
25 kg
A
56, 58
Barium chlorate, solid
5.1
UN1445
II
5.1, 6.1
A9, IB6, IP2, N34, T3, TP33
152
212
242
5 kg
25 kg
A
56, 58
( printed page 34750)
Barium chlorate, solution
5.1
UN3405
II
5.1, 6.1
A9, IB2, N34, T4, TP1
152
202
243
1 L
5 L
A
56, 58, 133
III
5.1, 6.1
A9, IB2, N34, T4, TP1
152
203
242
2.5 L
30 L
A
56, 58, 133
Barium compounds, n.o.s.
6.1
UN1564
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
Barium cyanide
6.1
UN1565
I
6.1
IB7, IP1, N74, N75, T6, TP33
None
211
242
5 kg
50 kg
A
40, 52
Barium hypochlorite
with more than 22 percent available chlorine
Batteries, wet, filled with acid,
electric storage
8
UN2794
III
8
159
159
159
30 kg gross
No limit
A
Batteries, wet, filled with alkali,
electric storage
8
UN2795
III
8
159
159
159
30 kg gross
No limit
A
Batteries, wet, non-spillable,
electric storage
8
UN2800
III
8
159
159
159
No Limit
No Limit
A
Batteries, dry,
not subject to the requirements of this subchapter
130
Battery fluid, acid
8
UN2796
II
8
A3, A7, B2, B15, IB2, N6, N34, T8, TP2, TP12
154
202
242
1 L
30 L
B
Battery fluid, alkali
8
UN2797
II
8
B2, IB2, N6, T7, TP2, TP28
154
202
242
1 L
30 L
A
29
Battery lithium type, see
Lithium batteries
etc
Battery-powered vehicle
or
Battery-powered equipment
9
UN3171
9
134
220
220
None
No limit
No limit
Battery, wet, filled with acid or alkali with vehicle or mechanical equipment containing an internal combustion engine, see
Vehicle,
etc. or
Engines, internal combustion,
etc
+
Benzaldehyde
9
UN1990
III
9
IB3, T2, TP1
155
203
241
100 L
220 L
A
Benzene
3
UN1114
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
B
40
Benzene diazonium chloride (dry)
Forbidden
Benzene diazonium nitrate (dry)
Forbidden
Benzene phosphorus dichloride, see
Phenyl phosphorus dichloride
Benzene phosphorus thiodichloride, see
Phenyl phosphorus thiodichloride
Chlorodifluorobromomethane
or
Refrigerant gas R 12B1
2.2
UN1974
2.2
T50
306
304
314, 315
75 kg
150 kg
A
Chlorodifluoromethane and chloropentafluoroethane mixture
or
Refrigerant gas R 502
with fixed boiling point, with approximately 49 percent chlorodifluoromethane
Cyclonite and cyclotetramethylenetetranitramine mixtures, wetted
or
desensitized
see
RDX and HMX mixtures, wetted
or
desensitized
etc
Cyclonite and HMX mixtures, wetted
or
desensitized
see
RDX and HMX mixtures, wetted
or
desensitized
etc
Cyclonite and octogen mixtures, wetted
or
desensitized
see
RDX and HMX mixtures, wetted
or
desensitized
etc
Cyclonite,
see
Cyclotrimethylenetrinitramine,
etc
Cyclooctadiene phosphines,
see
9-Phosphabicyclononanes
Cyclooctadienes
3
UN2520
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Cyclooctatetraene
3
UN2358
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
B
Cyclopentane
3
UN1146
II
3
IB2, T7, TP1
150
202
242
5 L
60 L
E
Cyclopentane, methyl, see
Methylcyclopentane
Cyclopentanol
3
UN2244
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Cyclopentanone
3
UN2245
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Cyclopentene
3
UN2246
II
3
IB2, IP8, T7, TP2
150
202
242
5 L
60 L
E
Cyclopropane
2.1
UN1027
2.1
T50
306
304
314, 315
Forbidden
150 kg
E
40
Cyclotetramethylene tetranitramine (dry or unphlegmatized) (HMX)
Forbidden
Cyclotetramethylenetetranitramine, desensitized
or
Octogen, desensitized
or
HMX, desensitized
1.1D
UN0484
II
1.1D
None
62
None
Forbidden
Forbidden
10
Cyclotetramethylenetetranitramine, wetted
or
HMX, wetted
or
Octogen, wetted
with not less than 15 percent water, by mass
1.1D
UN0226
II
1.1D
None
62
None
Forbidden
Forbidden
10
Cyclotrimethylenetrinitramine and cyclotetramethylenetetranitramine mixtures, wetted
or
desensitized
see
RDX and HMX mixtures, wetted
or
desensitized
etc
Cyclotrimethylenenitramine and octogen, mixtures, wetted
or
desensitized
see
RDX and HMX mixtures, wetted
or
desensitized
etc
Cyclotrimethylenetrinitramine and HMX mixtures, wetted
or
desensitized
see
RDX and HMX mixtures, wetted
or
desensitized
etc
Cyclotrimethylenetrinitramine, desensitized
or
Cyclonite, desensitized
or
Hexogen, desensitized
or
RDX, desensitized
1.1D
UN0483
II
1.1D
None
62
None
Forbidden
Forbidden
10
Cyclotrimethylenetrinitramine, wetted
or
Cyclonite, wetted
or
Hexogen, wetted
or
RDX, wetted
with not less than 15 percent water by mass
1.1D
UN0072
II
1.1D
None
62
None
Forbidden
Forbidden
10
Cymenes
3
UN2046
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Dangerous Goods in Machinery
or
Dangerous Goods in Apparatus
9
UN3363
136
None
222
None
No limit
No limit
A
Decaborane
4.1
UN1868
II
4.1, 6.1
A19, A20, IB6, IP2, T3, TP33
None
212
None
Forbidden
50 kg
A
74
Decahydronaphthalene
3
UN1147
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
n-Decane
3
UN2247
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Deflagrating metal salts of aromatic nitroderivatives, n.o.s.
1.3C
UN0132
II
1.3C
None
62
None
Forbidden
Forbidden
10
5E
( printed page 34767)
Delay electric igniter, see
Igniters
Depth charges, see
Charges, depth
G
Desensitized explosive, liquid, n.o.s.
3
UN3379
I
3
164
None
201
None
Forbidden
Forbidden
D
36
G
Desensitized explosive, solid, n.o.s.
4.1
UN3380
I
4.1
164
None
211
None
Forbidden
Forbidden
D
28, 36
Detonating relays, see
Detonators,
etc
Detonator assemblies, non-electric
for blasting
1.1B
UN0360
II
1.1B
None
62
None
Forbidden
Forbidden
11
Detonator assemblies, non-electric,
for blasting
1.4B
UN0361
II
1.4B
103
63(f), 63(g)
62
None
Forbidden
75 kg
06
Detonator, assemblies, non-electric
for blasting
1.4S
UN0500
II
1.4S
63(f), 63(g)
62
None
25 kg
100 kg
05
Detonators, electric,
for blasting
1.1B
UN0030
II
1.1B
63(f), 63(g)
62
None
Forbidden
Forbidden
11
Detonators, electric,
for blasting
1.4B
UN0255
II
1.4B
103
63(f), 63(g)
62
None
Forbidden
75 kg
06
Detonators, electric
for blasting
1.4S
UN0456
II
1.4S
63(f), 63(g)
62
None
25 kg
100 kg
05
Detonators for ammunition
1.1B
UN0073
II
1.1B
None
62
None
Forbidden
Forbidden
11
Detonators for ammunition
1.2B
UN0364
II
1.2B
None
62
None
Forbidden
Forbidden
11
Detonators for ammunition
1.4B
UN0365
II
1.4B
103
None
62
None
Forbidden
75 kg
06
Detonators for ammunition
1.4S
UN0366
II
1.4S
None
62
None
25 kg
100 kg
05
Detonators, non-electric,
for blasting
1.1B
UN0029
II
1.1B
None
62
None
Forbidden
Forbidden
11
Detonators, non-electric,
for blasting
1.4B
UN0267
II
1.4B
103
63(f), 63(g)
62
None
Forbidden
75 kg
06
Detonators, non-electric,
for blasting
1.4S
UN0455
II
1.4S
63(f), 63(g)
62
None
25 kg
100 kg
5
Deuterium, compressed
2.1
UN1957
2.1
306
302
None
Forbidden
150 kg
E
40
Devices, small, hydrocarbon gas powered
or
Hydrocarbon gas refills for small devices
with release device
2.1
UN3150
2.1
306
304
None
Forbidden
150 kg
B
40
Di-n-amylamine
3
UN2841
III
3, 6.1
B1, IB3, T4, TP1
150
203
242
60 L
220 L
A
Di-n-butyl peroxydicarbonate, with more than 52 percent in solution
Forbidden
Di-n-butylamine
8
UN2248
II
8, 3
IB2, T7, TP2
None
202
243
1 L
30 L
A
2,2-Di-(tert-butylperoxy) butane, with more than 55 percent in solution
Forbidden
Di-(tert-butylperoxy) phthalate, with more than 55 percent in solution
Forbidden
2,2-Di-(4,4-di-tert-butylperoxycyclohexyl) propane, with more than 42 percent with inert solid
Forbidden
Di-2,4-dichlorobenzoyl peroxide, with more than 75 percent with water
Forbidden
1,2-Di-(dimethylamino)ethane
3
UN2372
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
B
Di-2-ethylhexyl phosphoric acid, see
Diisooctyl acid phosphate
Di-(1-hydroxytetrazole) (dry)
Forbidden
Di-(1-naphthoyl) peroxide
Forbidden
a,a'-Di-(nitroxy) methylether
Forbidden
Di-(beta-nitroxyethyl) ammonium nitrate
Forbidden
Diacetone alcohol
3
UN1148
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
B
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Diacetone alcohol peroxides, with more than 57 percent in solution with more than 9 percent hydrogen peroxide, less than 26 percent diacetone alcohol and less than 9 percent water; total active oxygen content more than 9 percent by mass
Forbidden
Diacetyl, see
Butanedione
Diacetyl peroxide, solid, or with more than 25 percent in solution
Forbidden
Diallylamine
3
UN2359
II
3, 6.1, 8
IB2, T7, TP1
150
202
243
1 L
5 L
B
21, 40, 100
Diallylether
3
UN2360
II
3, 6.1
IB2, N12, T7, TP1, TP13
150
202
243
1 L
60 L
E
40
4,4'-Diaminodiphenyl methane
6.1
UN2651
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
p-Diazidobenzene
Forbidden
1,2-Diazidoethane
Forbidden
1,1'-Diazoaminonaphthalene
Forbidden
Diazoaminotetrazole (dry)
Forbidden
Diazodinitrophenol (dry)
Forbidden
Diazodinitrophenol, wetted
with not less than 40 percent water or mixture of alcohol and water, by mass
1.1A
UN0074
II
1.1A
111, 117
None
62
None
Forbidden
Forbidden
12
Diazodiphenylmethane
Forbidden
Diazonium nitrates (dry)
Forbidden
Diazonium perchlorates (dry)
Forbidden
1,3-Diazopropane
Forbidden
Dibenzyl peroxydicarbonate, with more than 87 percent with water
Ethylamine, aqueous solution
with not less than 50 percent but not more than 70 percent ethylamine
3
UN2270
II
3, 8
IB2, T7, TP1
150
202
243
1 L
5 L
B
40
N-Ethylaniline
6.1
UN2272
III
6.1
IB3, T4, TP1
153
203
241
60 L
220 L
A
52, 74
2-Ethylaniline
6.1
UN2273
III
6.1
IB3, T4, TP1
153
203
241
60 L
220 L
A
52, 74
Ethylbenzene
3
UN1175
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
B
N-Ethylbenzyltoluidines liquid
6.1
UN2753
III
6.1
IB3, T7, TP1
153
203
241
60 L
220 L
A
2-Ethylbutanol
3
UN2275
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
2-Ethylbutyl acetate
3
UN1177
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
2-Ethylbutyraldehyde
3
UN1178
II
3
B1, IB2, T4, TP1
150
202
242
5 L
60 L
B
Ethyldichloroarsine
6.1
UN1892
I
6.1
2, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP45
None
227
244
Forbidden
Forbidden
D
40
Ethyldichlorosilane
4.3
UN1183
I
4.3, 8, 3
A2, A3, A7, N34, T10, TP2, TP7, TP13
None
201
244
Forbidden
1 L
D
21, 28, 40, 49, 100
Ethylene, acetylene and propylene in mixture, refrigerated liquid
with at least 71.5 percent ethylene with not more than 22.5 percent acetylene and not more than 6 percent propylene
Fire extinguisher charges, expelling, explosive, see
Cartridges, power device
Fire extinguishers
containing compressed or liquefied gas
2.2
UN1044
2.2
18, 110
309
309
None
75 kg
150 kg
A
Firelighters, solid
with flammable liquid
4.1
UN2623
III
4.1
A1, A19
None
213
None
25 kg
100 kg
A
52
Fireworks
1.1G
UN0333
II
1.1G
108
None
62
None
Forbidden
Forbidden
07
Fireworks
1.2G
UN0334
II
1.2G
108
None
62
None
Forbidden
Forbidden
07
Fireworks
1.3G
UN0335
II
1.3G
108
None
62
None
Forbidden
Forbidden
07
Fireworks
1.4G
UN0336
II
1.4G
108
None
62
None
Forbidden
75 kg
06
Fireworks
1.4S
UN0337
II
1.4S
108
None
62
None
25 kg
100 kg
05
First aid kits
9
UN3316
9
15
161
161
None
10 kg
10 kg
A
W
Fish meal, stabilized
or
Fish scrap, stabilized
9
UN2216
III
None
155, IB8, IP3, T1, TP33
155
218
218
No limit
No limit
B
88, 122, 128
Fish meal, unstablized
or
Fish scrap, unstabilized
4.2
UN1374
II
4.2
155, A1, A19, IB8, IP2, IP4, T3, TP33
None
212
241
15 kg
50 kg
B
18, 128
Fissile radioactive materials, see
Radioactive material, fissile, n.o.s.
Flammable compressed gas, see
Compressed
or
Liquefied gas, flammable,
etc
Flammable compressed gas (small receptacles not fitted with a dispersion device, not refillable), see
Receptacles,
etc
Flammable gas in lighters, see
Lighters
or
lighter refills,
cigarettes, containing flammable gas
G
Flammable liquid, toxic, corrosive, n.o.s.
3
UN3286
I
3, 6.1, 8
T14, TP2, TP13, TP27
None
201
243
Forbidden
2.5 L
E
21, 40, 100
II
3, 6.1, 8
IB2, T11, TP2, TP13, TP27
150
202
243
1 L
5 L
B
21, 40, 100
G
Flammable liquids, corrosive, n.o.s.
3
UN2924
I
3, 8
T14, TP2
None
201
243
0.5 L
2.5 L
E
40
II
3, 8
IB2, T11, TP2, TP27
150
202
243
1 L
5 L
B
40
III
3, 8
B1, IB3, T7, TP1, TP28
150
203
242
5 L
60 L
A
40
( printed page 34776)
G
Flammable liquids, n.o.s.
3
UN1993
I
3
T11, TP1, TP27
150
201
243
1 L
30 L
E
II
3
IB2, T7, TP1, TP8, TP28
150
202
242
5 L
60 L
B
III
3
B1, B52, IB3, T4, TP1, TP29
150
203
242
60 L
220 L
A
G
Flammable liquids, toxic, n.o.s.
3
UN1992
I
3, 6.1
T14, TP2, TP13, TP27
None
201
243
Forbidden
30 L
E
40
II
3, 6.1
IB2, T7, TP2, TP13
150
202
243
1 L
60 L
B
40
III
3, 6.1
B1, IB3, T7, TP1, TP28
150
203
242
60 L
220 L
A
G
Flammable solid, corrosive, inorganic, n.o.s.
4.1
UN3180
II
4.1, 8
A1, IB6, IP2, T3, TP33
151
212
242
15 kg
50 kg
D
40
III
4.1, 8
A1, IB6, T1, TP33
151
213
242
25 kg
100 kg
D
40
G
Flammable solid, inorganic, n.o.s.
4.1
UN3178
II
4.1
A1, IB8, IP2, IP4, T3, TP33
151
212
240
15 kg
50 kg
B
III
4.1
A1, IB8, IP3, T1, TP33
151
213
240
25 kg
100 kg
B
G
Flammable solid, organic, molten, n.o.s.
4.1
UN3176
II
4.1
IB1, T3, TP3, TP26
151
212
240
Forbidden
Forbidden
C
III
4.1
IB1, T1, TP3, TP26
151
213
240
Forbidden
Forbidden
C
G
Flammable solid, oxidizing, n.o.s.
4.1
UN3097
II
4.1, 5.1
131
None
214
214
Forbidden
Forbidden
E
40
III
4.1, 5.1
131, T1, TP33
None
214
214
Forbidden
Forbidden
D
40
G
Flammable solid, toxic, inorganic, n.o.s.
4.1
UN3179
II
4.1, 6.1
A1, IB6, IP2, T3, TP33
151
212
242
15 kg
50 kg
B
40
III
4.1, 6.1
A1, IB6, T1, TP33
151
213
242
25 kg
100 kg
B
40
G
Flammable solids, corrosive, organic, n.o.s.
4.1
UN2925
II
4.1, 8
A1, IB6, IP2, T3, TP33
None
212
242
15 kg
50 kg
D
40
III
4.1, 8
A1, IB6, T1, TP33
151
213
242
25 kg
100 kg
D
40
G
Flammable solids, organic, n.o.s.
4.1
UN1325
II
4.1
A1, IB8, IP2, IP4, T3, TP33
151
212
240
15 kg
50 kg
B
III
4.1
A1, IB8, IP3, T1, TP33
151
213
240
25 kg
100 kg
B
G
Flammable solids, toxic, organic, n.o.s.
4.1
UN2926
II
4.1, 6.1
A1, IB6, IP2, T3, TP33
151
212
242
15 kg
50 kg
B
40
III
4.1, 6.1
A1, IB6, T1, TP33
151
213
242
25 kg
100 kg
B
40
Flares, aerial
1.3G
UN0093
II
1.3G
None
62
None
Forbidden
75 kg
07
Flares, aerial
1.4G
UN0403
II
1.4G
None
62
None
Forbidden
75 kg
06
Flares, aerial
1.4S
UN0404
II
1.4S
None
62
None
25 kg
100 kg
05
Flares, aerial
1.1G
UN0420
II
1.1G
None
62
None
Forbidden
Forbidden
07
Flares, aerial
1.2G
UN0421
II
1.2G
None
62
None
Forbidden
Forbidden
07
Flares, airplane, see
Flares, aerial
Flares, signal, see
Cartridges, signal
Flares, surface
1.3G
UN0092
II
1.3G
None
62
None
Forbidden
75 kg
07
Flares, surface
1.1G
UN0418
II
1.1G
None
62
None
Forbidden
Forbidden
07
Flares, surface
1.2G
UN0419
II
1.2G
None
62
None
Forbidden
Forbidden
07
Flares, water-activated, see
Contrivances, water-activated,
etc
Flash powder
1.1G
UN0094
II
1.1G
None
62
None
Forbidden
Forbidden
15
Flash powder
1.3G
UN0305
II
1.3G
None
62
None
Forbidden
Forbidden
15
Flue dusts, poisonous, see
Arsenical dust
Fluoric acid, see
Hydrofluoric acid,
etc
Fluorine, compressed
2.3
UN1045
2.3, 5.1, 8
1
None
302
None
Forbidden
Forbidden
D
40, 89, 90
Fluoroacetic acid
6.1
UN2642
I
6.1
IB7, IP1, T6, TP33
None
211
242
1 kg
15 kg
E
Fluoroanilines
6.1
UN2941
III
6.1
IB3, T4, TP1
153
203
241
60 L
220 L
A
Fluorobenzene
3
UN2387
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
B
( printed page 34777)
Fluoroboric acid
8
UN1775
II
8
A6, A7, B2, B15, IB2, N3, N34, T7, TP2
154
202
242
1 L
30 L
A
Fluorophosphoric acid anhydrous
8
UN1776
II
8
A6, A7, B2, IB2, N3, N34, T8, TP2, TP12
None
202
242
1 L
30 L
A
Fluorosilicates, n.o.s.
6.1
UN2856
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
52
Fluorosilicic acid
8
UN1778
II
8
A6, A7, B2, B15, IB2, N3, N34, T8, TP2, TP12
None
202
242
1 L
30 L
A
Fluorosulfonic acid
8
UN1777
I
8
A3, A6, A7, A10, B6, B10, N3, N36, T10, TP2, TP12
None
201
243
0.5 L
2.5 L
D
40
Fluorotoluenes
3
UN2388
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
B
40
Forbidden materials. See § 173.21
Forbidden
Formaldehyde, solutions, flammable
3
UN1198
III
3, 8
B1, IB3, T4, TP1
150
203
242
5 L
60 L
A
40
Formaldehyde, solutions,
with not less than 25 percent formaldehyde
8
UN2209
III
8
IB3, T4, TP1
154
203
241
5 L
60 L
A
Formalin, see
Formaldehyde, solutions
Formic acid
8
UN1779
II
8
B2, B28, IB2, T7, TP2
154
202
242
1 L
30 L
A
40
Fracturing devices, explosive,
without detonators for oil wells
1.1D
UN0099
II
1.1D
None
62
None
Forbidden
Forbidden
07
Fuel, aviation, turbine engine
3
UN1863
I
3
144, T11, TP1, TP8, TP28
150
201
243
1 L
30 L
E
II
3
144, IB2, T4, TP1, TP8
150
202
242
5 L
60 L
B
III
3
144, B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
D
Fuel oil
(No. 1, 2, 4, 5, or 6)
3
NA1993
III
3
144, B1, IB3, T4, TP1, TP29
150
203
242
60 L
220 L
A
Fuel system components (including fuel control units (FCU), carburetors, fuel lines, fuel pumps) see
Dangerous Goods in Apparatus
or
Dangerous Goods in Machinery
Fulminate of mercury (dry)
Forbidden
Fulminate of mercury, wet, see
Mercury fulminate,
etc
Fulminating gold
Forbidden
Fulminating mercury
Forbidden
Fulminating platinum
Forbidden
Fulminating silver
Forbidden
Fulminic acid
Forbidden
Fumaryl chloride
8
UN1780
II
8
B2, IB2, T7, TP2
154
202
242
1 L
30 L
C
8, 40
Fumigated lading, see
§§ 172.302(g), 173.9 and 176.76(h)
Fumigated transport vehicle or freight container see 173.9
Furaldehydes
6.1
UN1199
II
6.1, 3
IB2, T7, TP2
153
202
243
5 L
60 L
A
Furan
3
UN2389
I
3
T12, TP2, TP13
None
201
243
1 L
30 L
E
40
Furfuryl alcohol
6.1
UN2874
III
6.1
IB3, T4, TP1
153
203
241
60 L
220 L
A
52, 74
Furfurylamine
3
UN2526
III
3, 8
B1, IB3, T4, TP1
150
203
242
5 L
60 L
A
40
Fuse, detonating,
metal clad, see
Cord, detonating,
metal clad
Fuse, detonating, mild effect,
metal clad, see
Cord, detonating, mild effect,
metal clad
Fuse, igniter
tubular metal clad
1.4G
UN0103
II
1.4G
None
62
None
Forbidden
75 kg
06
Fuse, non-detonating
instantaneous or quickmatch
1.3G
UN0101
II
1.3G
None
62
None
Forbidden
Forbidden
07
Fuse, safety
1.4S
UN0105
II
1.4S
None
62
None
25 kg
100 kg
05
D
Fusee (
railway or highway)
4.1
NA1325
II
4.1
None
184
None
15 kg
50 kg
B
Fusel oil
3
UN1201
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
B
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Fuses, tracer, see
Tracers for ammunition
Fuzes, combination, percussion and time, see
Fuzes, detonating
(UN0257, UN0367);
Fuzes, igniting
(UN0317, UN0368)
Fuzes, detonating
1.1B
UN0106
II
1.1B
None
62
None
Forbidden
Forbidden
11
Fuzes, detonating
1.2B
UN0107
II
1.2B
None
62
None
Forbidden
Forbidden
11
Fuzes, detonating
1.4B
UN0257
II
1.4B
116
None
62
None
Forbidden
75 kg
06
Fuzes, detonating
1.4S
UN0367
II
1.4S
116
None
62
None
25 kg
100 kg
05
Fuzes, detonating,
with protective features
1.1D
UN0408
II
1.1D
None
62
None
Forbidden
Forbidden
07
Fuzes, detonating,
with protective features
1.2D
UN0409
II
1.2D
None
62
None
Forbidden
Forbidden
07
Fuzes, detonating,
with protective features
1.4D
UN0410
II
1.4D
116
None
62
None
Forbidden
75 kg
06
Fuzes, igniting
1.3G
UN0316
II
1.3G
None
62
None
Forbidden
Forbidden
07
Fuzes, igniting
1.4G
UN0317
II
1.4G
None
62
None
Forbidden
75 kg
06
Fuzes, igniting
1.4S
UN0368
II
1.4S
None
62
None
25 kg
100 kg
05
Galactsan trinitrate
Forbidden
Gallium
8
UN2803
III
8
T1, TP33
None
162
240
20 kg
20 kg
B
48
Gas cartridges,
(flammable) without a release device, non-refillable
2.1
UN2037
2.1
306
304
None
1 kg
15 kg
B
40
Gas generator assemblies (aircraft),
containing a non-flammable non-toxic gas and a propellant cartridge
Gas sample, non-pressurized, flammable, n.o.s.,
not refrigerated liquid
2.1
UN3167
2.1
306
302, 304
None
1 L
5 L
D
Gas sample, non-pressurized, toxic, flammable, n.o.s.,
not refrigerated liquid
2.3
UN3168
2.3, 2.1
6
306
302
None
Forbidden
1 L
D
Gas sample, non-pressurized, toxic, n.o.s.,
not refrigerated liquid
2.3
UN3169
2.3
6
306
302, 304
None
Forbidden
1 L
D
D
Gasohol
gasoline mixed with ethyl alcohol, with not more than 20 percent alcohol
3
NA1203
II
3
144
150
202
242
5 L
60 L
E
Gasoline
3
UN1203
II
3
139, B33, B101, T8
150
202
242
5 L
60 L
E
Gasoline, casinghead, see
Gasoline
Gelatine, blasting, see
Explosive, blasting, type A
Gelatine dynamites, see
Explosive, blasting, type A
Germane
2.3
UN2192
2.3, 2.1
2
None
302
245
Forbidden
Forbidden
D
40
Glycerol-1,3-dinitrate
Forbidden
Glycerol gluconate trinitrate
Forbidden
Glycerol lactate trinitrate
Forbidden
Glycerol alpha-monochlorohydrin
6.1
UN2689
III
6.1
IB3, T4, TP1
153
203
241
60 L
220 L
A
Glyceryl trinitrate, see
Nitroglycerin,
etc
Glycidaldehyde
3
UN2622
II
3, 6.1
IB2, IP8, T7, TP1
150
202
243
1 L
60 L
A
40
Grenades,
hand or rifle, with bursting charge
1.1D
UN0284
II
1.1D
62
None
Forbidden
Forbidden
07
Grenades,
hand or rifle, with bursting charge
1.2D
UN0285
II
1.2D
62
None
Forbidden
Forbidden
07
Grenades,
hand or rifle, with bursting charge
1.1F
UN0292
II
1.1F
62
None
Forbidden
Forbidden
08
Grenades,
hand or rifle, with bursting charge
1.2F
UN0293
II
1.2F
62
None
Forbidden
Forbidden
08
Grenades, illuminating, see
Ammunition, illuminating,
etc
Grenades, practice,
hand or rifle
1.4S
UN0110
II
1.4S
62
None
25 kg
100 kg
05
Grenades, practice,
hand or rifle
1.3G
UN0318
II
1.3G
62
None
Forbidden
Forbidden
07
Grenades, practice,
hand or rifle
1.2G
UN0372
II
1.2G
62
None
Forbidden
Forbidden
07
Grenades practice
Hand or rifle
1.4G
UN0452
II
1.4G
62
None
Forbidden
75 kg
06
Grenades, smoke, see
Ammunition, smoke,
etc
Guanidine nitrate
5.1
UN1467
III
5.1
A1, IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
73
Guanyl nitrosaminoguanylidene hydrazine (dry)
Forbidden
Guanyl nitrosaminoguanylidene hydrazine, wetted
with not less than 30 percent water, by mass
1.1A
UN0113
II
1.1A
111, 117
None
62
None
Forbidden
Forbidden
12
Guanyl nitrosaminoguanyltetrazene (dry)
Forbidden
Guanyl nitrosaminoguanyltetrazene, wetted
or
Tetrazene, wetted
with not less than 30 percent water or mixture of alcohol and water, by mass
1.1A
UN0114
II
1.1A
111, 117
None
62
None
Forbidden
Forbidden
12
Gunpowder, compressed
or
Gunpowder in pellets,
see
Black powder
(UN 0028)
Gunpowder,
granular or as a meal, see
Black powder
(UN 0027)
Hafnium powder, dry
4.2
UN2545
I
4.2
None
211
242
Forbidden
Forbidden
D
II
4.2
A19, A20, IB6, IP2, N34, T3, TP33
None
212
241
15 kg
50 kg
D
III
4.2
IB8, IP3, T1, TP33
None
213
241
25 kg
100 kg
D
Hafnium powder, wetted
with not less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns
4.1
UN1326
II
4.1
A6, A19, A20, IB6, IP2, N34, T3, TP33
None
212
241
15 kg
50 kg
E
74
Hand signal device, see
Signal devices, hand
Hazardous substances, liquid or solid, n.o.s., see
Environmentally hazardous substances,
etc
D G
Hazardous waste, liquid, n.o.s.
9
NA3082
III
9
IB3, T2, TP1
155
203
241
No limit
No limit
A
D G
Hazardous waste, solid, n.o.s.
9
NA3077
III
9
B54, IB8, IP2, T1, TP33
155
213
240
No limit
No limit
A
Heating oil, light
3
UN1202
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Helium, compressed
2.2
UN1046
2.2
306
302
302, 314
75 kg
150 kg
A
85
Helium-oxygen mixture, see
Rare gases and oxygen mixtures
Isocyanates, flammable, toxic, n.o.s.
or
Isocyanate solutions, flammable, toxic, n.o.s.
flash point less than 23 degrees C
3
UN2478
II
3, 6.1
5, A3, A7, IB2, T11, TP2, TP13, TP27
150
202
243
1 L
60 L
D
40
III
3, 6.1
5, A3, A7, IB3, T7, TP1, TP13, TP28
150
203
242
60 L
220 L
A
G
Isocyanates, toxic, flammable, n.o.s.
or
Isocyanate solutions, toxic, flammable, n.o.s.,
flash point not less than 23 degrees C but not more than 61 degrees C and boiling point less than 300 degrees C
6.1
UN3080
II
6.1, 3
IB2, T11, TP2, TP13, TP27
153
202
243
5 L
60 L
B
25, 40, 48
G
Isocyanates, toxic, n.o.s.
or
Isocyanate solutions, toxic, n.o.s.,
flash point more than 61 degrees C and boiling point less than 300 degrees C
Isopropyl phosphoric acid, see
Isopropyl acid phosphate
Isopropyl propionate
3
UN2409
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
B
Isopropylamine
3
UN1221
I
3, 8
T11, TP2
None
201
243
0.5 L
2.5 L
E
Isopropylbenzene
3
UN1918
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Isopropylcumyl hydroperoxide, with more than 72 percent in solution
Forbidden
Isosorbide dinitrate mixture
with not less than 60 percent lactose, mannose, starch or calcium hydrogen phosphate
4.1
UN2907
II
4.1
IB6, IP2, N85
None
212
None
15 kg
50 kg
E
28, 36
Isosorbide-5-mononitrate
4.1
UN3251
III
4.1
66, IB8
151
213
240
Forbidden
Forbidden
D
12
Isothiocyanic acid
Forbidden
Jet fuel, see
Fuel aviation, turbine engine
D
Jet perforating guns, charged oil well, with detonator
1.1D
NA0124
II
1.1D
55, 56
None
62
None
Forbidden
Forbidden
07
D
Jet perforating guns, charged oil well, with detonator
1.4D
NA0494
II
1.4D
55, 56
None
62
None
Forbidden
Forbidden
06
Jet perforating guns, charged
oil well, without detonator
1.1D
UN0124
II
1.1D
55
None
62
None
Forbidden
Forbidden
07
Jet perforating guns, charged,
oil well, without detonator
1.4D
UN0494
II
1.4D
55, 114
None
62
None
Forbidden
300 kg
06
Jet perforators, see
Charges, shaped,
etc
Jet tappers, without detonator, see
Charges, shaped,
etc
Jet thrust igniters, for rocket motors or Jato, see
Igniters
Jet thrust unit (Jato), see
Rocket motors
Kerosene
3
UN1223
III
3
144, B1, IB3, T2, TP2
150
203
242
60 L
220 L
A
G
Ketones, liquid, n.o.s.
3
UN1224
I
3
T11, TP1, TP8, TP27
None
201
243
1 L
30 L
E
( printed page 34784)
II
3
IB2, T7, TP1, TP8, TP28
150
202
242
5 L
60 L
B
III
3
B1, IB3, T4, TP1, TP29
150
203
242
60 L
220 L
A
Krypton, compressed
2.2
UN1056
2.2
306
302
None
75 kg
150 kg
A
Krypton, refrigerated liquid
(cryogenic liquid)
2.2
UN1970
2.2
T75, TP5
320
None
None
50 kg
500 kg
B
Lacquer base or lacquer chips, nitrocellulose, dry, see
Nitrocellulose,
etc. (UN 2557)
Lacquer base or lacquer chips, plastic, wet with alcohol or solvent, see
Nitrocellulose
(UN2059, UN2555, UN2556, UN2557) or
Paint
etc.(UN1263)
Lead acetate
6.1
UN1616
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
Lead arsenates
6.1
UN1617
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Lead arsenites
6.1
UN1618
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Lead azide (dry)
Forbidden
Lead azide, wetted
with not less than 20 percent water or mixture of alcohol and water, by mass
1.1A
UN0129
II
1.1A
111, 117
None
62
None
Forbidden
Forbidden
12
Lead compounds, soluble, n.o.s.
6.1
UN2291
III
6.1
138, IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
Lead cyanide
6.1
UN1620
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
52
Lead dioxide
5.1
UN1872
III
5.1
A1, IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
Lead dross, see
Lead sulfate,
with more than 3 percent free acid
Lead nitrate
5.1
UN1469
II
5.1, 6.1
IB8, IP2, IP4, T3, TP33
152
212
242
5 kg
25 kg
A
Lead nitroresorcinate (dry)
Forbidden
Lead perchlorate, solid
5.1
UN1470
II
5.1, 6.1
IB6, IP2, T3, TP33
152
212
242
5 kg
25 kg
A
56, 58
Lead perchlorate, solution
5.1
UN3408
III
5.1, 6.1
IB2, T4, TP1
152
203
242
2.5 L
30 L
A
56, 58
II
5.1, 6.1
IB2, T4, TP1
152
202
243
1 L
5 L
A
56, 58
Lead peroxide, see
Lead dioxide
Lead phosphite, dibasic
4.1
UN2989
II
4.1
IB8, IP2, IP4, T3, TP33
None
212
240
5 kg
25 kg
B
34
III
4.1
IB8, IP3, T1, TP33
151
213
240
15 kg
50 kg
B
34
Lead picrate (dry)
Forbidden
Lead styphnate (dry)
Forbidden
Lead styphnate, wetted
or
Lead trinitroresorcinate, wetted
with not less than 20 percent water or mixture of alcohol and water, by mass
1.1A
UN0130
II
1.1A
111, 117
None
62
None
Forbidden
Forbidden
12
Lead sulfate
with more than 3 percent free acid
8
UN1794
II
8
IB8, IP2, IP4, T3, TP33
154
212
240
15 kg
50 kg
A
Lead trinitroresorcinate,
see
Lead styphnate,
etc
Life-saving appliances, not self inflating
containing dangerous goods as equipment
9
UN3072
None
None
219
None
No limit
No limit
A
Life-saving appliances, self inflating
9
UN2990
None
None
219
None
No limit
No limit
A
Lighter replacement cartridges containing liquefied petroleum gases (and similar devices, each not exceeding 65 grams), see
Lighters
or
lighter refills
etc. containing flammable gas
Lighters, fuse
1.4S
UN0131
II
1.4S
None
62
None
25 kg
100 kg
05
Lighters
or
Lighter refills
containing flammable gas
2.1
UN1057
2.1
N10
None
21, 308
None
1 kg
15 kg
B
40
Lime, unslaked, see
Calcium oxide
G
Liquefied gas, flammable, n.o.s.
2.1
UN3161
2.1
T50
306
304
314, 315
Forbidden
150 kg
D
40
G
Liquefied gas, n.o.s.
2.2
UN3163
2.2
T50
306
304
314, 315
75 kg
150 kg
A
G
Liquefied gas, oxidizing, n.o.s.
2.2
UN3157
2.2, 5.1
A14
306
304
314, 315
75 kg
150 kg
D
G I
Liquefied gas, toxic, corrosive, n.o.s.
Inhalation Hazard Zone A
2.3
UN3308
2.3, 8
1
None
192
245
Forbidden
Forbidden
D
40
G I
Liquefied gas, toxic, corrosive, n.o.s.
Inhalation Hazard Zone B
2.3
UN3308
2.3, 8
2, B9, B14
None
304
314, 315
Forbidden
Forbidden
D
40
G I
Liquefied gas, toxic, corrosive, n.o.s.
Inhalation Hazard Zone C
2.3
UN3308
2.3, 8
3, B14
None
304
314, 315
Forbidden
Forbidden
D
40
( printed page 34785)
G I
Liquefied gas, toxic, corrosive, n.o.s.
Inhalation Hazard Zone D
2.3
UN3308
2.3, 8
4
None
304
314, 315
Forbidden
Forbidden
D
40
G I
Liquefied gas, toxic, flammable, corrosive, n.o.s.
Inhalation Hazard Zone A
2.3
UN3309
2.3, 2.1, 8
1
None
192
245
Forbidden
Forbidden
D
17, 40
G I
Liquefied gas toxic, flammable, corrosive, n.o.s.
Inhalation Hazard Zone B
2.3
UN3309
2.3, 2.1, 8
2, B9, B14
None
304
314, 315
Forbidden
Forbidden
D
17, 40
G I
Liquefied gas, toxic, flammable, corrosive, n.o.s.
Inhalation Hazard Zone C
2.3
UN3309
2.3, 2.1, 8
3, B14
None
304
314, 315
Forbidden
Forbidden
D
17, 40
G I
Liquefied gas, toxic, flammable, corrosive, n.o.s.
Inhalation Hazard Zone D
2.3
UN3309
2.3, 2.1, 8
4
None
304
314, 315
Forbidden
Forbidden
D
17, 40
G
Liquefied gas, toxic, flammable, n.o.s.
Inhalation Hazard Zone A
2.3
UN3160
2.3, 2.1
1
None
192
245
Forbidden
Forbidden
D
40
G
Liquefied gas, toxic, flammable, n.o.s.
Inhalation Hazard Zone B
2.3
UN3160
2.3, 2.1
2, B9, B14
None
304
314, 315
Forbidden
Forbidden
D
40
G
Liquefied gas, toxic, flammable, n.o.s.
Inhalation Hazard Zone C
2.3
UN3160
2.3, 2.1
3, B14
None
304
314, 315
Forbidden
Forbidden
D
40
G
Liquefied gas, toxic, flammable, n.o.s.
Inhalation Hazard Zone D
2.3
UN3160
2.3, 2.1
4
None
304
314, 315
Forbidden
Forbidden
D
40
G
Liquefied gas, toxic, n.o.s.
Inhalation Hazard Zone A
2.3
UN3162
2.3
1
None
192
245
Forbidden
Forbidden
D
40
G
Liquefied gas, toxic, n.o.s.
Inhalation Hazard Zone B
2.3
UN3162
2.3
2, B9, B14
None
304
314, 315
Forbidden
Forbidden
D
40
G
Liquefied gas, toxic, n.o.s.
Inhalation Hazard Zone C
2.3
UN3162
2.3
3, B14
None
304
314, 315
Forbidden
Forbidden
D
40
G
Liquefied gas, toxic, n.o.s.
Inhalation Hazard Zone D
2.3
UN3162
2.3
4
None
304
314, 315
Forbidden
Forbidden
D
40
G I
Liquefied gas, toxic, oxidizing, corrosive, n.o.s.
Inhalation Hazard Zone A
2.3
UN3310
2.3, 5.1, 8
1
None
192
245
Forbidden
Forbidden
D
40, 89, 90
G I
Liquefied gas, toxic, oxidizing, corrosive, n.o.s.
Inhalation Hazard Zone B
2.3
UN3310
2.3, 5.1, 8
2, B9, B14
None
304
314, 315
Forbidden
Forbidden
D
40, 89, 90
G I
Liquefied gas, toxic, oxidizing, corrosive, n.o.s.
Inhalation Hazard Zone C
2.3
UN3310
2.3, 5.1, 8
3, B14
None
304
314, 315
Forbidden
Forbidden
D
40, 89, 90
G I
Liquefied gas, toxic, oxidizing, corrosive, n.o.s.
Inhalation Hazard Zone D
2.3
UN3310
2.3, 5.1, 8
4
None
304
314, 315
Forbidden
Forbidden
D
40, 89, 90
G
Liquefied gas, toxic, oxidizing, n.o.s.
Inhalation Hazard Zone A
2.3
UN3307
2.3, 5.1
1
None
192
245
Forbidden
Forbidden
D
40
G
Liquefied gas, toxic, oxidizing, n.o.s.
Inhalation Hazard Zone B
2.3
UN3307
2.3, 5.1
2, B9, B14
None
304
314, 315
Forbidden
Forbidden
D
40
G
Liquefied gas, toxic, oxidizing, n.o.s.
Inhalation Hazard Zone C
2.3
UN3307
2.3, 5.1
3, B14
None
304
314, 315
Forbidden
Forbidden
D
40
G
Liquefied gas, toxic, oxidizing, n.o.s.
Inhalation Hazard Zone D
2.3
UN3307
2.3, 5.1
4
None
304
314, 315
Forbidden
Forbidden
D
40
Liquefied gases,
non-flammable charged with nitrogen, carbon dioxide or air
2.2
UN1058
2.2
306
304
None
75 kg
150 kg
A
Liquefied hydrocarbon gas, see
Hydrocarbon gas mixture, liquefied, n.o.s.
Liquefied natural gas, see
Methane,
etc. (UN 1972)
Liquefied petroleum gas
see
Petroleum gases, liquefied
Lithium
4.3
UN1415
I
4.3
A7, A19, IB4, IP1, N45
None
211
244
Forbidden
15 kg
E
52
Lithium acetylide ethylenediamine complex, see
Water reactive solid
etc
Lithium alkyls, liquid
4.2
UN2445
I
4.2, 4.3
B11, T21, TP2, TP7
None
181
244
Forbidden
Forbidden
D
Lithium alkyls, solid
4.2
UN3433
I
4.2, 4.3
B11, T21, TP7, TP33
None
181
244
Forbidden
Forbidden
D
Lithium aluminum hydride
4.3
UN1410
I
4.3
A19
None
211
242
Forbidden
15 kg
E
52
Lithium aluminum hydride, ethereal
4.3
UN1411
I
4.3, 3
A2, A3, A11, N34
None
201
244
Forbidden
1 L
D
40
Lithium batteries, contained in equipment
9
UN3091
II
9
29, A54, A55
185
185
None
5 kg
5 kg
A
Lithium batteries packed with equipment
9
UN3091
II
9
29, A54, A55
185
185
None
5 kg gross
35 kg gross
A
Lithium battery
9
UN3090
II
9
29, A54, A55
185
185
None
5 kg gross
35 kg gross
A
Lithium borohydride
4.3
UN1413
I
4.3
A19, N40
None
211
242
Forbidden
15 kg
E
52
Lithium ferrosilicon
4.3
UN2830
II
4.3
A19, IB7, IP2, T3, TP33
151
212
241
15 kg
50 kg
E
40, 85, 103
Lithium hydride
4.3
UN1414
I
4.3
A19, N40
None
211
242
Forbidden
15 kg
E
52
Lithium hydride, fused solid
4.3
UN2805
II
4.3
A8, A19, A20, IB4, T3, TP33
151
212
241
15 kg
50 kg
E
52
Lithium hydroxide
8
UN2680
II
8
IB8, IP2, IP4, T3, TP33
154
212
240
15 kg
50 kg
A
Lithium hydroxide, solution
8
UN2679
II
8
B2, IB2, T7, TP2
154
202
242
1 L
30 L
A
29
( printed page 34786)
III
8
IB3, T4, TP2
154
203
241
5 L
60 L
A
29, 96
Lithium hypochlorite, dry
with more than 39% available chlorine (8.8% available oxygen) or
Lithium hypochlorite mixtures, dry
with more than 39% available chlorine (8.8% available oxygen)
5.1
UN1471
II
5.1
A9, IB8, IP2, IP4, N34
152
212
240
5 kg
25 kg
A
4, 48, 52, 56, 58, 69, 106, 116
Lithium in cartridges, see
Lithium
Lithium nitrate
5.1
UN2722
III
5.1
A1, IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
Lithium nitride
4.3
UN2806
I
4.3
A19, IB4, IP1, N40
None
211
242
Forbidden
15 kg
E
Lithium peroxide
5.1
UN1472
II
5.1
A9, IB6, IP2, N34, T3, TP33
152
212
None
5 kg
25 kg
A
13, 52, 66, 75
Lithium silicon
4.3
UN1417
II
4.3
A19, A20, IB7, IP2, T3, TP33
151
212
241
15 kg
50 kg
A
85, 103
LNG, see
Methane
etc. (UN 1972)
London purple
6.1
UN1621
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
LPG, see
Petroleum gases, liquefied
Lye, see
Sodium hydroxide, solutions
Magnesium alkyls
4.2
UN3053
I
4.2, 4.3
B11, T21, TP2, TP7
None
181
244
Forbidden
Forbidden
D
18
Magnesium aluminum phosphide
4.3
UN1419
I
4.3, 6.1
A19, N34, N40
None
211
242
Forbidden
15 kg
E
40, 52, 85
+
Magnesium arsenate
6.1
UN1622
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Magnesium bisulfite solution, see
Bisulfites, aqueous solutions, n.o.s.
Magnesium bromate
5.1
UN1473
II
5.1
A1, IB8, IP4, T3, TP33
152
212
242
5 kg
25 kg
A
56, 58
Magnesium chlorate
5.1
UN2723
II
5.1
IB8, IP2, IP4, T3, TP33
152
212
242
5 kg
25 kg
A
56, 58
Magnesium diamide
4.2
UN2004
II
4.2
A8, A19, A20, IB6, T3, TP33
None
212
241
15 kg
50 kg
C
Magnesium diphenyl
4.2
UN2005
I
4.2
T21, TP7, TP33
None
187
244
Forbidden
Forbidden
C
Magnesium dross, wet or hot
Forbidden
Magnesium fluorosilicate
6.1
UN2853
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
52
Magnesium granules, coated,
particle size not less than 149 microns
4.3
UN2950
III
4.3
A1, A19, IB8, IP4, T1, TP33
151
213
240
25 kg
100 kg
A
52
Magnesium hydride
4.3
UN2010
I
4.3
A19, N40
None
211
242
Forbidden
15 kg
E
52
Magnesium
or
Magnesium alloys
with more than 50 percent magnesium in pellets, turnings or ribbons
4.1
UN1869
III
4.1
A1, IB8, IP3, T1, TP33
151
213
240
25 kg
100 kg
A
39, 52, 53, 74, 101
Magnesium nitrate
5.1
UN1474
III
5.1
A1, IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
Magnesium perchlorate
5.1
UN1475
II
5.1
IB6, IP2, T3, TP33
152
212
242
5 kg
25 kg
A
56, 58
Magnesium peroxide
5.1
UN1476
II
5.1
IB6, IP2, T3, TP33
152
212
242
5 kg
25 kg
A
13, 52, 66, 75
Magnesium phosphide
4.3
UN2011
I
4.3, 6.1
A19, N40
None
211
None
Forbidden
15 kg
E
40, 52, 85
Magnesium, powder
or
Magnesium alloys, powder
4.3
UN1418
I
4.3, 4.2
A19, B56
None
211
244
Forbidden
15 kg
A
39, 52
II
4.3, 4.2
A19, B56, IB5, IP2, T3, TP33
None
212
241
15 kg
50 kg
A
39, 52
III
4.3, 4.2
A19, B56, IB8, IP4, T1, TP33
None
213
241
25 kg
100 kg
A
39, 52
Magnesium scrap, see
Magnesium,
etc. (UN 1869)
Magnesium silicide
4.3
UN2624
II
4.3
A19, A20, IB7, IP2, T3, TP33
151
212
241
15 kg
50 kg
B
85, 103
Magnetized material, see § 173.21
Maleic anhydride
8
UN2215
III
8
IB8, IP3, T1, TP33
154
213
240
25 kg
100 kg
A
Maleic anhydride, molten
8
UN2215
III
8
T4, TP3
None
213
240
Forbidden
Forbidden
A
( printed page 34787)
Malononitrile
6.1
UN2647
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
12
Mancozeb (manganese ethylenebisdithiocarbamate complex with zinc) see
Maneb
Maneb
or
Maneb preparations
with not less than 60 percent maneb
4.2
UN2210
III
4.2, 4.3
57, A1, A19, IB6, T1, TP33
None
213
242
25 kg
100 kg
A
34
Maneb stabilized
or
Maneb preparations, stabilized
against self-heating
4.3
UN2968
III
4.3
54, A1, A19, IB8, IP4, T1, TP33
151
213
242
25 kg
100 kg
B
34, 52
Manganese nitrate
5.1
UN2724
III
5.1
A1, IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
Manganese resinate
4.1
UN1330
III
4.1
A1, IB6, T1, TP33
151
213
240
25 kg
100 kg
A
Mannitan tetranitrate
Forbidden
Mannitol hexanitrate (dry)
Forbidden
Mannitol hexanitrate, wetted
or
Nitromannite, wetted
with not less than 40 percent water, or mixture of alcohol and water, by mass
1.1D
UN0133
II
1.1D
121
None
62
None
Forbidden
Forbidden
10
Marine pollutants, liquid or solid, n.o.s., see
Environmentally hazardous substances, liquid
or
solid, n.o.s.
Matches, block, see
Matches, 'strike anywhere'
Matches, fusee
4.1
UN2254
III
4.1
186
186
None
Forbidden
Forbidden
A
Matches, safety
(book, card or strike on box)
4.1
UN1944
III
4.1
186
186
None
25 kg
100 kg
A
Matches, strike anywhere
4.1
UN1331
III
4.1
186
186
None
Forbidden
Forbidden
B
Matches, wax, Vesta
4.1
UN1945
III
4.1
186
186
None
25 kg
100 kg
B
Matting acid, see
Sulfuric acid
Medicine, liquid, flammable, toxic, n.o.s.
3
UN3248
II
3, 6.1
36, IB2
150
202
None
1 L
5 L
B
40
III
3, 6.1
36, IB3
150
203
None
5 L
5 L
A
Medicine, liquid, toxic, n.o.s.
6.1
UN1851
II
6.1
36
153
202
243
5 L
5 L
C
40
III
6.1
36
153
203
241
5 L
5 L
C
40
Medicine, solid, toxic, n.o.s.
6.1
UN3249
II
6.1
36, T3, TP33
153
212
None
5 kg
5 kg
C
40
III
6.1
36, T1, TP33
153
213
None
5 kg
5 kg
C
40
Memtetrahydrophthalic anhydride, see
Corrosive liquids, n.o.s.
Mercaptans, liquid, flammable, n.o.s.
or
Mercaptan mixture, liquid, flammable, n.o.s.
Mine rescue equipment containing carbon dioxide, see
Carbon dioxide
Mines
with bursting charge
1.1F
UN0136
II
1.1F
62
None
Forbidden
Forbidden
08
Mines
with bursting charge
1.1D
UN0137
II
1.1D
62
None
Forbidden
Forbidden
03
Mines
with bursting charge
1.2D
UN0138
II
1.2D
62
None
Forbidden
Forbidden
03
Mines
with bursting charge
1.2F
UN0294
II
1.2F
62
None
Forbidden
Forbidden
08
Mixed acid, see
Nitrating acid, mixtures
etc
Mobility aids, see
Battery powered equipment
or
Battery powered vehicle'
D
Model rocket motor
1.4C
NA0276
II
1.4C
51
None
62
None
Forbidden
75 kg
06
D
Model rocket motor
1.4S
NA0323
II
1.4S
51
None
62
None
25 kg
100 kg
05
Molybdenum pentachloride
8
UN2508
III
8
IB8, IP3, T1, TP33
154
213
240
25 kg
100 kg
C
40
Monochloroacetone (unstabilized)
Forbidden
Monochloroethylene, see
Vinyl chloride, stabilized
Monoethanolamine, see
Ethanolamine, solutions
Monoethylamine, see
Ethylamine
Morpholine
8
UN2054
I
8, 3
A6, T10, TP2
None
201
243
0.5 L
2.5 L
A
Morpholine, aqueous, mixture, see
Corrosive liquids, n.o.s.
Motor fuel anti-knock compounds
see
Motor fuel anti-knock mixtures
+
Motor fuel anti-knock mixtures
6.1
UN1649
I
6.1, 3
14, 151, B9, B90, T14, TP2, TP13
None
201
244
Forbidden
30 L
D
25, 40
Motor spirit,
see
Gasoline
Muriatic acid, see
Hydrochloric acid
Musk xylene,
see
5-tert-Butyl-2,4,6-trinitro-m-xylene
Naphtha see
Petroleum distillates n.o.s.
Naphthalene, crude
or
Naphthalene, refined
4.1
UN1334
III
4.1
A1, IB8, IP3, T1, TP33
151
213
240
25 kg
100 kg
A
Naphthalene diozonide
Forbidden
beta-Naphthylamine
6.1
UN1650
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
beta-Naphthylamine, solid
6.1
UN1650
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
beta-Naphthylamine solution
6.1
UN3411
II
6.1
IB2, T7, TP2
153
202
243
5 L
60 L
A
III
6.1
IB2, T7, TP2
153
203
241
60 L
220 L
A
alpha-Naphthylamine
6.1
UN2077
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
Naphthalene, molten
4.1
UN2304
III
4.1
IB1, T1, TP3
151
213
241
Forbidden
Forbidden
C
Naphthylamineperchlorate
Forbidden
Naphthylthiourea
6.1
UN1651
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Naphthylurea
6.1
UN1652
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Natural gases (with high methane content), see
Methane,
etc. (UN 1971, UN 1972)
Neohexane, see
Hexanes
Neon, compressed
2.2
UN1065
2.2
306
302
302
75 kg
150 kg
A
Neon, refrigerated liquid
(cryogenic liquid)
2.2
UN1913
2.2
T75, TP5
320
316
None
50 kg
500 kg
B
New explosive or explosive device, see §§ 173.51 and 173.56
Nickel carbonyl
6.1
UN1259
I
6.1, 3
1
None
198
None
Forbidden
Forbidden
D
18, 40
Nickel cyanide
6.1
UN1653
II
6.1
IB8, IP2, IP4, N74, N75, T3, TP33
153
212
242
25 kg
100 kg
A
52
Nickel nitrate
5.1
UN2725
III
5.1
A1, IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
Nickel nitrite
5.1
UN2726
III
5.1
A1, IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
56, 58
Nickel picrate
Forbidden
Nicotine
6.1
UN1654
II
6.1
IB2
153
202
243
5 L
60 L
A
( printed page 34793)
Nicotine compounds, liquid, n.o.s.
or
Nicotine preparations, liquid, n.o.s.
6.1
UN3144
I
6.1
A4
None
201
243
1 L
30 L
B
40
II
6.1
IB2, T11, TP2, TP27
153
202
243
5 L
60 L
B
40
III
6.1
IB3, T7, TP1, TP28
153
203
241
60 L
220 L
B
40
Nicotine compounds, solid, n.o.s.
or
Nicotine preparations, solid, n.o.s.
6.1
UN1655
I
6.1
IB7, IP1, T6, TP33
None
211
242
5 kg
50 kg
B
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
Nicotine hydrochloride liquid
or
solution
6.1
UN1656
II
6.1
IB2
153
202
243
5 L
60 L
A
III
6.1
IB3
153
203
241
60 L
220 L
A
Nicotine hydrochloride, solid
6.1
UN3444
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Nicotine salicylate
6.1
UN1657
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Nicotine sulfate solution
6.1
UN1658
II
6.1
IB2, T7, TP2
153
202
243
5 L
60 L
A
III
6.1
IB3, T7, TP2
153
203
241
60 L
220 L
A
Nicotine sulphate, solid
6.1
UN3445
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Nicotine tartrate
6.1
UN1659
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Nitrated paper (unstable)
Forbidden
Nitrates, inorganic, aqueous solution, n.o.s.
5.1
UN3218
II
5.1
58, IB2, T4, TP1
152
202
242
1 L
5 L
B
56, 58, 133
III
5.1
58, IB2, T4, TP1
152
203
241
2.5 L
30 L
B
56, 58, 133
Nitrates, inorganic, n.o.s.
5.1
UN1477
II
5.1
IB8, IP2, IP4, T3, TP33
152
212
240
5 kg
25 kg
A
56, 58
III
5.1
IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
56, 58
Nitrates of diazonium compounds
Forbidden
Nitrating acid mixtures, spent
with more than 50 percent nitric acid
8
UN1826
I
8, 5.1
A7, T10, TP2, TP12, TP13
None
158
243
Forbidden
2.5 L
D
40, 66
Nitrating acid mixtures spent
with not more than 50 percent nitric acid
8
UN1826
II
8
A7, B2, IB2, T8, TP2, TP12
None
158
242
Forbidden
30 L
D
40
Nitrating acid mixtures
with more than 50 percent nitric acid
8
UN1796
I
8, 5.1
A7, T10, TP2, TP12, TP13
None
158
243
Forbidden
2.5 L
D
40, 66
Nitrating acid mixtures
with not more than 50 percent nitric acid
8
UN1796
II
8
A7, B2, IB2, T8, TP2, TP12, TP13
None
158
242
Forbidden
30 L
D
40
Nitric acid
other than red fuming, with more than 70 percent nitric acid
8
UN2031
I
8, 5.1
A3, B47, B53, T10, TP2, TP12, TP13
None
158
243
Forbidden
2.5 L
D
44, 66, 89, 90, 110, 111
Nitric acid
other than red fuming, with not more than 70 percent nitric acid
8
UN2031
II
8
A6, B2, B47, B53, IB2, T8, TP2, TP12
None
158
242
Forbidden
30 L
D
44, 66, 89, 90, 110, 111
+
Nitric acid, red fuming
8
UN2032
I
8, 5.1, 6.1
2, B9, B32, B74, T20, TP2, TP12, TP13, TP38, TP45
None
227
244
Forbidden
Forbidden
D
40, 66, 74, 89, 90
Nitric oxide, compressed
2.3
UN1660
2.3, 5.1, 8
1, B37, B46, B50, B60, B77
None
337
None
Forbidden
Forbidden
D
40, 89, 90
Nitric oxide and dinitrogen tetroxide mixtures
or
Nitric oxide and nitrogen dioxide mixtures
2.3
UN1975
2.3, 5.1, 8
1, B7, B9, B14, B45, B46, B61, B66, B67, B77
None
337
None
Forbidden
Forbidden
D
40, 89, 90
G
Nitriles, flammable, toxic, n.o.s.
3
UN3273
I
3, 6.1
T14, TP2, TP13, TP27
None
201
243
Forbidden
30 L
E
40, 52
II
3, 6.1
IB2, T11, TP2, TP13, TP27
150
202
243
1 L
60 L
B
40, 52
G
Nitriles, toxic, flammable, n.o.s.
6.1
UN3275
I
6.1, 3
5, T14, TP2, TP13, TP27
None
201
243
1 L
30 L
B
40, 52
II
6.1, 3
IB2, T11, TP2, TP13, TP27
153
202
243
5 L
60 L
B
40, 52
G
Nitriles, toxic, liquid, n.o.s.
6.1
UN3276
I
6.1
5, T14, TP2, TP13, TP27
None
201
243
1 L
30 L
B
52
G
Nitriles, toxic, solid, n.o.s.
6.1
UN3439
I
6.1
IB7, IP1, T6, TP33
None
211
242
5 kg
50 kg
D
52
G
Nitriles, toxic, liquid, n.o.s.
6.1
UN3276
II
6.1
IB2, T11, TP2, TP27
153
202
243
5 L
60 L
B
52
G
Nitriles, toxic, solid, n.o.s.
6.1
UN3439
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
B
52
( printed page 34794)
G
Nitriles, toxic, liquid, n.o.s.
6.1
UN3276
III
6.1
IB3, T7, TP1, TP28
153
203
241
60 L
220 L
A
52
G
Nitriles, toxic, solid, n.o.s.
6.1
UN3439
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
52
Nitrites, inorganic, aqueous solution, n.o.s.
5.1
UN3219
II
5.1
IB1, T4, TP1
152
202
242
1 L
5 L
B
46, 56, 58, 133
III
5.1
IB2, T4, TP1
152
203
241
2.5 L
30 L
B
46, 56, 58, 133
Nitrites, inorganic, n.o.s.
5.1
UN2627
II
5.1
33, IB8, IP4, T3, TP33
152
212
None
5 kg
25 kg
A
46, 56, 58, 133
3-Nitro-4-chlorobenzotrifluoride
6.1
UN2307
II
6.1
IB2, T7, TP2
153
202
243
5 L
60 L
A
40
6-Nitro-4-diazotoluene-3-sulfonic acid (dry)
Forbidden
Nitro isobutane triol trinitrate
Forbidden
N-Nitro-N-methylglycolamide nitrate
Forbidden
2-Nitro-2-methylpropanol nitrate
Forbidden
Nitro urea
1.1D
UN0147
II
1.1D
None
62
None
Forbidden
Forbidden
10
N-Nitroaniline
Forbidden
+
Nitroanilines (
o-; m-; p-;)
6.1
UN1661
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Nitroanisole, liquid
6.1
UN2730
III
6.1
IB3, T4, TP1
153
203
241
60 L
220 L
A
Nitroanisoles, solid
6.1
UN3458
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
+
Nitrobenzene
6.1
UN1662
II
6.1
IB2, T7, TP2
153
202
243
5 L
60 L
A
40
m-Nitrobenzene diazonium perchlorate
Forbidden
Nitrobenzenesulfonic acid
8
UN2305
II
8
B2, B4, IB8, IP2, IP4, T3, TP33
154
202
242
1 L
30 L
A
Nitrobenzol, see
Nitrobenzene
5-Nitrobenzotriazol
1.1D
UN0385
II
1.1D
None
62
None
Forbidden
Forbidden
10
Nitrobenzotrifluorides, liquid
6.1
UN2306
II
6.1
IB2, T7, TP2
153
202
243
5 L
60 L
A
40
Nitrobenzotrifluorides, solid
6.1
UN3431
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
40
Nitrobromobenzenes, liquid
6.1
UN2732
III
6.1
IB3, T4, TP1
153
203
241
60 L
220 L
A
Nitrobromobenzenes, solid
6.1
UN3459
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
Nitrocellulose,
dry or wetted with less than 25 percent water (or alcohol), by mass
1.1D
UN0340
II
1.1D
None
62
None
Forbidden
Forbidden
13
27E
Nitrocellulose membrane filters,
with not more than 12.6% nitrogen, by dry mass
4.1
UN3270
II
4.1
43, A1
151
212
240
1 kg
15 kg
D
Nitrocellulose, plasticized
with not less than 18 percent plasticizing substance, by mass
1.3C
UN0343
II
1.3C
None
62
None
Forbidden
Forbidden
10
Nitrocellulose, solution, flammable
with not more than 12.6 percent nitrogen, by mass, and not more than 55 percent nitrocellulose
3
UN2059
I
3
T11, TP1, TP8, TP27
None
201
243
1 L
30 L
E
II
3
IB2, T4, TP1, TP8
150
202
242
5 L
60 L
B
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Nitrocellulose,
unmodified or plasticized with less than 18 percent plasticizing substance, by mass
1.1D
UN0341
II
1.1D
None
62
None
Forbidden
Forbidden
13
27E
Nitrocellulose, wetted
with not less than 25 percent alcohol, by mass
1.3C
UN0342
II
1.3C
None
62
None
Forbidden
Forbidden
10
Nitrocellulose with alcohol
with not less than 25 percent alcohol by mass, and with not more than 12.6 percent nitrogen, by dry mass
4.1
UN2556
II
4.1
151
212
None
1 kg
15 kg
D
28
Nitrocellulose,
with not more than 12.6 percent nitrogen, by dry mass, or
Nitrocellulose mixture with pigment
or
Nitrocellulose mixture with plasticizer
or
Nitrocellulose mixture with pigment and plasticizer
4.1
UN2557
II
4.1
44
151
212
None
1 kg
15 kg
D
28
Nitrocellulose with water
with not less than 25 percent water, by mass
4.1
UN2555
II
4.1
151
212
None
15 kg
50 kg
E
28
Nitrochlorobenzene, see
Chloronitrobenzenes
etc
Nitrocresols, solid
6.1
UN2446
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
Nitrocresols, liquid
6.1
UN3434
III
6.1
IB3, T4, TP1
153
203
241
60 L
220 L
A
Nitroethane
3
UN2842
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Nitroethyl nitrate
Forbidden
Nitroethylene polymer
Forbidden
Nitrogen, compressed
2.2
UN1066
2.2
306
302
314, 315
75 kg
150 kg
A
Nitrogen dioxide,
see
Dinitrogen tetroxide
Nitrogen fertilizer solution, see
Fertilizer ammoniating solution
etc
Nitrogen, mixtures with rare gases, see
Rare gases and nitrogen mixtures
Nitrogen peroxide, seeDinitrogen tetroxide
Nitrogen, refrigerated liquid
cryogenic liquid
2.2
UN1977
2.2
T75, TP5
320
316
318
50 kg
500 kg
D
( printed page 34795)
Nitrogen tetroxide and nitric oxide mixtures, see
Nitric oxide and nitrogen tetroxide mixtures
Nitrogen tetroxide, see
Dinitrogen tetroxide
Nitrogen trichloride
Forbidden
Nitrogen trifluoride
2.2
UN2451
2.2, 5.1
None
302
None
75 kg
150 kg
D
40
Nitrogen triiodide
Forbidden
Nitrogen triiodide monoamine
Forbidden
Nitrogen trioxide
2.3
UN2421
2.3, 5.1, 8
1
None
336
245
Forbidden
Forbidden
D
40, 89, 90
Nitroglycerin, desensitized
with not less than 40 percent non-volatile water insoluble phlegmatizer, by mass
1.1D
UN0143
II
1.1D, 6.1
125
None
62
None
Forbidden
Forbidden
13
21E
Nitroglycerin, liquid, not desensitized
Forbidden
Nitroglycerin mixture, desensitized, liquid, flammable, n.o.s.
with not more than 30 percent nitroglycerin, by mass
3
UN3343
3
129
None
214
None
Forbidden
Forbidden
D
Nitroglycerin mixture, desensitized, liquid, n.o.s.
with not more than 30% nitroglycerin, by mass
3
UN3357
II
3
142
None
202
243
5 L
60 L
E
Nitroglycerin mixture, desensitized, solid, n.o.s.
with more than 2 percent but not more than 10 percent nitroglycerin, by mass
4.1
UN3319
II
4.1
118
None
None
None
Forbidden
0.5 kg
E
Nitroglycerin, solution in alcohol,
with more than 1 percent but not more than 5 percent nitroglycerin
3
UN3064
II
3
N8
None
202
None
Forbidden
5 L
E
Nitroglycerin, solution in alcohol,
with more than 1 percent but not more than 10 percent nitrogylcerin
1.1D
UN0144
II
1.1D
None
62
None
Forbidden
Forbidden
10
21E
Nitroglycerin solution in alcohol
with not more than 1 percent nitroglycerin
3
UN1204
II
3
IB2, N34
150
202
None
5 L
60 L
B
Nitroguanidine nitrate
Forbidden
Nitroguanidine
or
Picrite,
dry or wetted with less than 20 percent water, by mass
1.1D
UN0282
II
1.1D
None
62
None
Forbidden
Forbidden
10
Nitroguanidine, wetted
or
Picrite, wetted
with not less than 20 percent water, by mass
4.1
UN1336
I
4.1
23, A8, A19, A20, N41
None
211
None
1 kg
15 kg
E
28
1-Nitrohydantoin
Forbidden
Nitrohydrochloric acid
8
UN1798
I
8
A3, B10, N41, T10, TP2, TP12, TP13
None
201
243
Forbidden
2.5 L
D
40, 66, 74, 89, 90
Nitromannite (dry)
Forbidden
Nitromannite, wetted,
see
Mannitol hexanitrate,
etc
Nitromethane
3
UN1261
II
3
150
202
None
Forbidden
60 L
A
Nitromuriatic acid, see
Nitrohydrochloric acid
Nitronaphthalene
4.1
UN2538
III
4.1
A1, IB8, IP3, T1, TP33
151
213
240
25 kg
100 kg
A
4-Nitrophenylhydrazine,
with not less than 30% water, by mass
4.1
UN3376
I
4.1
164, A8, A19, A20, N41
None
211
None
Forbidden
15 kg
E
36
+
Nitrophenols (
o-; m-; p-;)
6.1
UN1663
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
m-Nitrophenyldinitro methane
Forbidden
Nitropropanes
3
UN2608
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
p-Nitrosodimethylaniline
4.2
UN1369
II
4.2
A19, A20, IB6, IP2, N34, T3, TP33
None
212
241
15 kg
50 kg
D
34
Nitrostarch,
dry or wetted with less than 20 percent water, by mass
1.1D
UN0146
II
1.1D
None
62
None
Forbidden
Forbidden
10
Nitrostarch, wetted
with not less than 20 percent water, by mass
4.1
UN1337
I
4.1
23, A8, A19, A20, N41
None
211
None
1 kg
15 kg
D
28
Nitrosugars (dry)
Forbidden
Nitrosyl chloride
2.3
UN1069
2.3, 8
3, B14
None
304
314, 315
Forbidden
Forbidden
D
40
Nitrosylsulfuric acid, liquid
8
UN2308
II
8
A3, A6, A7, B2, IB2, N34, T8, TP2, TP12
154
202
242
1 L
30 L
D
40, 66, 74, 89, 90
Nitrosylsulphuric acid, solid
8
UN3456
II
8
IB8, IP2, IP4, T3, TP33
154
212
240
15 kg
50 kg
D
40, 66, 74, 89, 90
Nitrotoluenes, liquid
6.1
UN1664
II
6.1
IB2, T7, TP2
153
202
243
5 L
60 L
A
Nitrotoluenes, solid
6.1
UN3446
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Nitrotoluidines (mono)
6.1
UN2660
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
Nitrotriazolone
or
NTO
1.1D
UN0490
II
1.1D
None
62
None
Forbidden
Forbidden
10
Nitrous oxide and carbon dioxide mixtures, see
Carbon dioxide and nitrous oxide mixtures
Nitrous oxide
2.2
UN1070
2.2, 5.1
A14
306
304
314, 315
75 kg
150 kg
A
40
Nitrous oxide, refrigerated liquid
2.2
UN2201
2.2, 5.1
B6, T75, TP5, TP22
None
304
314, 315
Forbidden
Forbidden
B
40
Nitroxylenes, liquid
6.1
UN1665
II
6.1
IB2, T7, TP2
153
202
243
5 L
60 L
A
Nitroxylenes, solid
6.1
UN3447
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Nitroxylol, see
Nitroxylenes
Nonanes
3
UN1920
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Non-flammable gas, n.o.s., see
Compressed gas,
etc. or
Liquefied gas,
etc
( printed page 34796)
Nonliquefied gases, see
Compressed gases,
etc
Nonliquefied hydrocarbon gas, see
Hydrocarbon gas mixture, compressed, n.o.s.
Nonyltrichlorosilane
8
UN1799
II
8
A7, B2, B6, IB2, N34, T7, TP2, TP13
None
202
242
Forbidden
30 L
C
40
Nordhausen acid, see
Sulfuric acid, fuming
etc
2,5-Norbornadiene, stabilized,
see
Bicyclo
2,2,1
hepta-2,5-diene, stabilized
Octogen,
etc. see
Cyclotetramethylene tetranitramine,
etc.
Octolite
or
Octol,
dry or wetted with less than 15 percent water, by mass
1.1D
UN0266
II
1.1D
None
62
None
Forbidden
Forbidden
10
Octonal
1.1D
UN0496
1.1D
None
62
None
Forbidden
Forbidden
10
Octyl aldehydes
3
UN1191
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Octyltrichlorosilane
8
UN1801
II
8
A7, B2, B6, IB2, N34, T7, TP2, TP13
None
202
242
Forbidden
30 L
C
40
Oil gas, compressed
2.3
UN1071
2.3, 2.1
6
None
304
314, 315
Forbidden
25 kg
D
40
Oleum, see
Sulfuric acid, fuming
Organic peroxide type A, liquid or solid
Forbidden
G
Organic peroxide type B, liquid
5.2
UN3101
II
5.2, 1
53
152
225
None
Forbidden
Forbidden
D
12, 40, 52, 53
G
Organic peroxide type B, liquid, temperature controlled
5.2
UN3111
II
5.2, 1
53
None
225
None
Forbidden
Forbidden
D
2, 40, 52, 53
G
Organic peroxide type B, solid
5.2
UN3102
II
5.2, 1
53
152
225
None
Forbidden
Forbidden
D
12, 40, 52, 53
G
Organic peroxide type B, solid, temperature controlled
5.2
UN3112
II
5.2, 1
53
None
225
None
Forbidden
Forbidden
D
2, 40, 52, 53
G
Organic peroxide type C, liquid
5.2
UN3103
II
5.2
152
225
None
5 L
10 L
D
12, 40, 52, 53
G
Organic peroxide type C, liquid, temperature controlled
5.2
UN3113
II
5.2
None
225
None
Forbidden
Forbidden
D
2, 40, 52, 53
G
Organic peroxide type C, solid
5.2
UN3104
II
5.2
152
225
None
5 kg
10 kg
D
12, 40, 52, 53
G
Organic peroxide type C, solid, temperature controlled
5.2
UN3114
II
5.2
None
225
None
Forbidden
Forbidden
D
2, 40, 52, 53
G
Organic peroxide type D, liquid
5.2
UN3105
II
5.2
152
225
None
5 L
10 L
D
12, 40, 52, 53
G
Organic peroxide type D, liquid, temperature controlled
5.2
UN3115
II
5.2
None
225
None
Forbidden
Forbidden
D
2, 40, 52, 53
G
Organic peroxide type D, solid
5.2
UN3106
II
5.2
152
225
None
5 kg
10 kg
D
12, 40, 52, 53
G
Organic peroxide type D, solid, temperature controlled
5.2
UN3116
II
5.2
None
225
None
Forbidden
Forbidden
D
2, 40, 52, 53
G
Organic peroxide type E, liquid
5.2
UN3107
II
5.2
152
225
None
10 L
25 L
D
12, 40, 52, 53
G
Organic peroxide type E, liquid, temperature controlled
5.2
UN3117
II
5.2
None
225
None
Forbidden
Forbidden
D
2, 40, 52, 53
G
Organic peroxide type E, solid
5.2
UN3108
II
5.2
152
225
None
10 kg
25 kg
D
12, 40, 52, 53
G
Organic peroxide type E, solid, temperature controlled
5.2
UN3118
II
5.2
None
225
None
Forbidden
Forbidden
D
2, 40, 52, 53
G
Organic peroxide type F, liquid
5.2
UN3109
II
5.2
IP5
152
225
225
10 L
25 L
D
12, 40, 52, 53
( printed page 34797)
G
Organic peroxide type F, liquid, temperature controlled
5.2
UN3119
II
5.2
IP5
None
225
225
Forbidden
Forbidden
D
2, 40, 52, 53
G
Organic peroxide type F, solid
5.2
UN3110
II
5.2
TP33
152
225
225
10 kg
25 kg
D
12, 40, 52, 53
G
Organic peroxide type F, solid, temperature controlled
5.2
UN3120
II
5.2
TP33
None
225
225
Forbidden
Forbidden
D
2, 52, 53
D
Organic phosphate, mixed with compressed gas
or
Organic phosphate compound, mixed with compressed gas
or
Organic phosphorus compound, mixed with compressed gas
2.3
NA1955
2.3
3
None
334
None
Forbidden
Forbidden
D
40
Organic pigments, self-heating
4.2
UN3313
II
4.2
IB8, IP2, IP4, T3, TP33
None
212
241
15 kg
50 kg
C
III
4.2
IB8, IP3, T1, TP33
None
213
241
25 kg
100 kg
C
G
Organoarsenic compound, liquid, n.o.s.
6.1
UN3280
I
6.1
5, T14, TP2, TP13, TP27
None
211
242
5 kg
50 kg
B
II
6.1
IB2, T11, TP2, TP27
153
212
242
25 kg
100 kg
B
III
6.1
IB3, T7, TP1, TP28
153
213
240
100 kg
200 kg
A
G
Organoarsenic compound, solid, n.o.s.
6.1
UN3465
I
6.1
IB7, IP1, T6, TP33
None
211
242
5 kg
50 kg
B
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
B
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
Organochlorine pesticides liquid, flammable, toxic,
flash point less than 23 degrees C
3
UN2762
I
3, 6.1
T14, TP2, TP13, TP27
None
201
243
Forbidden
30 L
B
40
II
3, 6.1
IB2, T11, TP2, TP13, TP27
150
202
243
1 L
60 L
B
40
Organochlorine pesticides, liquid, toxic
6.1
UN2996
I
6.1
T14, TP2, TP13, TP27
None
201
243
1 L
30 L
B
40
II
6.1
IB2, T11, TP2, TP13, TP27
153
202
243
5 L
60 L
B
40
III
6.1
IB3, T7, TP2, TP28
153
203
241
60 L
220 L
A
40
Organochlorine pesticides, liquid, toxic, flammable,
flash point not less than 23 degrees C
Organophosphorus pesticides, liquid, flammable, toxic,
flash point less than 23 degrees C
3
UN2784
I
3, 6.1
T14, TP2, TP13, TP27
None
201
243
Forbidden
30 L
B
40
II
3, 6.1
IB2, T11, TP2, TP13, TP27
150
202
243
1 L
60 L
B
40
Organophosphorus pesticides, liquid, toxic
6.1
UN3018
I
6.1
N76, T14, TP2, TP13, TP27
None
201
243
1 L
30 L
B
40
II
6.1
IB2, N76, T11, TP2, TP13, TP27
153
202
243
5 L
60 L
B
40
III
6.1
IB3, N76, T7, TP2, TP28
153
203
241
60 L
220 L
A
40
Organophosphorus pesticides, liquid, toxic, flammable,
flash point not less than 23 degrees C
6.1
UN3017
I
6.1, 3
N76, T14, TP2, TP13, TP27
None
201
243
1 L
30 L
B
40
II
6.1, 3
IB2, N76, T11, TP2, TP13, TP27
153
202
243
5 L
60 L
B
40
III
6.1, 3
B1, IB3, N76, T7, TP2, TP28
153
203
242
60 L
220 L
A
40
Organophosphorus pesticides, solid, toxic
6.1
UN2783
I
6.1
IB7, IP1, N77, T6, TP33
None
211
242
5 kg
50 kg
A
40
II
6.1
IB8, IP2, IP4, N77, T3, TP33
153
212
242
25 kg
100 kg
A
40
III
6.1
IB8, IP3, N77, T1, TP33
153
213
240
100 kg
200 kg
A
40
Organotin compounds, liquid, n.o.s.
6.1
UN2788
I
6.1
A3, N33, N34, T14, TP2, TP13, TP27
None
201
243
1 L
30 L
B
40
II
6.1
A3, IB2, N33, N34, T11, TP2, TP13, TP27
153
202
243
5 L
60 L
A
40
III
6.1
IB3, T7, TP2, TP28
153
203
241
60 L
220 L
A
40
( printed page 34799)
Organotin compounds, solid, n.o.s.
6.1
UN3146
I
6.1
A5, IB7, IP1, T6, TP33
None
211
242
5 kg
50 kg
B
40
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
40
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
40
Organotin pesticides, liquid, flammable, toxic,
flash point less than 23 degrees C
3
UN2787
I
3, 6.1
T14, TP2, TP13, TP27
None
201
243
Forbidden
30 L
B
40
II
3, 6.1
IB2, T11, TP2, TP13, TP27
150
202
243
1 L
60 L
B
40
Organotin pesticides, liquid, toxic
6.1
UN3020
I
6.1
T14, TP2, TP13, TP27
None
201
243
1 L
30 L
B
40
II
6.1
IB2, T11, TP2, TP13, TP27
153
202
243
5 L
60 L
B
40
III
6.1
IB3, T7, TP2, TP28
153
203
241
60 L
220 L
A
40
Organotin pesticides, liquid, toxic, flammable,
flash point not less than 23 degrees C
6.1
UN3019
I
6.1, 3
T14, TP2, TP13, TP27
None
201
243
1 L
30 L
B
40
II
6.1, 3
IB2, T11, TP2, TP13, TP27
153
202
243
5 L
60 L
B
40
III
6.1, 3
B1, IB3, T7, TP2, TP28
153
203
242
60 L
220 L
A
40
Organotin pesticides, solid, toxic
6.1
UN2786
I
6.1
IB7, IP1, T6, TP33
None
211
242
5 kg
50 kg
A
40
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
40
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
40
Orthonitroaniline, see
Nitroanilines
etc
Osmium tetroxide
6.1
UN2471
I
6.1
A8, IB7, IP1, N33, N34, T6, TP33
None
211
242
5 kg
50 kg
B
40
D G
Other regulated substances, liquid, n.o.s.
9
NA3082
III
9
IB3, T2, TP1
155
203
241
No limit
No limit
A
D G
Other regulated substances, solid, n.o.s.
9
NA3077
III
9
B54, IB8, IP2, T1, TP33
155
213
240
No limit
No limit
A
G
Oxidizing liquid, corrosive, n.o.s.
5.1
UN3098
I
5.1, 8
A6
None
201
244
Forbidden
2.5 L
D
13, 56, 58, 106, 138
II
5.1, 8
IB1
None
202
243
1 L
5 L
B
34, 56, 58, 106, 138
III
5.1, 8
IB2
152
203
242
2.5 L
30 L
B
34, 56, 58, 106, 138
G
Oxidizing liquid, n.o.s.
5.1
UN3139
I
5.1
127, A2, A6
None
201
243
Forbidden
2.5 L
D
56, 58, 106, 138
II
5.1
127, A2, IB2
152
202
242
1 L
5 L
B
56, 58, 106, 138
III
5.1
127, A2, IB2
152
203
241
2.5 L
30 L
B
56, 58, 106, 138
G
Oxidizing liquid, toxic, n.o.s.
5.1
UN3099
I
5.1, 6.1
A6
None
201
244
Forbidden
2.5 L
D
56, 58, 106, 138
II
5.1, 6.1
IB1
152
202
243
1 L
5 L
B
56, 58, 95, 106, 138
III
5.1, 6.1
IB2
152
203
242
2.5 L
30 L
B
56, 58, 95, 106, 138
G
Oxidizing solid, corrosive, n.o.s.
5.1
UN3085
I
5.1, 8
None
211
242
1 kg
15 kg
D
13, 56, 58, 106, 138
II
5.1, 8
IB6, IP2, T3, TP33
None
212
242
5 kg
25 kg
B
13, 34, 56, 58, 106, 138
( printed page 34800)
III
5.1, 8
IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
B
13, 34, 56, 58, 106, 138
G
Oxidizing solid, flammable, n.o.s.
5.1
UN3137
I
5.1, 4.1
None
214
214
Forbidden
Forbidden
G
Oxidizing solid, n.o.s.
5.1
UN1479
I
5.1
IB5, IP1
None
211
242
1 kg
15 kg
D
56, 58, 106, 138
II
5.1
IB8, IP2, IP4, T3, TP33
152
212
240
5 kg
25 kg
B
56, 58, 106, 138
III
5.1
IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
B
56, 58, 106, 138
G
Oxidizing solid, self-heating, n.o.s.
5.1
UN3100
I
5.1, 4.2
None
214
214
Forbidden
Forbidden
II
5.1, 4.2
None
214
214
Forbidden
Forbidden
G
Oxidizing solid, toxic, n.o.s.
5.1
UN3087
I
5.1, 6.1
None
211
242
1 kg
15 kg
D
56, 58, 106, 138
II
5.1, 6.1
IB6, IP2, T3, TP33
152
212
242
5 kg
25 kg
B
56, 58, 95, 106, 138
III
5.1, 6.1
IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
B
56, 58, 95, 106, 138
G
Oxidizing solid, water-reactive, n.o.s.
5.1
UN3121
5.1, 4.3
None
214
214
Forbidden
Forbidden
Oxygen and carbon dioxide mixtures, see
Carbon dioxide and oxygen mixtures
Oxygen, compressed
2.2
UN1072
2.2, 5.1
A14, A52
306
302
314, 315
75 kg
150 kg
A
Oxygen difluoride, compressed
2.3
UN2190
2.3, 5.1, 8
1
None
304
None
Forbidden
Forbidden
D
13, 40, 89, 90
Oxygen generator, chemical
(including when contained in associated equipment, e.g., passenger service units (PSUs), portable breathing equipment (PBE), etc).
5.1
UN3356
II
5.1
60, A51
None
212
None
Forbidden
25 kg gross
D
56, 58, 69, 106
+
Oxygen generator, chemical, spent
9
NA3356
III
9
61
None
213
None
Forbidden
Forbidden
A
Oxygen, mixtures with rare gases, see
Rare gases and oxygen mixtures
Oxygen, refrigerated liquid
(cryogenic liquid)
2.2
UN1073
2.2, 5.1
T75, TP5, TP22
320
316
318
Forbidden
Forbidden
D
Paint
including paint, lacquer, enamel, stain, shellac solutions, varnish, polish, liquid filler, and liquid lacquer base
3
UN1263
I
3
T11, TP1, TP8
150
201
243
1 L
30 L
E
II
3
149, B52, IB2, T4, TP1, TP8
150
173
242
5 L
60 L
B
III
3
B1, B52, IB3, T2, TP1
150
173
242
60 L
220 L
A
Paint
or
Paint related material
8
UN3066
II
8
B2, IB2, T7, TP2
154
173
242
1 L
30 L
A
III
8
B52, IB3, T4, TP1
154
173
241
5 L
60 L
A
Paint related material
including paint thinning, drying, removing, or reducing compound
Pentaerythrite tetranitrate mixture, desensitized, solid, n.o.s.
with more than 10 percent but not more than 20 percent PETN, by mass
4.1
UN3344
II
4.1
118, N85
None
214
None
Forbidden
Forbidden
E
Pentaerythrite tetranitrate
or
Pentaerythritol tetranitrate
or
PETN,
with not less than 7 percent wax by mass
1.1D
UN0411
II
1.1D
None
62
None
Forbidden
Forbidden
10
Pentaerythrite tetranitrate, wetted
or
Pentaerythritol tetranitrate, wetted,
or
PETN, wetted
with not less than 25 percent water, by mass, or
Pentaerythrite tetranitrate,
or
Pentaerythritol tetranitrate
or
PETN, desensitized
with not less than 15 percent phlegmatizer by mass
1.1D
UN0150
II
1.1D
121
None
62
None
Forbidden
Forbidden
10
Pentaerythritol tetranitrate,
see
Pentaerythrite tetranitrate,
etc
Pentafluoroethane
or
Refrigerant gas R 125
2.2
UN3220
2.2
T50
306
304
314, 315
75 kg
150 kg
A
Pentamethylheptane
3
UN2286
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Pentane-2,4-dione
3
UN2310
III
3, 6.1
B1, IB3, T4, TP1
150
203
242
60 L
220 L
A
Pentanes
3
UN1265
I
3
T11, TP2
150
201
243
1 L
30 L
E
II
3
IB2, IP8, T4, TP1
150
202
242
5 L
60 L
E
Pentanitroaniline (dry)
Forbidden
Pentanols
3
UN1105
II
3
IB2, T4, TP1, TP29
150
202
242
5 L
60 L
B
III
3
B1, B3, IB3, T2, TP1
150
203
242
60 L
220 L
A
1-Pentene
(n-amylene)
3
UN1108
I
3
T11, TP2
150
201
243
1 L
30 L
E
1-Pentol
8
UN2705
II
8
B2, IB2, T7, TP2
154
202
242
1 L
30 L
B
26, 27
Pentolite,
dry or wetted with less than 15 percent water, by mass
1.1D
UN0151
II
1.1D
None
62
None
Forbidden
Forbidden
10
Pepper spray, see
Aerosols,
etc. or
Self-defense spray, non-pressurized
Perchlorates, inorganic, aqueous solution, n.o.s.
5.1
UN3211
II
5.1
IB2, T4, TP1
152
202
242
1 L
5 L
B
56, 58, 133
III
5.1
IB2, T4, TP1
152
202
241
2.5 L
30 L
B
56, 58, 69, 133
Perchlorates, inorganic, n.o.s.
5.1
UN1481
II
5.1
IB6, IP2, T3, TP33
152
212
242
5 kg
25 kg
A
56, 58
III
5.1
IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
56, 58
Perchloric acid, with more than 72 percent acid by mass
Forbidden
Perchloric acid
with more than 50 percent but not more than 72 percent acid, by mass
5.1
UN1873
I
5.1, 8
A2, A3, N41, T10, TP1, TP12
None
201
243
Forbidden
2.5 L
D
66
Perchloric acid
with not more than 50 percent acid by mass
Phosphorus trisulfide,
free from yellow or white phosphorus
4.1
UN1343
II
4.1
A20, IB4, N34, T3, TP33
None
212
240
15 kg
50 kg
B
74
Phosphorus, white dry
or
Phosphorus, white, under water
or
Phosphorus white, in solution
or
Phosphorus, yellow dry
or
Phosphorus, yellow, under water
or
Phosphorus, yellow, in solution
4.2
UN1381
I
4.2, 6.1
B9, B26, N34, T9, TP3, TP31
None
188
243
Forbidden
Forbidden
E
Phosphorus white, molten
4.2
UN2447
I
4.2, 6.1
B9, B26, N34, T21, TP3, TP7, TP26
None
188
243
Forbidden
Forbidden
D
Phosphorus (white or red) and a chlorate, mixtures of
Forbidden
Phosphoryl chloride, see
Phosphorus oxychloride
Phthalic anhydride
with more than .05 percent maleic anhydride
8
UN2214
III
8
IB8, IP3, T1, TP33
154
213
240
25 kg
100 kg
A
Picolines
3
UN2313
III
3
B1, IB3, T4, TP1
150
203
242
60 L
220 L
A
40
Picric acid,
see
Trinitrophenol,
etc
Picrite,
see
Nitroguanidine,
etc
Picryl chloride,
see
Trinitrochlorobenzene
Pine oil
3
UN1272
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
alpha-Pinene
3
UN2368
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Piperazine
8
UN2579
III
8
IB8, IP3, T1, TP33
154
213
240
25 kg
100 kg
A
12, 52
Piperidine
8
UN2401
I
8, 3
A10, T10, TP2
None
201
243
0.5 L
2.5 L
B
52
Pivaloyl chloride, see
Trimethylacetyl chloride
Plastic molding compound
in dough, sheet or extruded rope form evolving flammable vapor
9
UN3314
III
9
32, IB8, IP3, IP7
155
221
221
100 kg
200 kg
A
85, 87
Plastic solvent, n.o.s., see
Flammable liquids, n.o.s.
Railway torpedo, see
Signals, railway track, explosive
Rare gases and nitrogen mixtures, compressed
2.2
UN1981
2.2
306
302
None
75 kg
150 kg
A
Rare gases and oxygen mixtures, compressed
2.2
UN1980
2.2
79
306
302
None
75 kg
150 kg
A
Rare gases mixtures, compressed
2.2
UN1979
2.2
306
302
None
75 kg
150 kg
A
RC 318, see
Octafluorocyclobutane
RDX and cyclotetramethylenetetranitramine, wetted
or
desensitized
see
RDX and HMX mixtures, wetted or desensitized
RDX and HMX mixtures, wetted
with not less than 15 percent water by massor
RDX and HMX mixtures, desensitized
with not less than 10 percent phlegmatizer by mass
1.1D
UN0391
II
1.1D
None
62
None
Forbidden
Forbidden
10
RDX and Octogen mixtures, wetted
or
desensitized
see
RDX and HMX mixtures, wetted
or
desensitized
etc
RDX, see
Cyclotrimethylene trinitramine,
etc
Receptacles, small, containing gas (gas cartridges)
flammable, without release device, not refillable and not exceeding 1 L capacity
2.1
UN2037
2.1
306
304
None
1 kg
15 kg
B
40
Receptacles, small, containing gas (gas cartridges)
non-flammable, without release device, not refillable and not exceeding 1 L capacity
2.2
UN2037
2.2
306
304
None
1 kg
15 kg
B
40
2.2, 5.1
A14
306
304
None
1 kg
15 kg
B
40
Red phosphorus, see
Phosphorus, amorphous
Refrigerant gas R 404A
2.2
UN3337
2.2
T50
306
304
314, 315
75 kg
150 kg
A
Refrigerant gas R 407A
2.2
UN3338
2.2
T50
306
304
314, 315
75 kg
150 kg
A
Refrigerant gas R 407B
2.2
UN3339
2.2
T50
306
304
314, 315
75 kg
150 kg
A
Refrigerant gas R 407C
2.2
UN3340
2.2
T50
306
304
314, 315
75 kg
150 kg
A
G
Refrigerant gases, n.o.s.
2.2
UN1078
2.2
T50
306
304
314, 315
75 kg
150 kg
A
D
Refrigerant gases, n.o.s.
or
Dispersant gases, n.o.s.
2.1
NA1954
2.1
T50
306
304
314, 315
Forbidden
150 kg
D
40
Refrigerating machines,
containing flammable, non-toxic, liquefied gas
2.1
UN3358
2.1
306
306
306
Forbidden
Forbidden
C
40
Refrigerating machines,
containing non-flammable, non-toxic, or ammonia solution (UN2672)
2.2
UN2857
2.2
A53
306, 307
306
306, 307
450 kg
450 kg
A
Regulated medical waste
6.2
UN3291
II
6.2
A13
134
197
197
No limit
No limit
A
40
Release devices, explosive
1.4S
UN0173
II
1.4S
None
62
None
25 kg
100 kg
05
Resin solution,
flammable
3
UN1866
I
3
B52, T11, TP1, TP8, TP28
150
201
243
1 L
30 L
E
II
3
149, B52, IB2, T4, TP1, TP8
150
173
242
5 L
60 L
B
III
3
B1, B52, IB3, T2, TP1
150
173
242
60 L
220 L
A
Resorcinol
6.1
UN2876
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
Rifle grenade, see
Grenades,
hand or rifle, etc
Rifle powder, see
Powder, smokeless
(UN 0160)
Rivets, explosive
1.4S
UN0174
II
1.4S
None
62
None
25 kg
100 kg
05
Road asphalt or tar liquid, see
Tars, liquid,
etc
Rocket motors
1.3C
UN0186
II
1.3C
109
None
62
None
Forbidden
220 kg
03
Rocket motors
1.1C
UN0280
II
1.1C
109
None
62
None
Forbidden
Forbidden
03
Rocket motors
1.2C
UN0281
II
1.2C
109
None
62
None
Forbidden
Forbidden
03
Rocket motors, liquid fueled
1.2J
UN0395
II
1.2J
109
None
62
None
Forbidden
Forbidden
04
23E
Rocket motors, liquid fueled
1.3J
UN0396
II
1.3J
109
None
62
None
Forbidden
Forbidden
04
23E
Rocket motors with hypergolic liquids
with or without an expelling charge
1.3L
UN0250
II
1.3L
109
None
62
None
Forbidden
Forbidden
08
8E, 14E, 15E
Rocket motors with hypergolic liquids
with or without an expelling charge
1.2L
UN0322
II
1.2L
109
None
62
None
Forbidden
Forbidden
08
8E, 14E, 15E
( printed page 34810)
Rockets, line-throwing
1.2G
UN0238
II
1.2G
None
62
None
Forbidden
Forbidden
07
Rockets, line-throwing
1.3G
UN0240
II
1.3G
None
62
None
Forbidden
75 kg
07
Rockets, line-throwing
1.4G
UN0453
II
1.4G
None
62
None
Forbidden
75 kg
06
Rockets, liquid fueled
with bursting charge
1.1J
UN0397
II
1.1J
None
62
None
Forbidden
Forbidden
04
23E
Rockets, liquid fueled
with bursting charge
1.2J
UN0398
II
1.2J
None
62
None
Forbidden
Forbidden
04
23E
Rockets,
with bursting charge
1.1F
UN0180
II
1.1F
None
62
None
Forbidden
Forbidden
08
Rockets,
with bursting charge
1.1E
UN0181
II
1.1E
None
62
None
Forbidden
Forbidden
03
Rockets,
with bursting charge
1.2E
UN0182
II
1.2E
None
62
None
Forbidden
Forbidden
03
Rockets,
with bursting charge
1.2F
UN0295
II
1.2F
None
62
None
Forbidden
Forbidden
08
Rockets,
with expelling charge
1.2C
UN0436
II
1.2C
None
62
None
Forbidden
Forbidden
03
Rockets,
with expelling charge
1.3C
UN0437
II
1.3C
None
62
None
Forbidden
Forbidden
03
Rockets,
with expelling charge
1.4C
UN0438
II
1.4C
None
62
None
Forbidden
75 kg
02
Rockets,
with inert head
1.3C
UN0183
II
1.3C
None
62
None
Forbidden
Forbidden
03
Rockets,
with inert head
1.2C
UN0502
1.2C
None
62
None
Forbidden
Forbidden
B
1E, 5E
Rosin oil
3
UN1286
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
B
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Rubber solution
3
UN1287
II
3
149, IB2, T4, TP1, TP8
150
202
242
5 L
60 L
B
Rubber scrap
or
shoddy,
powdered or granulated, not exceeding 840 microns and rubber contend exceeding 45%
4.1
UN1345
II
4.1
IB8, IP2, IP4, T3, TP33
151
212
240
15 kg
50 kg
A
Rubber solution
3
UN1287
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Rubidium
4.3
UN1423
I
4.3
22, A7, A19, IB4, IP1, N34, N40, N45
None
211
242
Forbidden
15 kg
D
52
Rubidium hydroxide
8
UN2678
II
8
IB8, IP2, IP4, T3, TP33
154
212
240
15 kg
50 kg
A
29
Rubidium hydroxide solution
8
UN2677
II
8
B2, IB2, T7, TP2
154
202
242
1 L
30 L
A
29
III
8
IB3, T4, TP1
154
203
241
5 L
60 L
A
29
Safety fuse, see
Fuse, safety
Sand acid, see
Fluorosilicic acid
Seed cake,
containing vegetable oil solvent extractions and expelled seeds, with not more than 10 percent of oil and when the amount of moisture is higher than 11 percent, with not more than 20 percent of oil and moisture combined
4.2
UN1386
III
None
IB8, IP3, IP7, N7
None
213
241
Forbidden
Forbidden
A
13
I
Seed cake
with more than 1.5 percent oil and not more than 11 percent moisture
4.2
UN1386
III
None
IB8, IP3, IP7, N7
None
213
241
Forbidden
Forbidden
E
13
I
Seed cake
with not more than 1.5 percent oil and not more than 11 percent moisture
4.2
UN2217
III
None
IB8, IP3, IP7, N7
None
213
241
Forbidden
Forbidden
A
13
Selenates
or
Selenites
6.1
UN2630
I
6.1
IB7, IP1, T6, TP33
None
211
242
5 kg
50 kg
E
Selenic acid
8
UN1905
I
8
IB7, IP1, N34, T6, TP33
None
211
242
Forbidden
25 kg
A
Selenium compound, solid, n.o.s.
6.1
UN3283
I
6.1
IB7, IP1, T6, TP33
None
211
242
5 kg
50 kg
B
Selenium compound, liquid, n.o.s.
6.1
UN3440
I
6.1
T14, TP2, TP27
None
201
243
1 L
30 L
B
Selenium compound, solid, n.o.s.
6.1
UN3283
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
B
Selenium compound, liquid, n.o.s.
6.1
UN3440
II
6.1
IB2, T11, TP2, TP27
153
202
243
5 L
60 L
B
Selenium compound, solid, n.o.s.
6.1
UN3283
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
Selenium compound, liquid, n.o.s.
6.1
UN3440
III
6.1
IB3, T7, TP1, TP28
153
203
241
60 L
220 L
A
Selenium disulfide
6.1
UN2657
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Selenium hexafluoride
2.3
UN2194
2.3, 8
1
None
302
None
Forbidden
Forbidden
D
40
Selenium nitride
Forbidden
Selenium oxychloride
8
UN2879
I
8, 6.1
A3, A6, A7, N34, T10, TP2, TP12, TP13
None
201
243
0.5 L
2.5 L
E
40
Self-defense spray, aerosol, see
Aerosols,
etc
+ A D
Self-defense spray, non-pressurized
9
NA3334
III
9
A37
155
203
None
No limit
No limit
A
G
Self-heating liquid, corrosive, inorganic, n.o.s.
4.2
UN3188
II
4.2, 8
IB2
None
202
243
1 L
5 L
C
III
4.2, 8
IB2
None
203
241
5 L
60 L
C
G
Self-heating liquid, corrosive, organic, n.o.s.
4.2
UN3185
II
4.2, 8
IB2
None
202
243
1 L
5 L
C
III
4.2, 8
IB2
None
203
241
5 L
60 L
C
G
Self-heating liquid, inorganic, n.o.s.
4.2
UN3186
II
4.2
IB2
None
202
242
1 L
5 L
C
III
4.2
IB2
None
203
241
5 L
60 L
C
( printed page 34811)
G
Self-heating liquid, organic, n.o.s.
4.2
UN3183
II
4.2
IB2
None
202
242
1 L
5 L
C
III
4.2
IB2
None
203
241
5 L
60 L
C
G
Self-heating liquid, toxic, inorganic, n.o.s.
4.2
UN3187
II
4.2, 6.1
IB2
None
202
243
1 L
5 L
C
III
4.2, 6.1
IB2
None
203
241
5 L
60 L
C
G
Self-heating liquid, toxic, organic, n.o.s.
4.2
UN3184
II
4.2, 6.1
IB2
None
202
243
1 L
5 L
C
III
4.2, 6.1
IB2
None
203
241
5 L
60 L
C
G
Self-heating solid, corrosive, inorganic, n.o.s.
4.2
UN3192
II
4.2, 8
IB5, IP2, T3, TP33
None
212
242
15 kg
50 kg
C
III
4.2, 8
IB8, IP3, T1, TP33
None
213
242
25 kg
100 kg
C
G
Self-heating, solid, corrosive, organic, n.o.s.
4.2
UN3126
II
4.2, 8
IB5, IP2, T3, TP33
None
212
242
15 kg
50 kg
C
III
4.2, 8
IB8, IP3, T1, TP33
None
213
242
25 kg
100 kg
C
G
Self-heating solid, inorganic, n.o.s.
4.2
UN3190
II
4.2
IB6, IP2, T3, TP33
None
212
241
15 kg
50 kg
C
III
4.2
IB8, IP3, T1, TP33
None
213
241
25 kg
100 kg
C
G
Self-heating, solid, organic, n.o.s.
4.2
UN3088
II
4.2
IB6, IP2, T3, TP33
None
212
241
15 kg
50 kg
C
III
4.2
IB8, IP3, T1, TP33
None
213
241
25 kg
100 kg
C
G
Self-heating, solid, oxidizing, n.o.s.
4.2
UN3127
4.2, 5.1
None
214
214
Forbidden
Forbidden
G
Self-heating solid, toxic, inorganic, n.o.s.
4.2
UN3191
II
4.2, 6.1
IB5, IP2, T3, TP33
None
212
242
15 kg
50 kg
C
III
4.2, 6.1
IB8, IP3, T1, TP33
None
213
242
25 kg
100 kg
C
G
Self-heating, solid, toxic, organic, n.o.s.
4.2
UN3128
II
4.2, 6.1
IB5, IP2, T3, TP33
None
212
242
15 kg
50 kg
C
III
4.2, 6.1
IB8, IP3, T1, TP33
None
213
242
25 kg
100 kg
C
Self-propelled vehicle, see
Engines
or
Batteries
etc
G
Self-reactive liquid type B
4.1
UN3221
II
4.1
53
None
224
None
Forbidden
Forbidden
D
52, 53
G
Self-reactive liquid type B, temperature controlled
4.1
UN3231
II
4.1
53
None
224
None
Forbidden
Forbidden
D
2, 52, 53
G
Self-reactive liquid type C
4.1
UN3223
II
4.1
None
224
None
5 L
10 L
D
52, 53
G
Self-reactive liquid type C, temperature controlled
4.1
UN3233
II
4.1
None
224
None
Forbidden
Forbidden
D
2, 52, 53
G
Self-reactive liquid type D
4.1
UN3225
II
4.1
None
224
None
5 L
10 L
D
52, 53
G
Self-reactive liquid type D, temperature controlled
4.1
UN3235
II
4.1
None
224
None
Forbidden
Forbidden
D
2, 52, 53
G
Self-reactive liquid type E
4.1
UN3227
II
4.1
None
224
None
10 L
25 L
D
52, 53
G
Self-reactive liquid type E, temperature controlled
4.1
UN3237
II
4.1
None
224
None
Forbidden
Forbidden
D
2, 52, 53
G
Self-reactive liquid type F
4.1
UN3229
II
4.1
T23
None
224
None
10 L
25 L
D
52, 53
G
Self-reactive liquid type F, temperature controlled
4.1
UN3239
II
4.1
None
224
None
Forbidden
Forbidden
D
2, 52, 53
G
Self-reactive solid type B
4.1
UN3222
II
4.1
53
None
224
None
Forbidden
Forbidden
D
52, 53
G
Self-reactive solid type B, temperature controlled
4.1
UN3232
II
4.1
53
None
224
None
Forbidden
Forbidden
D
2, 52, 53
G
Self-reactive solid type C
4.1
UN3224
II
4.1
None
224
None
5 kg
10 kg
D
52, 53
G
Self-reactive solid type C, temperature controlled
4.1
UN3234
II
4.1
None
224
None
Forbidden
Forbidden
D
2, 52, 53
G
Self-reactive solid type D
4.1
UN3226
II
4.1
None
224
None
5 kg
10 kg
D
52, 53
G
Self-reactive solid type D, temperature controlled
4.1
UN3236
II
4.1
None
224
None
Forbidden
Forbidden
D
2, 52, 53
G
Self-reactive solid type E
4.1
UN3228
II
4.1
None
224
None
10 kg
25 kg
D
52, 53
G
Self-reactive solid type E, temperature controlled
4.1
UN3238
II
4.1
None
224
None
Forbidden
Forbidden
D
2, 52, 53
G
Self-reactive solid type F
4.1
UN3230
II
4.1
None
224
None
10 kg
25 kg
D
52, 53
G
Self-reactive solid type F, temperature controlled
4.1
UN3240
II
4.1
None
224
None
Forbidden
Forbidden
D
2, 52, 53
Shale oil
3
UN1288
I
3
T11, TP1, TP8, TP27
None
201
243
1 L
30 L
B
II
3
IB2, T4, TP1, TP8
150
202
242
5 L
60 L
B
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Shaped charges, see
Charges, shaped,
etc
Signal devices, hand
1.4G
UN0191
II
1.4G
None
62
None
Forbidden
75 kg
06
Signal devices, hand
1.4S
UN0373
II
1.4S
None
62
None
25 kg
100 kg
05
( printed page 34812)
Signals, distress,
ship
1.1G
UN0194
II
1.1G
None
62
None
Forbidden
Forbidden
07
Signals, distress,
ship
1.3G
UN0195
II
1.3G
None
62
None
Forbidden
75 kg
07
Signals, highway, see
Signal devices, hand
Signals, railway track, explosive
1.1G
UN0192
II
1.1G
None
62
None
Forbidden
Forbidden
07
Signals, railway track, explosive
1.4S
UN0193
II
1.4S
None
62
None
25 kg
100 kg
05
Signals, railway track, explosive
1.3G
UN0492
1.3G
None
62
None
Forbidden
Forbidden
07
Signals, railway track, explosive
1.4G
UN0493
1.4G
None
62
None
Forbidden
75 kg
06
Signals, ship distress, water-activated, see
Contrivances, water-activated,
etc
Signals, smoke
1.1G
UN0196
II
1.1G
None
62
None
Forbidden
Forbidden
07
Signals, smoke
1.4G
UN0197
II
1.4G
None
62
None
Forbidden
75 kg
06
Signals, smoke
1.2G
UN0313
II
1.2G
None
62
None
Forbidden
Forbidden
07
Signals, smoke
1.3G
UN0487
II
1.3G
None
62
None
Forbidden
Forbidden
07
Silane
2.1
UN2203
2.1
None
302
None
Forbidden
Forbidden
E
40, 57, 104
Silicofluoric acid, see
Fluorosilicic acid
Silicon chloride, see
Silicon tetrachloride
Silicon powder, amorphous
4.1
UN1346
III
4.1
A1, IB8, IP3, T1, TP33
None
213
240
25 kg
100 kg
A
74
Silicon tetrachloride
8
UN1818
II
8
A3, A6, B2, B6, IB2, T7, TP2, TP7
154
202
242
1 L
30 L
C
40
Silicon tetrafluoride
2.3
UN1859
2.3, 8
2
None
302
None
Forbidden
Forbidden
D
40
Silver acetylide (dry)
Forbidden
Silver arsenite
6.1
UN1683
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Silver azide (dry)
Forbidden
Silver chlorite (dry)
Forbidden
Silver cyanide
6.1
UN1684
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
40, 52
Silver fulminate (dry)
Forbidden
Silver nitrate
5.1
UN1493
II
5.1
IB8, IP4, T3, TP33
152
212
242
5 kg
25 kg
A
Silver oxalate (dry)
Forbidden
Silver picrate (dry)
Forbidden
Silver picrate, wetted
with not less than 30 percent water, by mass
4.1
UN1347
I
4.1
23
None
211
None
Forbidden
Forbidden
D
28, 36
Sludge, acid
8
UN1906
II
8
A3, A7, B2, IB2, N34, T8, TP2, TP12, TP28
None
202
242
Forbidden
30 L
C
14
D
Smokeless powder for small arms (
100 pounds or less)
4.1
NA3178
I
4.1
16
None
171
None
Forbidden
7.3 kg
A
Soda lime
with more than 4 percent sodium hydroxide
Sodium bisulfite, solution, see
Bisulfites, aqueous solutions, n.o.s.
Sodium borohydride
4.3
UN1426
I
4.3
N40
None
211
242
Forbidden
15 kg
E
52
Sodium borohydride and sodium hydroxide solution,
with not more than 12 percent sodium borohydride and not more than 40 percent sodium hydroxide by mass
8
UN3320
II
8
B2, IB2, N34, T7, TP2
154
202
242
1 L
30 L
A
52
III
8
B2, IB3, N34, T4, TP2
154
203
241
5 L
60 L
A
52
Sodium bromate
5.1
UN1494
II
5.1
IB8, IP4, T3, TP33
152
212
242
5 kg
25 kg
A
56, 58
Sodium cacodylate
6.1
UN1688
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
52
Sodium carbonate peroxyhydrate
5.1
UN3378
II
5.1
IB8, IP2, IP4, T3, TP33
152
212
240
5 kg
25 kg
A
13, 48, 75
III
5.1
IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
13, 48, 75
Sodium chlorate
5.1
UN1495
II
5.1
A9, IB8, IP4, N34, T3, TP33
152
212
240
5 kg
25 kg
A
56, 58
Sodium chlorate, aqueous solution
5.1
UN2428
II
5.1
A2, IB2, T4, TP1
152
202
241
1 L
5 L
B
56, 58, 133
III
5.1
A2, IB2, T4, TP1
152
203
241
2.5 L
30 L
B
56, 58, 69, 133
Sodium chlorate mixed with dinitrotoluene, see
Explosive blasting, type C
Sodium chlorite
5.1
UN1496
II
5.1
A9, IB8, IP2, IP4, N34, T3, TP33
None
212
242
5 kg
25 kg
A
56, 58
Sodium chloroacetate
6.1
UN2659
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
Sodium cuprocyanide, solid
6.1
UN2316
I
6.1
IB7, IP1, T6, TP33
None
211
242
5 kg
50 kg
A
52
Sodium cuprocyanide, solution
6.1
UN2317
I
6.1
T14, TP2, TP13
None
201
243
1 L
30 L
B
40, 52
Sodium cyanide, solid
6.1
UN1689
I
6.1
B69, B77, IB7, N74, N75, T6, TP33
None
211
242
5 kg
50 kg
B
52
Sodium cyanide solution
6.1
UN3414
I
6.1
B69, B77, N74, N75, T14, TP2, TP13
None
201
243
1 L
30 L
B
52
II
6.1
B69, B77, IB2, N74, N75, T11, TP2, TP13, TP27
153
202
243
5 L
60 L
B
52
III
6.1
B69, B77, IB3, N74, N75, T7, TP2, TP13, TP28
153
203
241
60 L
220 L
A
52
Sodium dichloroisocyanurate or Sodium dichloro-s-triazinetrione, see
Dichloroisocyanuric acid
etc
Sodium dinitro-o-cresolate,
dry or wetted with less than 15 percent water, by mass
1.3C
UN0234
II
1.3C
None
62
None
Forbidden
Forbidden
10
5E
Sodium dinitro-o-cresolate, wetted
with not less than 10% water, by mass
4.1
UN3369
I
4.1
162, A8, A19, N41, N84
None
211
None
0.5 kg
0.5 kg
E
36
Sodium dinitro-o-cresolate, wetted
with not less than 15 percent water, by mass
4.1
UN1348
I
4.1, 6.1
23, A8, A19, A20, N41
None
211
None
1 kg
15 kg
E
28, 36
Sodium dithionite
or
Sodium hydrosulfite
4.2
UN1384
II
4.2
A19, A20, IB6, IP2, T3, TP33
None
212
241
15 kg
50 kg
E
13
Sodium fluoride, solid
6.1
UN1690
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
52
Sodium fluoride solution
6.1
UN3415
III
6.1
IB3, T4, TP1
153
203
241
60 L
220 L
A
52
Sodium fluoroacetate
6.1
UN2629
I
6.1
IB7, IP1, T6, TP33
None
211
242
5 kg
50 kg
E
Sodium fluorosilicate
6.1
UN2674
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
52
Sodium hydrate, see
Sodium hydroxide, solid
Sodium hydride
4.3
UN1427
I
4.3
A19, N40
None
211
242
Forbidden
15 kg
E
52
Sodium hydrogendifluoride
8
UN2439
II
8
IB8, IP2, IP4, N3, N34, T3, TP33
154
212
240
15 kg
50 kg
A
12, 25, 40, 52
Sodium hydrosulfide,
with less than 25 percent water of crystallization
4.2
UN2318
II
4.2
A7, A19, A20, IB6, IP2, T3, TP33
None
212
241
15 kg
50 kg
A
Sodium hydrosulfide
with not less than 25 percent water of crystallization
8
UN2949
II
8
A7, IB8, IP2, IP4, T7, TP2
154
212
240
15 kg
50 kg
A
52
Sodium hydrosulfite,
see
Sodium dithionite
Sodium hydroxide, solid
8
UN1823
II
8
IB8, IP2, IP4, T3, TP33
154
212
240
15 kg
50 kg
A
Sodium hydroxide solution
8
UN1824
II
8
B2, IB2, N34, T7, TP2
154
202
242
1 L
30 L
A
III
8
IB3, N34, T4, TP1
154
203
241
5 L
60 L
A
Sodium hypochlorite, solution, see
Hypochlorite solutions
etc
Sodium metal, liquid alloy, see
Alkali metal alloys, liquid, n.o.s.
( printed page 34814)
Sodium methylate
4.2
UN1431
II
4.2, 8
A7, A19, IB5, IP2, T3, TP33
None
212
242
15 kg
50 kg
B
Sodium methylate solutions
in alcohol
3
UN1289
II
3, 8
IB2, T7, TP1, TP8
150
202
243
1 L
5 L
B
III
3, 8
B1, IB3, T4, TP1
150
203
242
5 L
60 L
A
Sodium monoxide
8
UN1825
II
8
IB8, IP2, IP4, T3, TP33
154
212
240
15 kg
50 kg
A
Sodium nitrate
5.1
UN1498
III
5.1
A1, A29, IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
Sodium nitrate and potassium nitrate mixtures
5.1
UN1499
III
5.1
A1, A29, IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
Sodium nitrite
5.1
UN1500
III
5.1, 6.1
A1, A29, IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
56, 58
Sodium pentachlorophenate
6.1
UN2567
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Sodium perborate monohydrate
5.1
UN3377
III
5.1
IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
13, 48, 75
Sodium perchlorate
5.1
UN1502
II
5.1
IB6, IP2, T3, TP33
152
212
242
5 kg
25 kg
A
56, 58
Sodium permanganate
5.1
UN1503
II
5.1
IB6, IP2, T3, TP33
152
212
242
5 kg
25 kg
D
56, 58, 138
Sodium peroxide
5.1
UN1504
I
5.1
A20, IB5, IP1, N34
None
211
None
Forbidden
15 kg
B
13, 52, 66, 75
Sodium peroxoborate, anhydrous
5.1
UN3247
II
5.1
IB8, IP4, T3, TP33
152
212
240
5 kg
25 kg
A
13, 25
Sodium persulfate
5.1
UN1505
III
5.1
A1, IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
56, 58
Sodium phosphide
4.3
UN1432
I
4.3, 6.1
A19, N40
None
211
None
Forbidden
15 kg
E
40, 52, 85
Sodium picramate,
dry or wetted with less than 20 percent water, by mass
1.3C
UN0235
II
1.3C
None
62
None
Forbidden
Forbidden
10
5E
Sodium picramate, wetted
with not less than 20 percent water, by mass
4.1
UN1349
I
4.1
23, A8, A19, N41
None
211
None
Forbidden
15 kg
E
28, 36
Sodium picryl peroxide
Forbidden
Sodium potassium alloys, see
Potassium sodium alloys
Sodium selenate, see
Selenates
or
Selenites
Sodium sulfide, anhydrous
or
Sodium sulfide
with less than 30 percent water of crystallization
4.2
UN1385
II
4.2
A19, A20, IB6, IP2, N34, T3, TP33
None
212
241
15 kg
50 kg
A
52
Sodium sulfide, hydrated
with not less than 30 percent water
8
UN1849
II
8
IB8, IP2, IP4, T3, TP33
154
212
240
15 kg
50 kg
A
26
Sodium superoxide
5.1
UN2547
I
5.1
A20, IB6, IP1, N34
None
211
None
Forbidden
15 kg
E
13, 52, 66, 75
Sodium tetranitride
Forbidden
G
Solids containing corrosive liquid, n.o.s.
8
UN3244
II
8
49, IB5, T3, TP33
154
212
240
15 kg
50 kg
B
40
G
Solids containing flammable liquid, n.o.s.
4.1
UN3175
II
4.1
47, IB6, IP2, T3, TP33
151
212
240
15 kg
50 kg
B
G
Solids containing toxic liquid, n.o.s.
6.1
UN3243
II
6.1
48, IB2, T2, TP33
153
212
240
25 kg
100 kg
B
40
Sounding devices, explosive
1.2F
UN0204
II
1.2F
None
62
None
Forbidden
Forbidden
08
Sounding devices, explosive
1.1F
UN0296
II
1.1F
None
62
None
Forbidden
Forbidden
08
Sounding devices, explosive
1.1D
UN0374
II
1.1D
None
62
None
Forbidden
Forbidden
07
Sounding devices, explosive
1.2D
UN0375
II
1.2D
None
62
None
Forbidden
Forbidden
07
Spirits of salt, see
Hydrochloric acid
Squibs, see
Igniters
etc
Stannic chloride, anhydrous
8
UN1827
II
8
B2, IB2, T7, TP2
154
202
242
1 L
30 L
C
Stannic chloride pentahydrate
8
UN2440
III
8
IB8, IP3, T1, TP33
154
213
240
25 kg
100 kg
A
Stannic phosphide
4.3
UN1433
I
4.3, 6.1
A19, N40
None
211
242
Forbidden
15 kg
E
40, 52, 85
Steel swarf, see
Ferrous metal borings,
etc
Stibine
2.3
UN2676
2.3, 2.1
1
None
304
None
Forbidden
Forbidden
D
40
Storage batteries, wet, see
Batteries,
wet etc
Strontium arsenite
6.1
UN1691
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
( printed page 34815)
Strontium chlorate
5.1
UN1506
II
5.1
A1, A9, IB8, IP2, IP4, N34, T3, TP33
152
212
242
5 kg
25 kg
A
56, 58
Strontium nitrate
5.1
UN1507
III
5.1
A1, A29, IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
Strontium perchlorate
5.1
UN1508
II
5.1
IB6, IP2, T3, TP33
152
212
242
5 kg
25 kg
A
56, 58
Strontium peroxide
5.1
UN1509
II
5.1
IB6, IP2, T3, TP33
152
212
242
5 kg
25 kg
A
13, 52, 66, 75
Strontium phosphide
4.3
UN2013
I
4.3, 6.1
A19, N40
None
211
None
Forbidden
15 kg
E
40, 52, 85
Strychnine
or
Strychnine salts
6.1
UN1692
I
6.1
IB7, IP1, T6, TP33
None
211
242
5 kg
50 kg
A
40
Styphnic acid,
see
Trinitroresorcinol,
etc
Styrene monomer, stabilized
3
UN2055
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
G
Substances, explosive, n.o.s.
1.1L
UN0357
II
1.1L
101
None
62
None
Forbidden
Forbidden
8E, 14E, 15E, 17E
G
Substances, explosive, n.o.s.
1.2L
UN0358
II
1.2L
101
None
62
None
Forbidden
Forbidden
8E, 14E, 15E, 17E
G
Substances, explosive, n.o.s.
1.3L
UN0359
II
1.3L
101
None
62
None
Forbidden
Forbidden
8E, 14E, 15E, 17E
G
Substances, explosive, n.o.s.
1.1A
UN0473
II
1.1A
101, 111
None
62
None
Forbidden
Forbidden
12
G
Substances, explosive, n.o.s.
1.1C
UN0474
II
1.1C
101
None
62
None
Forbidden
Forbidden
10
G
Substances, explosive, n.o.s.
1.1D
UN0475
II
1.1D
101
None
62
None
Forbidden
Forbidden
10
G
Substances, explosive, n.o.s.
1.1G
UN0476
II
1.1G
101
None
62
None
Forbidden
Forbidden
08
G
Substances, explosive, n.o.s.
1.3C
UN0477
II
1.3C
101
None
62
None
Forbidden
Forbidden
10
G
Substances, explosive, n.o.s.
1.3G
UN0478
II
1.3G
101
None
62
None
Forbidden
Forbidden
08
G
Substances, explosive, n.o.s.
1.4C
UN0479
II
1.4C
101
None
62
None
Forbidden
75 kg
09
G
Substances, explosive, n.o.s.
1.4D
UN0480
II
1.4D
101
None
62
None
Forbidden
75 kg
09
G
Substances, explosive, n.o.s.
1.4S
UN0481
II
1.4S
101
None
62
None
25 kg
75 kg
05
G
Substances, explosive, n.o.s.
1.4G
UN0485
II
1.4G
101
None
62
None
Forbidden
75 kg
08
G
Substances, explosive, very insensitive, n.o.s.,
or
Substances, EVI, n.o.s.
1.5D
UN0482
II
1.5D
101
None
62
None
Forbidden
Forbidden
10
Substituted nitrophenol pesticides, liquid, flammable, toxic,
flash point less than 23 degrees C
3
UN2780
I
3, 6.1
T14, TP2, TP13, TP27
None
201
243
Forbidden
30 L
B
40
II
3, 6.1
IB2, T11, TP2, TP13, TP27
150
202
243
1 L
60 L
B
40
Substituted nitrophenol pesticides, liquid, toxic
6.1
UN3014
I
6.1
T14, TP2, TP13, TP27
None
201
243
1 L
30 L
B
40
II
6.1
IB2, T11, TP2, TP13, TP27
153
202
243
5 L
60 L
B
40
III
6.1
IB3, T7, TP2, TP28
153
203
241
60 L
220 L
A
40
Substituted nitrophenol pesticides, liquid, toxic, flammable,
flash point not less than 23 degrees C
Tin chloride, fuming, see
Stannic chloride, anhydrous
Tin perchloride or Tin tetrachloride, see
Stannic chloride, anhydrous
Tinctures, medicinal
3
UN1293
II
3
IB2, T4, TP1, TP8
150
202
242
5 L
60 L
B
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Tinning flux, see
Zinc chloride
Titanium disulphide
4.2
UN3174
III
4.2
IB8, IP3, T1, TP33
None
213
241
25 kg
100 kg
A
Titanium hydride
4.1
UN1871
II
4.1
A19, A20, IB4, N34, T3, TP33
None
212
241
15 kg
50 kg
E
Titanium powder, dry
4.2
UN2546
I
4.2
None
211
242
Forbidden
Forbidden
D
II
4.2
A19, A20, IB6, IP2, N5, N34, T3, TP33
None
212
241
15 kg
50 kg
D
III
4.2
IB8, IP3, T1, TP33
None
213
241
25 kg
100 kg
D
Titanium powder, wetted
with not less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns
4.1
UN1352
II
4.1
A19, A20, IB6, IP2, N34, T3, TP33
None
212
240
15 kg
50 kg
E
74
Titanium sponge granules
or
Titanium sponge powders
Titanium trichloride, pyrophoric
or
Titanium trichloride mixtures, pyrophoric
4.2
UN2441
I
4.2, 8
N34
None
181
244
Forbidden
Forbidden
D
40
TNT mixed with aluminum, see
Tritonal
TNT,
see
Trinitrotoluene,
etc
Toluene
3
UN1294
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
B
+
Toluene diisocyanate
6.1
UN2078
II
6.1
IB2, T7, TP2, TP13
153
202
243
5 L
60 L
D
25, 40
Toluene sulfonic acid, see
Alkyl,
or
Aryl sulfonic acid
etc
+
Toluidines, liquid
6.1
UN1708
II
6.1
IB2, T7, TP2
153
202
243
5 L
60 L
A
Toluidines, solid
6.1
UN3451
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
2,4-Toluylenediamine, solid
or
2,4-Toluenediamine, solid
6.1
UN1709
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
2,4-Toluylenediamine solution
or
2,4-Toluenediamine solution
6.1
UN3418
III
6.1
IB3, T4, TP1
153
203
241
60 L
220 L
A
Torpedoes, liquid fueled,
with inert head
1.3J
UN0450
II
1.3J
62
None
Forbidden
Forbidden
04
23E
Torpedoes, liquid fueled,
with or without bursting charge
1.1J
UN0449
II
1.1J
62
None
Forbidden
Forbidden
04
23E
Torpedoes
with bursting charge
1.1E
UN0329
II
1.1E
62
None
Forbidden
Forbidden
03
( printed page 34819)
Torpedoes
with bursting charge
1.1F
UN0330
II
1.1F
62
None
Forbidden
Forbidden
08
Torpedoes
with bursting charge
1.1D
UN0451
II
1.1D
62
None
Forbidden
Forbidden
03
G
Toxic by inhalation liquid, n.o.s.
with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50
Toxic by inhalation liquid, n.o.s.
with an inhalation toxicity toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50
Toxic by inhalation liquid, flammable, n.o.s.
with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50
Toxic by inhalation liquid, flammable, n.o.s.
with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50
Toxic by inhalation liquid, water-reactive, n.o.s.
with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50
6.1
UN3385
I
6.1, 4.3
1, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44
None
226
244
Forbidden
Forbidden
D
40
G
Toxic by inhalation liquid, water-reactive, n.o.s.
with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50
6.1
UN3386
I
6.1, 4.3
2, B9, B14, B32, B74, T20, TP2, TP13, TP38, TP44
None
227
244
Forbidden
Forbidden
D
40
G
Toxic by inhalation liquid, oxidizing, n.o.s.
with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50
6.1
UN3387
I
6.1, 5.1
1, B9, B14, B30, B72, T22, TP2, TP13, TP38, TP44
None
226
244
Forbidden
Forbidden
D
40
G
Toxic by inhalation liquid, oxidizing, n.o.s.
with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50
6.1
UN3388
I
6.1, 5.1
2, B9, B14, B32, T20, TP2, TP13, TP38, TP44
None
227
244
Forbidden
Forbidden
D
40
G
Toxic by inhalation liquid, corrosive, n.o.s.
with an inhalation toxicity lower than or equal to 200 ml/m3 and saturated vapor concentration greater than or equal to 500 LC50
Toxic by inhalation liquid, corrosive, n.o.s.
with an inhalation toxicity lower than or equal to 1000 ml/m3 and saturated vapor concentration greater than or equal to 10 LC50
Trinitroresorcinol
or
Styphnic acid,
dry or wetted with less than 20 percent water, or mixture of alcohol and water, by mass
1.1D
UN0219
II
1.1D
None
62
None
Forbidden
Forbidden
10
5E
Trinitroresorcinol, wetted
or
Styphnic acid, wetted
with not less than 20 percent water, or mixture of alcohol and water by mass
1.1D
UN0394
II
1.1D
None
62
None
Forbidden
Forbidden
10
5E
2,4,6-Trinitroso-3-methyl nitraminoanisole
Forbidden
Trinitrotetramine cobalt nitrate
Forbidden
Trinitrotoluene and Trinitrobenzene mixtures
or
TNT and trinitrobenzene mixtures
or
TNT and hexanitrostilbene mixtures
or
Trinitrotoluene and hexanitrostilnene mixtures
1.1D
UN0388
II
1.1D
None
62
None
Forbidden
Forbidden
10
Trinitrotoluene mixtures containing Trinitrobenzene and Hexanitrostilbene
or
TNT mixtures containing trinitrobenzene and hexanitrostilbene
1.1D
UN0389
II
1.1D
None
62
None
Forbidden
Forbidden
10
Trinitrotoluene
or
TNT,
dry or wetted with less than 30 percent water, by mass
1.1D
UN0209
II
1.1D
None
62
None
Forbidden
Forbidden
10
Trinitrotoluene (TNT), wetted,
with not less than 10 percent water by mass
4.1
UN3366
I
4.1
162, A8, A19, N41, N84
None
211
None
0.5 kg
0.5 kg
E
36
Trinitrotoluene, wetted
with not less than 30 percent water, by mass
4.1
UN1356
I
4.1
23, A2, A8, A19, N41
None
211
None
0.5 kg
0.5 kg
E
28
Tripropylamine
3
UN2260
III
3, 8
B1, IB3, T4, TP1
150
203
242
5 L
60 L
A
40
Tripropylene
3
UN2057
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
B
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Tris-(1-aziridinyl)phosphine oxide, solution
6.1
UN2501
II
6.1
IB2, T7, TP2
153
202
243
5 L
60 L
A
III
6.1
IB3, T4, TP1
153
203
241
60 L
220 L
A
Tris, bis-bifluoroamino diethoxy propane (TVOPA)
Forbidden
Tritonal
1.1D
UN0390
II
1.1D
None
62
None
Forbidden
Forbidden
10
Tungsten hexafluoride
2.3
UN2196
2.3, 8
2
None
338
None
Forbidden
Forbidden
D
40
Turpentine
3
UN1299
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Turpentine substitute
3
UN1300
I
3
T11, TP1, TP8, TP27
None
201
243
1 L
30 L
B
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
B
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Undecane
3
UN2330
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
( printed page 34823)
Urea hydrogen peroxide
5.1
UN1511
III
5.1, 8
A1, A7, A29, IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
13
Urea nitrate,
dry or wetted with less than 20 percent water, by mass
1.1D
UN0220
II
1.1D
119
None
62
None
Forbidden
Forbidden
10
Urea nitrate, wetted,
with not less than 10 percent water by mass
4.1
UN3370
I
4.1
162, A8, A19, N41, N84
None
211
None
0.5 kg
0.5 kg
E
36
Urea nitrate, wetted
with not less than 20 percent water, by mass
4.1
UN1357
I
4.1
23, 39, A8, A19, N41
None
211
None
1 kg
15 kg
E
28, 36
Urea peroxide, see
Urea hydrogen peroxide
Valeraldehyde
3
UN2058
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
B
Valeric acid, see
Corrosive liquids, n.o.s.
Valeryl chloride
8
UN2502
II
8, 3
A3, A6, A7, B2, IB2, N34, T7, TP2
154
202
243
1 L
30 L
C
40
Vanadium compound, n.o.s.
6.1
UN3285
I
6.1
IB7, IP1, T6, TP33
None
211
242
5 kg
50 kg
B
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
B
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
Vanadium oxytrichloride
8
UN2443
II
8
A3, A6, A7, B2, B16, IB2, N34, T7, TP2
154
202
242
Forbidden
30 L
C
40
Vanadium pentoxide,
non-fused form
6.1
UN2862
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
40
Vanadium tetrachloride
8
UN2444
I
8
A3, A6, A7, B4, N34, T10, TP2
None
201
243
Forbidden
2.5 L
C
40
Vanadium trichloride
8
UN2475
III
8
IB8, IP3, T1, TP33
154
213
240
25 kg
100 kg
A
40
Vanadyl sulfate
6.1
UN2931
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Vehicle, flammable gas powered
9
UN3166
9
135, 157
220
220
220
Forbidden
No limit
A
Vehicle, flammable liquid powered
9
UN3166
9
135, 157
220
220
220
No limit
No limit
A
Very signal cartridge, see
Cartridges, signal
Vinyl acetate, stabilized
3
UN1301
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
B
Vinyl bromide, stabilized
2.1
UN1085
2.1
T50
306
304
314, 315
Forbidden
150 kg
B
40
Vinyl butyrate, stabilized
3
UN2838
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
B
Vinyl chloride, stabilized
2.1
UN1086
2.1
21, B44, T50
306
304
314, 315
Forbidden
150 kg
B
40
Vinyl chloroacetate
6.1
UN2589
II
6.1, 3
IB2, T7, TP2
153
202
243
5 L
60 L
A
Vinyl ethyl ether, stabilized
3
UN1302
I
3
A3, T11, TP2
None
201
243
1 L
30 L
D
Vinyl fluoride, stabilized
2.1
UN1860
2.1
306
304
314, 315
Forbidden
150 kg
E
40
Vinyl isobutyl ether, stabilized
3
UN1304
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
B
Vinyl methyl ether, stabilized
2.1
UN1087
2.1
B44, T50
306
304
314, 315
Forbidden
150 kg
B
40
Vinyl nitrate polymer
Forbidden
Vinylidene chloride, stabilized
3
UN1303
I
3
T12, TP2, TP7
150
201
243
1 L
30 L
E
40
Vinylpyridines, stabilized
6.1
UN3073
II
6.1, 3, 8
IB1, T7, TP2, TP13
153
202
243
1 L
30 L
B
40
Vinyltoluenes, stabilized
3
UN2618
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Vinyltrichlorosilane, stabilized
3
UN1305
I
3, 8
A3, A7, B6, N34, T11, TP2, TP13
None
201
243
Forbidden
2.5 L
B
40
Warheads, rocket
with burster or expelling charge
1.4D
UN0370
II
1.4D
None
62
None
Forbidden
75 kg
02
Warheads, rocket
with burster or expelling charge
1.4F
UN0371
II
1.4F
None
62
None
Forbidden
Forbidden
08
Warheads, rocket
with bursting charge
1.1D
UN0286
II
1.1D
None
62
None
Forbidden
Forbidden
03
Warheads, rocket
with bursting charge
1.2D
UN0287
II
1.2D
None
62
None
Forbidden
Forbidden
03
Warheads, rocket
with bursting charge
1.1F
UN0369
II
1.1F
None
62
None
Forbidden
Forbidden
08
Warheads, torpedo
with bursting charge
1.1D
UN0221
II
1.1D
None
62
None
Forbidden
Forbidden
03
G
Water-reactive liquid, corrosive, n.o.s.
4.3
UN3129
I
4.3, 8
None
201
243
Forbidden
1 L
D
II
4.3, 8
IB1
None
202
243
1 L
5 L
E
85
III
4.3, 8
IB2
None
203
242
5 L
60 L
E
G
Water-reactive liquid, n.o.s.
4.3
UN3148
I
4.3
None
201
244
Forbidden
1 L
E
40
II
4.3
IB1
None
202
243
1 L
5 L
E
40
III
4.3
IB2
None
203
242
5 L
60 L
E
40
G
Water-reactive liquid, toxic, n.o.s.
4.3
UN3130
I
4.3, 6.1
A4
None
201
243
Forbidden
1 L
D
II
4.3, 6.1
IB1
None
202
243
1 L
5 L
E
85
III
4.3, 6.1
IB2
None
203
242
5 L
60 L
E
85
G
Water-reactive solid, corrosive, n.o.s.
4.3
UN3131
I
4.3, 8
IB4, IP1, N40
None
211
242
Forbidden
15 kg
D
II
4.3, 8
IB6, IP2, T3, TP33
151
212
242
15 kg
50 kg
E
85
III
4.3, 8
IB8, IP4, T1, TP33
151
213
241
25 kg
100 kg
E
85
( printed page 34824)
G
Water-reactive solid, flammable, n.o.s.
4.3
UN3132
I
4.3, 4.1
IB4, N40
None
211
242
Forbidden
15 kg
D
II
4.3, 4.1
IB4, T3, TP33
151
212
242
15 kg
50 kg
E
III
4.3, 4.1
IB6, T1, TP33
151
213
241
25 kg
100 kg
E
G
Water-reactive solid, n.o.s.
4.3
UN2813
I
4.3
IB4, N40
None
211
242
Forbidden
15 kg
E
40
II
4.3
IB7, IP2, T3, TP33
151
212
242
15 kg
50 kg
E
40
III
4.3
IB8, IP4, T1, TP33
151
213
241
25 kg
100 kg
E
40
G
Water-reactive, solid, oxidizing, n.o.s.
4.3
UN3133
II
4.3, 5.1
None
214
214
Forbidden
Forbidden
E
40
III
4.3, 5.1
None
214
214
Forbidden
Forbidden
E
40
G
Water-reactive solid, self-heating, n.o.s.
4.3
UN3135
I
4.3, 4.2
N40
None
211
242
Forbidden
15 kg
E
II
4.3, 4.2
IB5, IP2, T3, TP33
None
212
242
15 kg
50 kg
E
III
4.3, 4.2
IB8, IP4, T1, TP33
None
213
241
25 kg
100 kg
E
G
Water-reactive solid, toxic, n.o.s.
4.3
UN3134
I
4.3, 6.1
A8, IB4, IP1, N40
None
211
242
Forbidden
15 kg
D
II
4.3, 6.1
IB5, IP2, T3, TP33
151
212
242
15 kg
50 kg
E
85
III
4.3, 6.1
IB8, IP4, T1, TP33
151
213
241
25 kg
100 kg
E
85
Wheel chair, electric, see
Battery powered vehicle
or
Battery powered equipment
White acid, see
Hydrofluoric acid
I
White asbestos
(chrysotile, actinolite, anthophyllite, tremolite)
9
UN2590
III
9
156, IB8, IP2, IP3, T1, TP33
155
216
240
200 kg
200 kg
A
34, 40
Wood preservatives, liquid
3
UN1306
II
3
149, IB2, T4, TP1, TP8
150
202
242
5 L
60 L
B
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
40
A I W
Wool waste, wet
4.2
UN1387
III
4.2
151
213
240
Forbidden
Forbidden
A
Xanthates
4.2
UN3342
II
4.2
IB6, IP2, T3, TP33
None
212
241
15 kg
50 kg
D
40
III
4.2
IB8, IP3, T1, TP33
None
213
241
25 kg
100 kg
D
40
Xenon
2.2
UN2036
2.2
306
302
None
75 kg
150 kg
A
Xenon, refrigerated liquid
(cryogenic liquids)
2.2
UN2591
2.2
T75, TP5
320
None
None
50 kg
500 kg
B
Xylenes
3
UN1307
II
3
IB2, T4, TP1
150
202
242
5 L
60 L
B
III
3
B1, IB3, T2, TP1
150
203
242
60 L
220 L
A
Xylenols, solid
6.1
UN2261
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Xylenols, liquid
6.1
UN3430
II
6.1
IB2, T7, TP2
153
202
243
5 L
60 L
A
Xylidines, liquid
6.1
UN1711
II
6.1
IB2, T7, TP2
153
202
243
5 L
60 L
A
Xylidines, solid
6.1
UN3452
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Xylyl bromide, liquid
6.1
UN1701
II
6.1
A3, A6, A7, IB2, N33, T7, TP2, TP13
None
340
None
Forbidden
60 L
D
40
Xylyl bromide, solid
6.1
UN3417
II
6.1
A3, A6, A7, IB8, IP2, IP4, N33, T3, TP33
None
340
None
Forbidden
100 kg
B
40
p-Xylyl diazide
Forbidden
Zinc ammonium nitrite
5.1
UN1512
II
5.1
IB8, IP4, T3, TP33
None
212
242
5 kg
25 kg
E
Zinc arsenate
or
Zinc arsenite
or
Zinc arsenate and zinc arsenite mixtures
6.1
UN1712
II
6.1
IB8, IP2, IP4, T3, TP33
153
212
242
25 kg
100 kg
A
Zinc ashes
4.3
UN1435
III
4.3
A1, A19, IB8, IP4, T1, TP33
151
213
241
25 kg
100 kg
A
Zinc bisulfite solution, see
Bisulfites, aqueous solutions, n.o.s.
Zinc bromate
5.1
UN2469
III
5.1
A1, A29, IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
56, 58
( printed page 34825)
Zinc chlorate
5.1
UN1513
II
5.1
A9, IB8, IP2, IP4, N34, T3, TP33
152
212
242
5 kg
25 kg
A
56, 58
Zinc chloride, anhydrous
8
UN2331
III
8
IB8, IP3, T1, TP33
None
213
240
25 kg
100 kg
A
Zinc chloride, solution
8
UN1840
III
8
IB3, T4, TP1
154
203
241
5 L
60 L
A
Zinc cyanide
6.1
UN1713
I
6.1
IB7, IP1, T6, TP33
None
211
242
5 kg
50 kg
A
52
Zinc dithionite
or
Zinc hydrosulfite
9
UN1931
III
None
IB8, IP3, T1, TP33
155
204
240
100 kg
200 kg
A
49
Zinc ethyl, see
Diethylzinc
Zinc fluorosilicate
6.1
UN2855
III
6.1
IB8, IP3, T1, TP33
153
213
240
100 kg
200 kg
A
52
Zinc hydrosulfite,
see
Zinc dithionite
Zinc muriate solution, see
Zinc chloride, solution
Zinc nitrate
5.1
UN1514
II
5.1
IB8, IP4, T3, TP33
152
212
240
5 kg
25 kg
A
Zinc permanganate
5.1
UN1515
II
5.1
IB6, IP2, T3, TP33
152
212
242
5 kg
25 kg
D
56, 58, 138
Zinc peroxide
5.1
UN1516
II
5.1
IB6, IP2, T3, TP33
152
212
242
5 kg
25 kg
A
13, 52, 66, 75
Zinc phosphide
4.3
UN1714
I
4.3, 6.1
A19, N40
None
211
None
Forbidden
15 kg
E
40, 52, 85
Zinc powder
or
Zinc dust
4.3
UN1436
I
4.3, 4.2
A19, IB4, IP1, N40
None
211
242
Forbidden
15 kg
A
52, 53
II
4.3, 4.2
A19, IB7, IP2, T3, TP33
None
212
242
15 kg
50 kg
A
52, 53
III
4.3, 4.2
IB8, IP4, T1, TP33
None
213
242
25 kg
100 kg
A
52, 53
Zinc resinate
4.1
UN2714
III
4.1
A1, IB6, T1, TP33
151
213
240
25 kg
100 kg
A
Zinc selenate, see
Selenates
or
Selenites
Zinc selenite, see
Selenates
or
Selenites
Zinc silicofluoride, see
Zinc fluorosilicate
Zirconium, dry,
coiled wire, finished metal sheets, strip (thinner than 254 microns but not thinner than 18 microns)
4.1
UN2858
III
4.1
A1
151
213
240
25 kg
100 kg
A
Zirconium, dry,
finished sheets, strip or coiled wire
4.2
UN2009
III
4.2
A1, A19
None
213
240
25 kg
100 kg
D
Zirconium hydride
4.1
UN1437
II
4.1
A19, A20, IB4, N34, T3, TP33
None
212
240
15 kg
50 kg
E
Zirconium nitrate
5.1
UN2728
III
5.1
A1, A29, IB8, IP3, T1, TP33
152
213
240
25 kg
100 kg
A
Zirconium picramate,
dry or wetted with less than 20 percent water, by mass
1.3C
UN0236
II
1.3C
None
62
None
Forbidden
Forbidden
10
5E
Zirconium picramate, wetted
with not less than 20 percent water, by mass
4.1
UN1517
I
4.1
23, N41
None
211
None
1 kg
15 kg
D
28, 36
Zirconium powder, dry
4.2
UN2008
I
4.2
T21, TP7, TP33
None
211
242
Forbidden
Forbidden
D
II
4.2
A19, A20, IB6, IP2, N5, N34, T3, TP33
None
212
241
15 kg
50 kg
D
III
4.2
IB8, IP3, T1, TP33
None
213
241
25 kg
100 kg
D
Zirconium powder, wetted
with not less than 25 percent water (a visible excess of water must be present) (a) mechanically produced, particle size less than 53 microns; (b) chemically produced, particle size less than 840 microns
4.1
UN1358
II
4.1
A19, A20, IB6, IP2, N34, T3, TP33
None
212
241
15 kg
50 kg
E
74
Zirconium scrap
4.2
UN1932
III
4.2
IB8, IP3, N34, T1, TP33
None
213
240
Forbidden
Forbidden
D
Zirconium suspended in a liquid
3
UN1308
I
3
None
201
243
Forbidden
Forbidden
B
II
3
IB2
None
202
242
5 L
60 L
B
III
3
B1, IB2
150
203
242
60 L
220 L
B
Zirconium tetrachloride
8
UN2503
III
8
IB8, IP3, T1, TP33
154
213
240
25 kg
100 kg
A
( printed page 34826)
* * * * *
10. In Appendix B to § 172.101, the List of Marine Pollutants is amended by removing three entries, revising one entry and adding one entry in appropriate alphabetical order to read as follows:
Appendix B to § 172.101—List of Marine Pollutants
* * * * *
List of Marine Pollutants
S, M, P
Marine Pollutant
(1)
(2)
[Remove:]
Isoamyl mercaptan
Pentanethiols
Tetrachlorophenol
[Revise:]
PP
2, 6-Di-tert-Butylphenol
[Add:]
* * * * *
Chloropicrin
* * * * *
11. In § 172.102:
a. Paragraphs (b)(3), (b)(4) and (b)(8) are revised and a new paragraph (b)(9) is added.
b. In paragraph (c)(1), Special Provisions 47, 135, and 137 are revised; Special Provisions 163, 164, 165, 166, 167, 170 and 171 are added; and Special Provision 143 and 153 are removed.
c. In paragraph (c)(2), Special Provision A11 is revised and a new Special Provision A14 is added.
d. The introductory text of paragraph (c)(3) is revised; in paragraph (c)(3) Special Provision B69 is revised and paragraph (c)(4) is revised.
e. Paragraphs (c)(7)(viii) and (c)(8) are redesignated as paragraphs (c)(8) and (c)(9) respectively, the introductory paragraph of (c)(8) is revised, a new paragraph (c)(8)(ii) is added, Special Provisions TP3 and TP6 are revised and a new Special Provision TP32 is added.
(3) A code containing the letter “B” refers to a special provision that applies only to bulk packaging requirements. Unless otherwise provided in this subchapter, these special provisions do not apply to UN portable tanks or IBCs.
(4) A code containing the letters “IB” or “IP” refers to a special provision that applies only to transportation in IBCs.
* * * * *
(8) A code containing the letters “TP” refers to a special provision for UN portable tanks that is in addition to those provided by the portable tank instructions or the requirements in part 178 of this subchapter.
(9) A code containing the letter “W” refers to a special provision that applies only to transportation by water.
(c) * * *
(1) * * *
Code/Special Provisions
* * * * *
47 Mixtures of solids that are not subject to this subchapter and flammable liquids may be transported under this entry without first applying the classification criteria of Division 4.1, provided there is no free liquid visible at the time the material is loaded or at the time the packaging or transport unit is closed. Except when the liquids are fully absorbed in solid material contained in sealed bags, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. Small inner packagings consisting of sealed packets containing less than 10 mL of a Class 3 liquid in Packing Group II or III absorbed into a solid material are not subject to this subchapter provided there is no free liquid in the packet.
* * * * *
135 The entries “Vehicle, flammable gas powered” or “Vehicle, flammable liquid powered,” as appropriate, must be used when internal combustion engines are installed in a vehicle. These entries include hybrid electric vehicles powered by both an internal combustion engine and batteries.
* * * * *
137 Cotton, dry; flax, dry; and sisal, dry are not subject to the requirements of this subchapter when they are baled in accordance with ISO 8115, “Cotton Bales—Dimensions and Density” (IBR, see § 171.7 of this subchapter) to a density of not less than 360 kg/m 3
(22.1 lb/ft 3
) for cotton, 400 kg/m 3
(24.97 lb/ft 3
) for flax and 620 kg/m 3
(38.71 lb/ft 3
) for sisal and transported in a freight container or closed transport vehicle.
* * * * *
163 Substances must satisfactorily pass Test Series 8 of the UN Manual of Tests and Criteria, Part I, Section 18 (IBR,
see
§ 171.7 of this subchapter).
164 Substances must not be transported under this entry unless approved by the Associate Administrator on the basis of the results of appropriate tests according to Part I of the UN Manual of Tests and Criteria (IBR,
see
§ 171.7 of this subchapter). The material must be packaged so that the percentage of diluent does not fall below that stated in the approval, at any time during transportation.
165 These substances are susceptible to exothermic decomposition at elevated temperatures. Decomposition can be initiated by heat, moisture or by impurities (
e.g., powdered metals (iron, manganese, cobalt, magnesium)). During the course of transportation, packages containing these substances must be shaded from direct sunlight and all sources of heat and be placed in adequately ventilated areas.
166 When transported in non-friable tablet form calcium hypochlorite, dry or hydrated, may be transported as a Packing Group III material.
167 These storage systems shall always be considered as containing hydrogen.
170 Air must be eliminated from the vapor space by nitrogen or other means.
171 This entry may only be used when the material is transported in non-friable tablet form or for granular or powered mixtures that have been shown to meet the PG III criteria in § 173.127.
* * * * *
(2) “A” codes. These provisions apply only to transportation by aircraft:
Code/Special Provisions
* * * * *
A11 Only specification cylinders constructed of metals which are compatible with the hazardous material may be used.
* * * * *
A14 This material is not authorized to be transported as a limited quantity or consumer commodity in accordance with § 173.306 of this subchapter when transported aboard an aircraft.
* * * * *
(3) “B” codes. These provisions apply only to bulk packagings. Unless otherwise provided in this subchapter, these special provisions do not apply to UN portable tanks or IBCs:
Code/Special Provisions
* * * * *
B69 Dry sodium cyanide or potassium cyanide may be shipped in sift-proof weather-resistant metal covered hopper cars, covered motor vehicles, portable tanks or non-specification bins. Bins must be approved by the Associate Administrator.
* * * * *
(4) Table 1 and Table 2—IB Codes and IP Special IBC Packing Provisions. These provisions apply only to transportation in IBCs. When no IBC code is assigned in the § 172.101 Table for a specific proper shipping name, or
( printed page 34827)
in § 173.225(e) for Type F organic peroxides, an IBC may not be used unless authorized by the Associate Administrator. The letter “Z” shown in the marking code for composite IBCs must be replaced with a capital code letter designation found in § 178.702(a)(2) of this subchapter to specify the material used for the outer packaging. Tables 1 and 2 follow:
Table 1.—IB Codes (IBC Codes)
IBC code
Authorized IBCs
IB1
Authorized IBCs:
Metal (31A, 31B and 31N).
Additional Requirement:
Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized.
IB2
Authorized IBCs:
Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1).
Additional Requirement:
Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130kPa at 55 °C (1.3 bar at 131 °F) are authorized.
IB3
Authorized IBCs:
Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2).
Additional Requirement:
Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized, except for UN2672 (also see Special Provision IP8 in Table 3 for UN2672).
IB4
Authorized IBCs:
Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N).
IB5
Authorized IBCs:
Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 21HZ1 and 31HZ1).
IB6
Authorized IBCs:
Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2).
Additional Requirement:
Composite IBCs 11HZ2 and 21HZ2 may not be used when the hazardous materials being transported may become liquid during transport.
IB7
Authorized IBCs:
Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Wooden (11C, 11D and 11F).
Additional Requirement:
Liners of wooden IBCs must be sift-proof.
IB8
Authorized IBCs:
Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2).
IB9
IBCs are only authorized if approved by the Associate Administrator.
Table 2.—IP Codes
IP1
IBCs must be packed in closed freight containers or a closed transport vehicle.
IP2
When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle.
IP3
Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner.
IP4
Flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and water-resistant liner.
IP5
IBCs must have a device to allow venting. The inlet to the venting device must be located in the vapor space of the IBC under maximum filling conditions.
IP6
Non-specification bulk bins are authorized.
IP7
For UN identification numbers 1327, 1363, 1364, 1365, 1386, 1841, 2211, 2217, 2793 and 3314, IBCs are not required to meet the IBC performance tests specified in part 178, subpart N of this subchapter.
IP8
Ammonia solutions may be transported in rigid or composite plastic IBCs (31H1, 31H2 and 31HZ1) that have successfully passed, without leakage or permanent deformation, the hydrostatic test specified in § 178.814 of this subchapter at a test pressure that is not less than 1.5 times the vapor pressure of the contents at 55 °C (131 °F).
IP13
Transportation by vessel in IBCs is prohibited.
IP14
Air shall be eliminated from the vapor space by nitrogen or other means.
IP20
Dry sodium cyanide or potassium cyanide is also permitted in siftproof, water-resistant, fiberboard IBCs when transported in closed freight containers or transport vehicles.
* * * * *
(7)
“T” codes.
(i) These provisions apply to the transportation of hazardous materials in UN portable tanks. Portable tank instructions specify the requirements applicable to a portable tank when used for the transportation of a specific hazardous material. These requirements must be met in addition to the design and construction specifications in part 178 of this subchapter. Portable tank instructions T1 through T22 specify the applicable minimum test pressure, the minimum shell thickness (in reference steel), bottom opening requirements and pressure relief requirements. Liquefied compressed gases are assigned to portable tank instruction T50. Refrigerated liquefied gases that are authorized to be transported in portable tanks are specified in tank instruction T75.
(ii) The following table specifies the portable tank requirements applicable to “T” Codes T1 through T22. Column 1 specifies the “T” Code. Column 2 specifies the minimum test pressure, in bar (1 bar = 14.5 psig), at which the periodic hydrostatic testing required by § 180.605 of this subchapter must be conducted. Column 3 specifies the section reference for minimum shell thickness or, alternatively, the minimum shell thickness value. Column 4 specifies the applicability of § 178.275(g)(3) of this subchapter for the pressure relief devices. When the word “Normal” is indicated, § 178.275(g)(3) of this subchapter does not apply. Column 5 references the applicable requirements for bottom openings in part 178 of this subchapter or references “Prohibited” which means bottom openings are prohibited. The table follows:
( printed page 34828)
Table of Portable Tank T Codes T1-T22
[Portable tank codes T1-T22 apply to liquid and solid hazardous materials of Classes 3 through 9 which are transported in portable tanks.]
Portable tank
instruction
(1)
Minimum test
pressure (bar)
(2)
Minimum shell
thickness
(in mm-reference steel)
(
See
§ 178.274(d))
(3)
Pressure-relief
requirements
(
See
§ 178.275(g))
(4)
Bottom opening
requirements
(
See
§ 178.275(d))
(5)
T1
1.5
§ 178.274(d)(2)
Normal
§ 178.275(d)(2)
T2
1.5
§ 178.274(d)(2)
Normal
§ 178.275(d)(3)
T3
2.65
§ 178.274(d)(2)
Normal
§ 178.275(d)(2)
T4
2.65
§ 178.274(d)(2)
Normal
§ 178.275(d)(3)
T5
2.65
§ 178.274(d)(2)
§ 178.275(g)(3)
Prohibited
T6
4
§ 178.274(d)(2)
Normal
§ 178.275(d)(2)
T7
4
§ 178.274(d)(2)
Normal
§ 178.275(d)(3)
T8
4
§ 178.274(d)(2)
Normal
Prohibited
T9
4
6 mm
Normal
Prohibited
T10
4
6 mm
§ 178.275(g)(3)
Prohibited
T11
6
§ 178.274(d)(2)
Normal
§ 178.275(d)(3)
T12
6
§ 178.274(d)(2)
§ 178.275(g)(3)
§ 178.275(d)(3)
T13
6
6 mm
Normal
Prohibited
T14
6
6 mm
§ 178.275(g)(3)
Prohibited
T15
10
§ 178.274(d)(2)
Normal
§ 178.275(d)(3)
T16
10
§ 178.274(d)(2)
§ 178.275(g)(3)
§ 178.275(d)(3)
T17
10
6 mm
Normal
§ 178.275(d)(3)
T18
10
6 mm
§ 178.275(g)(3)
§ 178.275(d)(3)
T19
10
6 mm
§ 178.275(g)(3)
Prohibited
T20
10
8 mm
§ 178.275(g)(3)
Prohibited
T21
10
10 mm
Normal
Prohibited
T22
10
10 mm
§ 178.275(g)(3)
Prohibited
(iii)
T50.
When portable tank instruction T50 is referenced in Column (7) of the § 172.101 Table, the applicable liquefied compressed gases are authorized to be transported in portable tanks in accordance with the requirements of § 173.313 of this subchapter.
(iv)
T75.
When portable tank instruction T75 is referenced in Column (7) of the § 172.101 Table, the applicable refrigerated liquefied gases are authorized to be transported in portable tanks in accordance with the requirements of § 178.277 of this subchapter.
(v)
UN and IM portable tank codes/special provisions.
When a specific portable tank instruction is specified by a “T” Code in Column (7) of the § 172.101 Table for a specific hazardous material, a specification portable tank conforming to an alternative tank instruction may be used if:
(A) The alternative portable tank has a higher or equivalent test pressure (for example, 4 bar when 2.65 bar is specified);
(B) The alternative portable tank has greater or equivalent wall thickness (for example, 10 mm when 6 mm is specified);
(C) The alternative portable tank has a pressure relief device as specified in the “T” Code. If a frangible disc is required in series with the reclosing pressure relief device for the specified portable tank, the alternative portable tank must be fitted with a frangible disc in series with the reclosing pressure relief device; and
(D) With regard to bottom openings—
(1)
When two effective means are specified, the alternative portable tank is fitted with bottom openings having two or three effective means of closure or no bottom openings; or
(2)
When three effective means are specified, the portable tank has no bottom openings or three effective means of closure; or
(3)
When no bottom openings are authorized, the alternative portable tank must not have bottom openings.
(vi) Except when an organic peroxide is authorized under § 173.225(g), if a hazardous material is not assigned a portable tank “T” Code or TP9 is referenced in Column (7) of the § 172.101 Table, the hazardous material may not be transported in a portable tank unless approved by the Associate Administrator.
(8)
“TP” codes.
(i) These provisions apply to the transportation of hazardous materials in UN Specification portable tanks. Portable tank special provisions are assigned to certain hazardous materials to specify requirements that are in addition to those provided by the portable tank instructions or the requirements in part 178 of this subchapter. Portable tank special provisions are designated with the abbreviation TP (tank provision) and are assigned to specific hazardous materials in Column (7) of the § 172.101 Table.
(ii) The following is a list of the portable tank special provisions:
* * * * *
Code/Special Provisions
* * * * *
TP3 The maximum degree of filling (in %) for solids transported above their melting points and for elevated temperature liquids shall be determined by the following:
Where:
df
and dr
are the mean densities of the liquid at the mean temperature of the liquid during filling and the maximum mean bulk temperature during transport respectively.
* * * * *
TP6 The tank must be equipped with pressure release devices which prevent a tank from bursting under fire engulfment conditions (the conditions prescribed in CGA pamphlet S-1.2 (see § 171.7 of this subchapter) or alternative conditions approved by the Associate Administrator may be used to consider the fire engulfment condition), taking into account the properties of the hazardous material to be transported.
* * * * *
TP32 Portable tanks may be used subject to the following conditions:
( printed page 34829)
(a) Each portable tank constructed of metal must be fitted with a pressure-relief device consisting of a reclosing spring loaded type, a frangible disc or a fusible element. The set to discharge for the spring loaded pressure relief device and the burst pressure for the frangible disc, as applicable, must not be greater than 2.65 bar for portable tanks with minimum test pressures greater than 4 bar;
(b) The suitability for transport in tanks must be demonstrated using test 8 (d) in Test Series 8 (see UN Manual of Tests and Criteria, Part 1, Sub-section 18.7) (IBR, see § 171.7 of this subchapter) or an alternative means approved by the Associate Administrator.
* * * * *
12. In § 172.202, paragraph (a)(5)(i) is revised to read as follows:
Description of hazardous material on shipping papers.
(a) * * *
(5) * * *
(i) For Class I materials, the quantity must be the net explosive mass. For an explosive that is an article, such as Cartridges, small arms, the quantity must be the net mass of the article.
* * * * *
13. In § 172.203, paragraphs (f), (m)(2) and (o)(3) are revised and a new paragraph (i)(3) is added to read as follows:
(f)
Transportation by air.
A statement indicating that the shipment is within the limitations prescribed for either passenger and cargo aircraft or cargo aircraft only must be entered on the shipping paper.
* * * * *
(i) * * *
(3) For a hazardous material consigned under an “n.o.s.” entry not included in the segregation groups listed in section 3.1.4 of the IMDG Code but belonging, in the opinion of the consignor, to one of these groups, the appropriate segregation group must be shown in association with the basic description. When no segregation group is applicable, there is no requirement to indicate that condition.
(m) * * *
(2) For materials that are poisonous by inhalation (see § 171.8 of this subchapter), the words “Poison-Inhalation Hazard” or “Toxic-Inhalation Hazard” and the words “Zone A”, “Zone B”, “Zone C”, or “Zone D”, for gases or “Zone A” or “Zone B” for liquids, as appropriate, must be entered on the shipping description. The word “Poison” or “Toxic” or the phrase “Poison-Inhalation Hazard” or “Toxic Inhalation Hazard” need not be repeated if it otherwise appears in the shipping description.
* * * * *
(o) * * *
(3) The word “SAMPLE” must be included in association with the basic description when a sample of a Division 4.1 (self-reactive) material (
see
§ 173.224(c)(3) of this subchapter) or Division 5.2 (organic peroxide) material (
see
§ 173.225(b)(2) of this subchapter) is offered for transportation.
14. In § 172.204, paragraph (c)(3) is revised to read as follows:
(3)
Additional certification requirements.
Effective October 1, 2006, each person who offers a hazardous material for transportation by air must add to the certification required in this section the following statement:
“I declare that all of the applicable air transport requirements have been met.” Each person who offers any package or overpack of hazardous materials for transport by air must ensure that:
(a) The articles or substances are not prohibited for transport by air (see the § 172.101 Table);
(b) The articles or substances are properly classed, marked and labeled and otherwise in a condition for transport as required by this subchapter;
(c) The articles or substances are packaged in accordance with all the applicable air transport requirements, including appropriate types of packaging that conform to the packing requirements and the “A” Special Provisions in § 172.102; inner packaging and maximum quantity per package limits; the compatibility requirements (
see, for example, § 173.24 of this subchapter); and requirements for closure for both inner and outer packagings, absorbent materials, and pressure differential in § 173.27 of this subchapter. Other requirements may also apply. For example, single packagings may be prohibited, inner packaging may need to be packed in intermediate packagings, and certain materials may be required to be transported in packagings meeting a more stringent performance level.
(a)
General.
For transportation by aircraft, each package containing self-reactive substances of Division 4.1 or organic peroxides of Division 5.2 must be marked with the KEEP AWAY FROM HEAT handling mark specified in this section.
(b)
Location and design.
The marking must be a rectangle measuring at least 105 mm (4.1 inches) in height by 74 mm (2.9 inches) in width. Markings with not less than half this dimension are permissible where the dimensions of the package can only bear a smaller mark.
(c)
KEEP AWAY FROM HEAT handling mark.
The KEEP AWAY FROM HEAT handling mark must conform to the following:
(1) Except for size, the KEEP AWAY FROM HEAT handling mark must appear as follows:
( printed page 34830)
(2) The symbol, letters and border must be black and the background white, except for the starburst which must be red.
(3) The KEEP AWAY FROM HEAT handling marking required by paragraph (a) of this section must be durable, legible and displayed on a background of contrasting color.
(c)
Salvage drums.
Packages of hazardous materials that are damaged, defective, found to be not conforming to the requirements of this subchapter after having been placed in transportation, or found leaking, and hazardous materials that have spilled or leaked may be placed in a metal or plastic removable head salvage drum that is compatible with the lading and shipped for repackaging or disposal under the following conditions:
* * * * *
19. In § 173.24, paragraphs (g) and (i) are revised to read as follows:
(g)
Venting.
Venting of packagings, to reduce internal pressure which may develop by the evolution of gas from the contents, is permitted only when—
(1) Transportation by aircraft is not involved;
(2) Except as otherwise provided in this subchapter, the evolved gases are not poisonous, likely to create a flammable mixture with air or be an asphyxiant under normal conditions of transportation;
(3) The packaging is designed so as to preclude an unintentional release of hazardous materials from the receptacle;
(4) For bulk packagings, other than IBCs, venting is authorized for the specific hazardous material by a special provision in the § 172.101 table or by the applicable bulk packaging specification in part 178 of this subchapter; and
(5) Intermediate bulk packagings (IBCs) may be vented when required to reduce internal pressure that may develop by the evolution of gas subject to the requirements of paragraph (g)(1) through (g)(3) of this section. The IBC must be of a type that has successfully passed (with the vent in place) the applicable design qualification tests with no release of hazardous material.
* * * * *
(i)
Air transportation.
Packages offered or intended for transportation by aircraft are subject to requirements additional to those of other modes of transport (
e.g., quantity limitations, requirements for absorbent material, pressure differential requirements appropriate closure procedures, and specific packaging requirements) and must conform to the general requirements for transportation by aircraft in § 173.27.
20. In § 173.25, paragraphs (a)(2) and (a)(4) are revised to read as follows:
(2) The overpack is marked with the proper shipping and identification number, when applicable, and is labeled as required by this subchapter for each hazardous material contained therein, unless marking and labels representative of each hazardous material in the overpack are visible.
* * * * *
(4) The overpack is marked with the word “OVERPACK.” Alternatively, until October 1, 2007, the overpack is marked with a statement indicating that the “inside (inner) packages comply with prescribed specifications” when specification packagings are required, unless specification markings on the inside packages are visible.
* * * * *
21. In § 173.27, paragraph (i) is revised to read as follows:
General requirements for transportation by aircraft.
* * * * *
(i) Effective October 1, 2006, each person who offers a hazardous material for transportation by aircraft must include the certification statement specified in § 172.204(c)(3).
22. In § 173.28, paragraph (c)(2) is revised to read as follows:
(k) The following applies to aerosols (
see
§ 171.8 of this subchapter):
(1) An aerosols must be assigned to Division 2.1 if the contents include 85% by mass or more flammable components and the chemical heat of combustion is 30 kJ/g or more;
(2) An aerosol must be assigned to Division 2.2 if the contents contain 1% by mass or less flammable components and the heat of combustion is less than 20 kJ/g.
(3) Aerosols not meeting the provisions of (a) or (b) above must be classed in accordance with the appropriate tests of the UN Manual of Tests and Criteria (IBR,
see
§ 171.7 of this subchapter).
(4) Division 2.3 gases may not be transported in an aerosol container.
(5) When the contents are classified as Division 6.1 or Class 8, PG III, the aerosol must be assigned a subsidiary hazard of Division 6.1 or Class 8.
(6) Substances of Division 6.1 or Class 8 Packing Group I and Packing Group II may not be transported in an aerosol container.
(7) Flammable components are Class 3 flammable liquids, Class 4.1 flammable solids, or Division 2.2 flammable gases. The chemical heat of combustion must be determined in accordance with the UN Manual of Tests and Criteria (IBR,
see
§ 171.7 of this subchapter).
24. In § 173.128, paragraph (d)(1) is revised to read as follows:
(d)
Approvals.
(1) An organic peroxide must be approved, in writing, by the Associate Administrator, before being offered for transportation or transported, including assignment of a generic type and shipping description, except for—
(i) An organic peroxide which is identified by technical name in the Organic Peroxides Table in § 173.225(c);
(ii) A mixture of organic peroxides prepared according to § 173.225(b); or
(iii) An organic peroxide which may be shipped as a sample under the provisions of § 173.225(b).
* * * * *
25. In 173.132, paragraph (b)(1) is revised to read as follows:
(1) LD50
(median lethal dose) for acute oral toxicity is the statistically derived single dose of a substance that can be expected to cause death within 14 days in 50% of young adult albino rats when administered by the oral route. The LD50
value is expressed in terms of mass of test substance per mass of test animal (mg/kg).
* * * * *
26. In § 173.136, paragraph (d) is added to read as follows:
(d) Steel or aluminum corrosion test data produced no later than September 30, 2005, using the procedures of § 173.137(c)(2), in effect on September 30, 2004 (
see49 CFR 173.137 revised as of October 1, 2003), for appropriate steel or aluminum types may be used for classification and assignment of packing group for Class 8 materials corrosive to steel or aluminum.
27. In § 173.137, paragraph (c)(2) is revised to read as follows:
(2) That do not cause full thickness destruction of intact skin tissue but exhibit a corrosion on steel or aluminum surfaces exceeding 6.25 mm (0.25 inch) a year at a test temperature of 55 °C (130 °F). The corrosion must be determined in accordance with the UN Manual of Tests and Criteria (IBR,
see
§ 171.7 of this subchapter).
28. In § 173.150, paragraph (a), the introductory text of paragraph (b), paragraph (b)(2) and paragraph (c) are revised to read as follows:
Exceptions for Class 3 (flammable) and combustible liquids.
(a)
General.
Exceptions for hazardous materials shipments in the following paragraphs are permitted only if this section is referenced for the specific hazardous material in the §§ 172.101 Table of this subchapter.
(b)
Limited quantities.
Limited quantities of flammable liquids and combustible liquids are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized:
* * * * *
(2) For flammable liquids in Packing Group II, inner packagings not over 1.0 L (0.3 gallons) net capacity each, unless the material has a subsidiary hazard of Division 6.1, Packing Group II, in which case the inner packagings may not exceed 100 mL (3.38 ounces) net capacity each, packed in a strong outer packaging.
* * * * *
(c)
Consumer commodities.
Except for a material that has a subsidiary hazard of Division 6.1, Packing Group II, a limited quantity which conforms to the provisions of paragraph (b) of this section and is a ”consumer commodity” as defined in 171.8 of this subchapter, may be renamed ”Consumer commodity” and reclassed as ORM-D material. In addition to the exceptions provided by paragraph (b) of this section, shipments of ORM-D materials are not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or are offered for transportation and transported by aircraft, and are eligible for the exceptions provided in § 173.156.
* * * * *
29. In 173.151, paragraphs (b) and (c), and the introductory text of paragraph (d) are revised to read as follows:
(b)
Limited quantities of Division 4.1.
Limited quantities of flammable solids
( printed page 34832)
(Division 4.1) in Packing Group II or III are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized:
(1) For flammable solids in Packing Group II, inner packagings not over 1.0 kg (2.2 pounds) net capacity each, unless the material has a subsidiary hazard of Division 6.1, Packing Group II, in which case the inner packagings may not exceed 0.5 kg (1.1 pounds) net capacity each, packed in a strong outer packaging.
(2) For flammable solids in Packing Group III, inner packagings not over 5.0 kg (11 pounds) net capacity each, packed in a strong outer packaging.
(c)
Consumer commodities.
Except for a material that has a subsidiary hazard of Division 6.1, Packing Group II, a limited quantity which conforms to the provisions of paragraph (b) of this section, and charcoal briquettes in packagings not exceeding 30 kg (66 pounds) gross weight, may be renamed “Consumer commodity” and reclassed as ORM-D material if the material is a “consumer commodity” as defined in 171.8 of this subchapter. In addition to the exceptions provided by paragraph (b) of this section, shipments of ORM-D materials are not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or is offered for transportation and transported by aircraft, and are eligible for the exceptions provided in § 173.156.
(d)
Limited quantities of Division 4.3.
Limited quantities of dangerous when wet (Division 4.3) solids in Packing Group II or III are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized:
* * * * *
30. In § 173.152, the introductory text of paragraph (b), paragraph (b)(1), and paragraph (c) are revised to read as follows:
Exceptions for Division 5.1 (oxidizers) and Division 5.2 (organic peroxides).
* * * * *
(b)
Limited quantities.
Limited quantities of oxidizers (Division 5.1) in Packing Group II and III and organic peroxides are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized:
(1) For oxidizers in Packing Group II, inner packagings not over 1.0 L (0.3 gallon) net capacity each for liquids or not over 1.0 kg (2.2 pounds) net capacity each for solids, unless the material has a subsidiary hazard of Division 6.1, Packing Group II, in which case the inner packagings may not exceed 100 mL (3.38 ounces) for liquids or 0.5 kg (1.1 pounds) for solids, packed in a strong outer packaging.
* * * * *
(c)
Consumer commodities.
Except for a material that has a subsidiary hazard of Division 6.1, Packing Group II, a limited quantity which conforms to the provisions of paragraph (b) of this section, and is a “consumer commodity” as defined in § 171.8 of this subchapter, may be renamed ”Consumer commodity” and reclassed as ORM-D. In addition to the exceptions provided by paragraph (b) of this section, shipments of ORM-D materials are not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or are offered for transportation and transported by aircraft, and are eligible for the exceptions provided in § 173.156.
31. In § 173.153, paragraph (b), and paragraph (c)(1) are revised to read as follows:
Exceptions for Division 6.1 (poisonous materials).
* * * * *
(b)
Limited quantities.
The exceptions in this paragraph do not apply to poison-by-inhalation materials. Limited quantities of poisonous materials (Division 6.1) in Packing Group II and III are excepted from the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds) gross weight. The following combination packagings are authorized:
(1) For poisonous materials in Packing Group II, inner packagings not over 100 mL (3.38 ounces) each for liquids or 0.5 kg (1.1 pounds) each for solids, packed in a strong outer packaging.
(2) For poisonous materials in Packing Group III, inner packagings not over 4 L (1.0 gallon) each for liquids or 5.0 kg (11 pounds) each for solids, packed in a strong outer packaging.
(c) * * *
(1) A limited quantity of poisonous material in Packing Group III which conforms to the provisions of paragraph (b) of this section, and is a ”consumer commodity” as defined in § 171.8 of this subchapter, may be renamed “Consumer commodity” and reclassed as ORM-D.
* * * * *
32. In § 173.154, the introductory text of paragraph (b), paragraph (b)(1), and paragraph (c) are revised to read as follows:
(b)
Limited quantities.
Limited quantities of corrosive materials (Class 8) in Packing Group II and III are excepted from labeling requirements, unless the material also meets the definition of Division 6.1 or is offered for transportation or transported by aircraft, and the specification packaging requirements of this subchapter when packaged in combination packagings according to this paragraph. In addition, shipments of limited quantities are not subject to subpart F (Placarding) of part 172 of this subchapter. Each package must conform to the packaging requirements of subpart B of this part and may not exceed 30 kg (66 pounds)
( printed page 34833)
gross weight. The following combination packagings are authorized:
(1) For corrosive materials in Packing Group II, inner packagings not over 1.0 L (0.3 gallon) net capacity each for liquids or not over 1.0 kg (2.2 pounds) net capacity each for solids, unless the material has a subsidiary hazard of Division 6.1, Packing Group II in which case the inner packagings may not exceed 100 mL (3.38 ounces) for liquids or 0.5 kg (1.1 pounds) for solids, packed in a strong outer packaging.
* * * * *
(c)
Consumer commodities.
Except for a material that has a subsidiary hazard of Division 6.1, Packing Group II, a limited quantity which conforms to the provisions of paragraph (b) of this section, and is a ”consumer commodity” as defined in § 171.8 of this subchapter, may be renamed ”Consumer commodity” and reclassed as ORM-D. In addition to the exceptions provided by paragraph (b) of this section, shipments of ORM-D materials are not subject to the shipping paper requirements of subpart C of part 172 of this subchapter, unless the material meets the definition of a hazardous substance, hazardous waste, marine pollutant, or are offered for transportation and transported by aircraft, and are eligible for the exceptions provided in § 173.156.
* * * * *
33. In Section 173.185, paragraphs (c)(3) and (e)(6) are revised to read as follows:
(3) Each cell or battery is of the type proven to be non-dangerous by testing in accordance with Tests in the UN Manual of Tests and Criteria (IBR;
see
§ 171.7 of this subchapter). Such testing must be carried out on each type of cell or battery prior to the initial transport of that type. A cell or battery and equipment containing a cell or battery which was first transported prior to [INSERT EFFECTIVE DATE OF RULE] and is of a type proven to meet the criteria of Class 9 by testing in accordance with the tests in the UN Manual of Tests and Criteria, Third Revised Edition, 1999 is not required to be retested;
* * * * *
(e) * * *
(6) Each cell or battery is of the type proven to meet the lithium battery requirements in the UN Manual of Tests and Criteria (IBR;
see
§ 171.7 of this subchapter). A cell or battery and equipment containing a cell or battery which was first transported prior to [INSERT EFFECTIVE DATE OF RULE] and is of a type proven to meet the criteria of Class 9 by testing in accordance with the tests in the UN Manual of Tests and Criteria, Third Revised Edition, 1999 is not required to be retested;
* * * * *
34. In § 173.186, paragraph (e) is revised to read as follows:
(e) Packagings. Strike-anywhere matches must be tightly packed in securely closed chipboard, fiberboard, wooden, or metal inner packagings to prevent accidental ignition under conditions normally incident to transportation. Each inner packaging may contain no more than 700 strike-anywhere matches and must be packed in outer steel drums (1A2), aluminum drums (1B2), steel jerricans (3A2), wooden (4C1, 4C2), plywood (4D), reconstituted wood (4F) or fiberboard (4G) boxes, plywood (1D) or fiber (1G) drums. Gross weight of fiberboard boxes (4G) must not exceed 30 kg (66 pounds). Gross weight of other outer packagings must not exceed 45 kg (100 pounds).
35. In § 173.187, a new paragraph (f) is added to read as follows:
(a) A life-saving appliance, self-inflating or non-self-inflating, containing small quantities of hazardous materials that are required as part of the life-saving appliance must conform to the requirements of this section. Packagings must conform to the general packaging requirements of subpart B of this part but need not conform to the requirements of part 178 of this subchapter. The appliances must be packed, so that they cannot be accidentally activated and, except for life vests, the hazardous materials must be in inner packagings packed so as to prevent movement. The hazardous materials must be an integral part of the appliance and in quantities that do not exceed those appropriate for the actual appliance when in use.
(b) Life saving appliances may contain:
(1) Division 2.2 compressed gases, including oxygen. However, oxygen generators are not permitted;
(2) Signal devices (Class 1), which may include smoke and illumination signal flares;
(3) Electric storage batteries and lithium batteries (Life saving appliances containing lithium batteries must be transported in accordance with § 173.185.);
(4) First aid or repair kits conforming to the applicable material and quantity limitations of § 173.161 of this subchapter;
(5) Strike-anywhere matches;
(6) For self-inflating life saving appliances only, cartridges power device of Division 1.4S, for purposes of the self-inflating mechanism provided that the quantity of explosives per appliance does not exceed 3.2 g; or
(7) Limited quantities of other hazardous materials.
(c) Hazardous materials in life saving appliances must be packaged as follows:
(1) Division 2.2 compressed gases must be packaged in cylinders in accordance with the requirements of this subchapter;
(2) Signal devices (Class 1) must be in packagings that prevent them from being inadvertently activated;
(3) Strike-anywhere matches must be cushioned to prevent movement or friction in a metal or composition receptacle with a screw-type closure in a manner that prevents them from being inadvertently activated;
(4) Limited quantities of other hazardous materials must be packaged in accordance with the requirements of this subchapter; and
(5) For other than transportation by aircraft, life saving appliances containing no hazardous materials other than carbon dioxide cylinders with a capacity not exceeding 100 cm3
are not subject to the provisions of this subchapter provided they are overpacked in rigid outer packagings with a maximum gross mass of 40 kg.
40. In § 173.220, paragraph (b)(2) is revised to read as follows:
Internal combustion engines, self-propelled vehicles, mechanical equipment containing internal combustion engines, and battery powered vehicles or equipment.
* * * * *
(b) * * *
(2)
Flammable liquefied or compressed gas fuel.
(i) For transportation by motor vehicle, rail car or vessel, fuel tanks and fuel systems containing flammable liquefied or compressed gas fuel must be securely closed. For transportation by vessel, the requirements of §§ 176.78(k) and 176.905 of this subchapter apply.
(ii) For transportation by aircraft:
(A) Flammable gas-powered vehicles, machines, equipment or cylinders containing the flammable gas must be completely emptied of flammable gas. Lines from vessels to gas regulators, and gas regulators themselves, must also be drained of all traces of flammable gas. To ensure that these conditions are met, gas shut-off valves must be left open and connections of lines to gas regulators must be left disconnected upon delivery of the vehicle to the operator. Shut-off valves must be closed and lines reconnected at gas regulators before loading the vehicle aboard the aircraft; or alternatively
(B) Flammable gas powered vehicles, machines or equipment, which have cylinders (fuel tanks) that are equipped with electrically operated valves, may be transported under the following conditions:
(1) The valves must be in the closed position and in the case of electrically operated valves, power to those valves must be disconnected;
(2) After closing the valves, the vehicle, equipment or machinery must be operated until it stops from lack of fuel before being loaded aboard the aircraft;
(3) In no part of the system between the pressure receptacle and the shut off valve shall the pressure exceed more than 5% of the maximum allowable working pressure of the system; and
(4) There must not be any residual liquefied gas in the system, including the fuel tank.
41. In § 173.224, paragraph (b) (4) is revised to read as follows:
Packaging and control and emergency temperatures for self-reactive materials.
* * * * *
(b) * * *
(4)
Packing method.
Column 4 specifies the highest packing method which is authorized for the self-reactive material. A packing method corresponding to a smaller package size may be used, but a packing method corresponding to a larger package size may not be used. The Table of Packing Methods in § 173.225(d) defines the packing methods. Bulk packagings for Type F self-reactive substances are authorized by § 173.225(f) for IBCs and § 173.225(h) for bulk packagings other than IBCs. Additional bulk packagings
( printed page 34835)
are authorized if approved by the Associate Administrator.
* * * * *
42. Section 173.225 is revised to read as follows:
Packaging requirements and other provisions for organic peroxides.
(a)
General.
When the § 172.101 table specifies that an organic peroxide must be packaged under this section, the organic peroxide must be packaged and offered for transportation in accordance with the provisions of this section. Each packaging must conform to the general requirements of subpart B of part 173 and to the applicable requirements of part 178 of this subchapter. Non-bulk packagings must meet Packing Group II performance levels. To avoid unnecessary confinement, metallic non-bulk packagings meeting Packing Group I are not authorized. No used material, other than production residues or regrind from the same production process, may be used in plastic packagings. Organic peroxides that require temperature control are subject to the provisions of § 173.21(f). When an IBC or bulk packaging is authorized and meets the requirements of paragraph (f) or (h) of this section, respectively, lower control temperatures than those specified for non-bulk packaging may be required. An organic peroxide not identified in paragraph (c), (e), or (g) of this section by technical name or formulation of identified organic peroxides must conform to the provisions of paragraph (c) of § 173.128.
(b)
New organic peroxides, formulations and samples.
(1) Except as provided for samples in paragraph (b)(2) of this section, no person may offer for transportation an organic peroxide that is not identified by technical name in the Organic Peroxides Table, Organic Peroxide IBC Table, or the Organic Peroxide Portable Tank Table of this section, or a formulation of one or more organic peroxides that are identified by technical name in one of those tables, unless the organic peroxide is assigned a generic type and shipping description and is approved by the Associate Administrator under the provisions of § 173.128(d) of this subchapter.
(2)
Samples.
Samples of new organic peroxides or new formulations of organic peroxides identified in the Organic Peroxides Table in paragraph (c) of this section, for which complete test data are not available, and that are to be transported for further testing or product evaluation, may be assigned an appropriate shipping description for organic peroxide Type C, packaged and offered for transportation, under the following conditions:
(i) Data available to the person offering the material for transportation must indicate that the sample would pose a level of hazard no greater than that of an organic peroxide Type B and that the control temperature, if any, is sufficiently low to prevent any dangerous decomposition and sufficiently high to prevent any dangerous phase separation;
(ii) The sample must be packaged in accordance with packing method OP2, for a liquid or solid, respectively;
(iii) Packages of the organic peroxide may be offered for transportation and transported in a quantity not to exceed 10 kg (22 pounds) per transport vehicle; and
(iv) One of the following shipping descriptions must be assigned:
(A) Organic peroxide Type C, liquid, 5.2, UN 3103;
(B) Organic peroxide Type C, solid, 5.2, UN 3104;
(C) Organic peroxide Type C, liquid, temperature controlled, 5.2, UN 3113; or
(D) Organic peroxide Type C, solid, temperature controlled, 5.2, UN 3114.
(3)
Mixtures.
Mixtures of organic peroxides individually identified in the Organic Peroxides Table in paragraph (c) of this section may be classified as the same type of organic peroxide as that of the most dangerous component and be transported under the conditions for transportation given for this type. If the stable components form a thermally less stable mixture, the SADT of the mixture must be determined and the new control and emergency temperature derived under the provisions of § 173.21(f).
(c)
Organic peroxides table.
The following Organic Peroxides Table specifies by technical name those organic peroxides that are authorized for transportation and not subject to the approval provisions of § 173.128 of this part. An organic peroxide identified by technical name in the following table is authorized for transportation only if it conforms to all applicable provisions of the table. The column headings of the Organic Peroxides Table are as follows:
(1)
Technical name.
The first column specifies the technical name.
(2)
ID number.
The second column specifies the identification (ID) number which is used to identify the proper shipping name in the § 172.101 table. The word “EXEMPT” appearing in the column denotes that the material is not regulated as an organic peroxide.
(3)
Concentration of organic peroxide.
The third column specifies concentration (mass percent) limitations, if any, in mixtures or solutions for the organic peroxide. Limitations are given as minimums, maximums, or a range, as appropriate. A range includes the lower and upper limits (
i.e., “53-100” means from, and including, 53 % to, and including 100 %). See introductory paragraph of § 172.203(k) of this subchapter for additional description requirements for an organic peroxide that may qualify for more than one generic listing, depending on its concentration.
(4)
Concentration of diluents.
The fourth column specifies the type and concentration (mass percent) of diluent or inert solid, when required. Other types and concentrations of diluents may be used if approved by the Associate Administrator.
(i) The required mass percent of “Diluent type A” is specified in column 4a. A diluent type A is an organic liquid that does not detrimentally affect the thermal stability or increase the hazard of the organic peroxide and with a boiling point not less than 150 ° C at atmospheric pressure. Type A diluents may be used for desensitizing all organic peroxides.
(ii) The required mass percent of “Diluent type B” is specified in column 4b. A diluent type B is an organic liquid which is compatible with the organic peroxide and which has a boiling point, at atmospheric pressure, of less than 150 °C (302 °F) but at least 60 °C (140 °F), and a flash point greater than 5 °C (41 °F). Type B diluents may be used for desensitizing all organic peroxides, when specified in the organic peroxide tables, provided that the boiling point is at least 60 °C (140 °F) above the SADT of the peroxide in a 50 kg (110 lbs) package. A type A diluent may be used to replace a type B diluent in equal concentration.
(iii) The required mass percent of “Inert solid” is specified in column 4c. An inert solid is a solid that does not detrimentally affect the thermal stability or hazard of the organic peroxide.
(5)
Concentration of water.
Column 5 specifies, in mass percent, the minimum amount of water, if any, which must be in formulation.
(6)
Packing method.
Column 6 specifies the highest packing method (largest packaging capacity) authorized for the organic peroxide. Lower numbered packing methods (smaller packaging capacities) are also authorized. For example, if OP3 is specified, then OP2 and OP1 are also authorized. The Table of Packing Methods in paragraph (d) of this section defines the non-bulk packing methods.
(7)
Temperatures.
Column 7a specifies the control temperature. Column 7b specifies the emergency temperature. Temperatures are specified
( printed page 34836)
only when temperature controls are required. (
See
§ 173.21(f)).
(8)
Notes.
Column 8 specifies other applicable provisions, as set forth in notes following the table.
3. For concentrations <80% OP5 is allowed. For concentrations of at least 80% but <85%, OP4 is allowed. For concentrations of at least 85%, maximum package size is OP2.
4. The diluent may be replaced by di-tert-butyl peroxide.
5. Available oxygen must be ≤9%.
6. For domestic shipments, OP5 is authorized.
7. [Reserved]
8. Only non-metallic packagings are authorized.
9. [Reserved]
10. [Reserved]
11. [Reserved]
12. Samples may only be offered for transportation under the provisions of paragraph (c)(2) of this section.
13. “Corrosive” subsidiary risk label is required.
14. [Reserved]
15. No “Corrosive” subsidiary risk label is required for concentrations below 80%.
16. With 6% di-tert-butyl peroxide.
17. With ≥8% 1-isopropylhydroperoxy-4-isopropylhydroxybenzene.
18. Addition of water to this organic peroxide will decrease its thermal stability.
19. [Reserved]
20. Mixtures with hydrogen peroxide, water and acid(s).
21. With diluent type A, with or without water.
22. With ≥36% diluent type A by mass, and in addition ethylbenzene.
23. With ≥19% diluent type A by mass, and in addition methyl isobutyl ketone.
24. Diluent type B with boiling point >100 C.
25. No “Corrosive” subsidiary risk label is required for concentrations below 56%.
26. Available oxygen must be ≤7.6%.
27. Formulations derived from distillation of peroxyacetic acid originating from peroxyacetic acid in a concentration of not more than 41% with water, total active oxygen less than or equal to 9.5% (peroxyacetic acid plus hydrogen peroxide).
28. For the purposes of this section, the names “Peroxyacetic acid” and “Peracetic acid” are synonymous.
29. For international transportation, shipments of this material must be accompanied by a Competent Authority approval from the Associate Administrator.
(d)
Packing Method Table.
Packagings for organic peroxides and self-reactive substances are listed in the Maximum
( printed page 34841)
Quantity per Packing Method Table. The packing methods are designated OP1 to OP8. The quantities specified for each packing method represent the maximum that is authorized.
(1) The following types of packagings are authorized:
(iv) Composite packagings with a plastic inner receptacle: 6HA1, 6HA2, 6HB1, 6HB2, 6HC, 6HD1, 6HD2, 6HG1, 6HG2, 6HH1, 6HH2.
(2) Metal packaging (including inner packagings of combination packagings and outer packagings of combination or composite packagings) are used only for packing methods OP7 and OP8.
(3) In combination packagings, glass receptacles are used only as inner packagings with a maximum content of 0.5 kg for solids or 0.5 L for liquids.
(4) The maximum quantity per packaging or package for Packing Methods OP1-OP8 must be as follows:
Maximum Quantity per Packaging/Package for Packing Methods OP1 to OP8
Maximum Quantity
Packing Method
OP1
OP2
OP3
OP4 1
OP5
OP6
OP7
OP8
Solids and combination packagings (liquid and solid) (kg)
0.5
0.5/10
5
5
25
50
50
2
400
Liquids (L)
0.5
5
30
60
60
3
225
1
If two values are given, the first applies to the maximum net mass per inner packaging and the second to the maximum net mass of the complete package.
2
60 kg for jerricans/200 kg for boxes and, for solids, 400 kg in combination packagings with outer packagings comprising boxes (4C1, 4C2, 4D, 4F, 4G, 4H1, and 4H2) and with inner packagings of plastics or fiber with a maximum net mass of 25 kg.
3
60 L for jerricans.
(e)
Organic Peroxide IBC Table.
The following Organic Peroxide IBC Table specifies, by technical name, those organic peroxides that are authorized for transportation in certain IBCs and not subject to the approval provisions of § 173.128 of this part. Additional requirements for authorized IBCs are found in paragraph (f) of this section.
Organic Peroxide IBC Table
UN No.
Organic peroxide
Type of IBC
Maximum quantity (litres)
Control temperature
Emergency temperature
3109
ORGANIC PEROXIDE, TYPE F, LIQUID
tert-Butyl hydroperoxide, not more than 72% with water
31A
1250
tert-Butyl peroxyacetate, not more than 32% in diluent type A
31A
31HA1
1250
1000
tert-Butyl peroxy-3,5,5-trimethylhexanoate, not more than 32% in diluent type A
31A
31HA1
1250
1000
Cumyl hydroperoxide, not more than 90% in diluent type A
31HA1
1250
Dibenzoyl peroxide, not more than 42% as a stable dispersion
31H1
1000
Di-tert-butyl peroxide, not more than 52% in diluent type B
31A
31HA1
1250
1000
1,1-Di-(tert-butylperoxy) cyclohexane, not more than 42% in diluent type A
31H1
1000
Dicumyl peroxide, less than or equal to 100%
31A
31HA1
1250
1000
Dilauroyl peroxide, not more than 42%, stable dispersion, in water
31HA1
1000
Isopropyl cumyl hydroperoxide, not more than 72% in diluent type A
31HA1
1250
p-Menthyl hydroperoxide, not more than 72% in diluent type A
31HA1
1250
Peroxyacetic acid, stabilized, not more than 17%
31H1
31HA1
31A
1500
1500
1500
Peroxyacetic acid, with not more than 26% hydrogen peroxide
31A
31HA1
1500
1500
Peroxyacetic acid, type F, stabilized
31A
31HA1
1500
1500
3110
ORGANIC PEROXIDE TYPE F, SOLID
Dicumyl peroxide, less than or equal to 100%
31A
31H1
31HA1
2000
3119
ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED
tert-Butyl peroxy-2-ethylhexanoate, not more than 32% in diluent type B
31HA1
31A
1000
1250
+30 °C
+35 °C
tert-Butyl peroxyneodecanoate, not more than 32% in diluent type A
31A
1250
0 °C
+10 °C
tert-Butyl peroxyneodecanoate, not more than 42% stable dispersion, in water
31A
1250
−5 °C
+5 °C
( printed page 34842)
tert-Butyl peroxypivalate, not more than 27% in diluent type B
31HA1
31A
1000
1250
+10 °C
+15 °C
Cumyl peroxyneodecanoate, not more than 52%, stable dispersion, in water
31A
1250
−15 °C
−5 °C
Dicyclohexylperoxydicarbonate, not more than 42% as a stable dispersion, in water
31A
1250
+10 °C
+15 °C
Di-(4-tert-butylcyclohexyl) peroxydicarbonate, not more than 42%, stable dispersion, in water
31HA1
1000
+30 °C
+35 °C
Dicetyl peroxydicarbonate, not more than 42%, stable dispersion, in water
31HA1
1000
+30 °C
+35 °C
Di-(2-ethylhexyl) peroxydicarbonate, not more than 52%, stable dispersion, in water
31A
1250
−20 °C
−10 °C
Dimyristyl peroxydicarbonate, not more than 42%, stable dispersion, in water
31HA1
1000
+15 °C
+20 °C
Di-(3,5,5-trimethylhexanoyl) peroxide, not more than 38% in diluent type A
31HA1
31A
1000
1250
+10 °C
+15 °C
Di-(3,5,5-trimethylhexanoyl) peroxide, not more than 52%, stable dispersion, in water
31A
1250
+10 °C
+15 °C
1,1,3,3-Tetramethylbutyl peroxyneodecanoate, not more than 52%, stable dispersion, in water
31A
1250
−5 °C
+5 °C
(f)
IBCs.
IBCs are authorized subject to the conditions and limitations of this section if the IBC type is authorized according to paragraph (e) of this section, as applicable, and the IBC conforms to the requirements in subpart O of part 178 of this subchapter at the Packing Group II performance level. The additional requirements in paragraphs (h)(5)(i) and (h)(5)(ii) of this section also apply. Type F organic peroxides or self-reactive substances are not authorized for transportation in IBCs other than those specified, unless approved by the Associate Administrator.
(i) IBCs shall be provided with a device to allow venting during transportation. The inlet to the pressure relief device shall be sited in the vapor space of the IBC under maximum filling conditions during transportation.
(ii) To prevent explosive rupture of metal IBCs or composite IBCs with a complete metal casing, the emergency-relief devices shall be designed to vent all the decomposition products and vapors evolved during self-accelerating decomposition or during a period of not less than one hour of complete fire-engulfment as calculated by the formula in paragraph (h)(3)(v) of this section. The control and emergency temperatures specified in the Organic Peroxide IBC Table are based on a non-insulated IBC.
(g) Organic Peroxide Portable Tank Table. The following Organic Peroxide Portable Tank Table provides certain portable tank requirements and identifies, by technical name, those organic peroxides that are authorized for transportation in the bulk packagings listed in paragraph (h). Organic peroxides listed in this table, provided they meet the specific packaging requirements found in paragraph (h), are not subject to the approval provisions of § 173.128 of this part.
( printed page 34843)
Organic Peroxide Portable Tank Table
UN No.
Hazardous material
Minimum test pressure (bar)
Minimum shell thickness (mm-reference steel) See . . .
Bottom opening requirements See . . .
Pressure-relief requirements See . . .
Filling limits
Control temperature
Emergency temperature
3109
ORGANIC PEROXIDE, TYPE F, LIQUID
tert-Butyl more hydroperoxide, not more than 72% with water. * Provided that steps have been taken to achieve the safety equivalence of 65% tert-Butyl hydroperoxide and 35% water
4
§ 178.274(d)(2)
§ 178.275(d)(3)
§ 178.275(g)(1)
Not more than 90% at 59°F (15°C)
Cumyl hydro-peroxide, not more than 90% in diluent type A
4
§ 178.274(d)(2)
§ 178.275(d)(3)
§ 178.275(g)(1)
Not more than 90% at 59°F (15°C)
Di-tert-butyl peroxide, not more than 32% in diluent type A
4
§ 178.274(d)(2)
§ 178.275(d)(3)
§ 178.275(g)(1)
Not more than 90% at 59°F (15°C)
Dicumyl peroxide, less than or equal to 100% in diluent type B
4
§ 178.274(d)(2)
§ 178.275(d)(3)
§ 178.275(g)(1)
Not more than 90% at 59°F (15°C)
Isopropyl cumyl hydro-peroxide, not more than 72% in diluent type A
4
§ 178.274(d)(2)
§ 178.275(d)(3)
§ 178.275(g)(1)
Not more than 90% at 59°F (15°C)
p-Menthyl hydro-peroxide, not more than 72% in diluent type A
4
§ 178.274(d)(2)
§ 178.275(d)(3)
§ 178.275(g)(1)
Not more than 90% at 59°F (15°C)
Pinanyl hydro-peroxide, not more than 56% in diluent type A
4
§ 178.274(d)(2)
§ 178.275(d)(3)
§ 178.275(g)(1)
Not more than 90% at 59°F (15°C)
3110
ORGANIC PEROXIDE, TYPE F, SOLID
Dicumyl peroxide less than or equal to 100% with inert solids * Maximum quantity per portable tank 2,000 kg
4
§ 178.274(d)(2)
§ 178.275(d)(3)
§ 178.275(g)(1)
Not more than 90% at 59°F (15°C)
3119
ORGANIC PEROXIDE, TYPE F, LIQUID, TEMPERATURE CONTROLLED
tert-Butyl peroxyacetate, not more than 32% in diluent type B
4
§ 178.274(d)(2)
§ 178.275(d)(3)
§ 178.275(g)(1)
Not more than 90% at 59°F (15°C)
+30°C
+35°C
tert-Butyl peroxy-2-ethylhexanoate, not more than 32% in diluent type B
4
§ 178.274(d)(2)
§ 178.275(d)(3)
§ 178.275(g)(1)
Not more than 90% at 59°F (15°C)
+15°C
+20°C
tert-Butyl peroxypivalate, not more than 27% in diluent type B
4
§ 178.274(d)(2)
§ 178.275(d)(3)
§ 178.275(g)(1)
Not more than 90% at 59°F (15°C)
+5°C
+10°C
tert-Butyl peroxy-3,5,5-trimethyl-hexanoate, not more than 32% in diluent type B
4
§ 178.274(d)(2)
§ 178.275(d)(3)
§ 178.275(g)(1)
Not more than 90% at 59°F (15°C)
+35°C
+40°C
Di-(3,5,5-trimethyl-hexanoyl) peroxide, not more than 38% in diluent type A
4
§ 178.274(d)(2)
§ 178.275(d)(3)
§ 178.275(g)(1)
Not more than 90% at 59°F (15°C)
+0°C
+5°C
Peroxyacetic acid, distilled, stabilized, not more than 41%
4
§ 178.274(d)(2)
§ 178.275(d)(3)
§ 178.275(g)(1)
Not more than 90% at 59°F (15°C)
+30°C
+35°C
( printed page 34844)
(h)
Bulk packagings other than IBCs.
The following bulk packagings are authorized, subject to the conditions and limitations of this section, if the organic peroxide is listed in the Organic Peroxide Portable Tank Table and bulk packagings are authorized and the bulk packaging conforms to the requirements of this subchapter:
(1)
Rail cars.
Class DOT 103, 104, 105, 109, 111, 112, 114, 115, or 120 fusion-weld tank car tanks are authorized. DOT 103W, 111A60F1 and 111A60W1 tank car tanks must have bottom outlets effectively sealed from inside. Gauging devices are required on DOT 103W tank car tanks. Riveted tank car tanks are not authorized.
(2)
Cargo tanks.
Specification MC 307, MC 310, MC 311, MC 312, DOT 407, and DOT 412 cargo tank motor vehicles with a tank design pressure of at least 172 kPa (25 psig) are authorized.
(3)
Portable tanks.
The following requirements apply to portable tanks intended for the transport of Type F organic peroxides or Type F self-reactive substances. DOT 51, 57, IM 101 portable tanks, and UN portable tanks that conform to the requirements of paragraph (g) of this section. Type F organic peroxide or self-reactive substance formulations other than those indicated in the Organic Peroxide Portable Tank Table may be transported in portable tanks if approved by the Associate Administrator. The following conditions also apply:
(i) The portable tank must be designed for a test pressure of at least 0.4 MPa (4 bar).
(ii) The portable tank must be fitted with temperature-sensing devices.
(iii) The portable tank must be fitted with pressure relief devices and emergency-relief devices. Vacuum-relief devices may also be used. Pressure relief devices must operate at pressures determined according to both the properties of the hazardous material and the construction characteristics of the portable tank. Fusible elements are not allowed in the shell.
(iv) The pressure relief devices must consist of reclosing devices fitted to prevent significant build-up within the portable tank of the decomposition products and vapors released at a temperature of 50 °C (122 °F). The capacity and start-to-discharge pressure of the relief devices must be in accordance with the applicable requirements of this subchapter specified for the portable tank. The pressure relief devices must not allow liquid to escape in the event the portable tank is overturned in a loaded condition.
(v)(A) The emergency-relief devices may be of the reclosing or frangible types, or a combination of the two, designed to vent all the decomposition products and vapors evolved during a period of not less than one hour of complete fire engulfment as calculated by the following formula:
Where:
q = heat absorption (W)
A = wetted area (m2
)
F = insulation factor (−)
(B) Insulation factor (F) in the formula in paragraph (h)(3)(v)(A) of this section equals 1 for non-insulated vessels and for insulated vessels F is calculated using the following formula:
Where:
U = K/L = heat transfer coefficient of the insulation (W·m−2
); K−1
); where K = heat conductivity of insulation layer (W·m−1
);K−1
), and L = thickness of insulation layer (m).
TPO
= temperature of material at relieving conditions (K).
(vi) The start-to-discharge pressure of emergency-relief devices must be higher than that specified for the pressure relief devices in paragraph (h)(3)(iv) of this section. The emergency-relief devices must be sized and designed in such a way that the maximum pressure in the shell never exceeds the test pressure of the portable tank.
Note to Paragraph (h)(3)(vi):
An example of a method to determine the size of emergency-relief devices is given in Appendix 5 of the UN Manual of Tests and Criteria (IBR, see § 171.7 of this subchapter). A second example of a test method for venting sizing is given in the American Institute of Chemical Engineers Process Safety Progress Journal, June 2002 issue (Vol. 21, No. 2).
(vii) For insulated portable tanks, the capacity and setting of emergency-relief devices must be determined assuming a loss of insulation from 1% of the surface area.
(viii) Vacuum-relief devices and reclosing devices on portable tanks used for flammable hazardous materials must be provided with flame arresters. Any reduction of the relief capacity caused by the flame arrester must be taken into account and the appropriate relief capacity must be provided.
(ix) Service equipment such as devices and external piping must be designed and constructed so that no hazardous material remains in them after filling the portable tank.
(x) Portable tanks may be either insulated or protected by a sun-shield. If the SADT of the hazardous material in the portable tank is 55 °C (131 °F) or less, the portable tank must be completely insulated. The outer surface must be finished in white or bright metal.
(xi) The degree of filling must not exceed 90% at 15 °C (59 °F).
(xii) DOT 57 metal portable tanks are authorized only for tert-butyl cumyl peroxide, di-(2-tert-butylperoxyisopropyl-benzene(s)), dicumyl peroxide and mixtures of two or more of these peroxides. DOT 57 portable tanks must conform to the venting requirements of paragraph (f) of this section. These portable tanks are not subject to the requirements of paragraphs (h)(3)(ii) and (h)(3)(iv) of this section. These portable tanks are not subject to any other requirements of paragraph (h) of this section.
(4) For tertiary butyl hydroperoxide (TBHP), each tank car, cargo tank or portable tank must contain 7.6 cm (3.0 inches) low density polyethylene (PE) saddles having a melt index of at least 0.2 grams per 10 minutes (for example see, ASTM D1238, condition E) as part of the lading, with a ratio of PE to TBHP over a range of 0.008 to 0.012 by mass. Alternatively, plastic or metal containers equipped with fusible plugs having a melting point between 69 °C (156 °F) and 71 °C (160 °F) and filled with a sufficient quantity of water to dilute the TBHP to 65% or less by mass may be used. The PE saddles must be visually inspected after each trip and, at a minimum, once every 12 months, and replaced when discoloration, fracture, severe deformation, or other indication of change is noted.
43. Section 173.226 is revised to read as follows:
Materials poisonous by inhalation, Division 6.1, Packing Group I, Hazard Zone A.
Division 6.1, Packing Group I, Zone A poisonous by inhalation (see § 173.133) must be packed in non-bulk packagings in accordance with the following paragraphs:
(a) In seamless specification cylinders conforming to the requirements of § 173.40.
(b) In 1A1, 1B1, 1H1, 1N1, or 6HA1 drums further packed in a 1A2 or 1H2 drum. Both inner and outer drums must conform to the performance test requirements of subpart M of part 178 of this subchapter at the Packing Group I performance level. The outer drums may be tested either as a package
( printed page 34845)
intended to contain inner packagings (combination package) or as a single packaging intended to contain solids or liquids at a mass corresponding to the mass of the assembled packaging system. All outer drums, even those tested to contain inner packaging or as single packagings for solids, must withstand a hydrostatic test pressure of 100 kPa (15 psig). The outer drum must have a minimum thickness of 1.35 mm (0.053 inch) for a 1A2 outer drum or 6.3 mm (0.248 inch) for a 1H2 outer drum. In addition, the inner drum must—
(1) Be capable of satisfactorily withstanding the hydrostatic pressure test in § 178.605 of this subchapter at a test pressure of 300 kPa (45 psig);
(2) Satisfactorily withstand the leakproofness test in § 178.604 of this subchapter using an internal air pressure of at least twice the vapor pressure at 55 °C (131 °F) of the material to be packaged;
(3) Have screw-type closures that are—
(i) Closed and tightened to a torque prescribed by the closure manufacturer, using a properly calibrated device that is capable of measuring torque;
(ii) Physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transportation; and
(iii) Provided with a cap seal that is properly applied in accordance with the cap seal manufacturer's recommendations and is capable of withstanding an internal pressure of at least 100 kPa (15 psig).
(4) Have a minimum thickness as follows:
(i) For a 1A1 or 1N1 drum, 1.3 mm (0.051 inch);
(ii) For a 1B1 drum, 3.9 mm (0.154 inch);
(iii) For a 1H1 drum, 3.16 mm (0.124 inch); and
(iv) For a 6HA1 drum, the plastic inner container shall be 1.58 mm (0.0622 inch) and the outer steel drum shall be 0.96 mm (0.0378 inch).
(5) Be isolated from the outer drum by a shock-mitigating, non-reactive material, which completely surrounds the inner packaging on all sides.
(c) In combination packagings, consisting of an inner packaging system and an outer packaging, as follows:
(1) Outer packagings:
Steel drum: 1A2
Aluminum drum: 1B2
Metal drum, other than steel or aluminum: 1N2
Plywood drum: 1D
Fiber drum: 1G
Plastic drum: 1H2
Steel box: 4A
Aluminum box: 4B
Natural wood box: 4C1 or 4C2
Plywood box: 4D
Reconstituted wood box: 4F
Fiberboard box: 4G
Expanded plastic box: 4H2
Solid plastic box: 4H2
(2) Inner packaging system. The inner packaging system consists of two packagings:
(i) an impact-resistant receptacle of glass, earthenware, plastic or metal securely cushioned with a non-reactive, absorbent material, and
(A) Capacity of each inner receptacle may not exceed 4 L (1 gallon).
(B) An inner receptacle that has a closure must have a closure which is physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transportation.
(ii) Packed within a leak-tight packaging of metal or plastic.
(iii) This combination packaging in turn is packed within the outer packaging.
(A) The total amount of liquid contained in the outer packaging may not exceed 16 L (4 gallons).
(iv) the inner packaging system must conform to the performance test requirements of subpart M of part 178 of this subchapter, at the Packaging Group I performance level when subjected to the following tests:
(A) 178.603—Drop Test
(B) 178.604—Leakproofness Test
(C) 178.605—Hydrostatic Pressure Test
(v) The inner packaging system must meet the above tests without the benefit of the outer packaging.
(vi) The leakproofness and hydrostatic pressure test may be conducted on either the inner receptacle or the outer packaging of the inner packaging system.
(vii) In addition to the requirements in 173.226(b), the outer package must conform to the performance test requirements of subpart M of part 178 of this subchapter, at the Packaging Group I performance level as applicable for the type of package being used.
(d) If approved by the Associate Administrator, 1A1, 1B1, 1H1, 1N1, 6HA1 or 6HH1 drums described in paragraph (b) of this section may be used without being further packed in a 1A2 or 1H2 drum if the shipper loads the material, palletizes the drums, blocks and braces the drums within the transport vehicle and seals the transport vehicle used. Drums may not be stacked (double decked) within the transport vehicle. Shipments must be from one origin to one destination only without any intermediate pickup or delivery.
(e) Prior to reuse, all authorized inner drums must be leakproofness tested and marked in accordance with 173.28 using a minimum test pressure as indicated in paragraph (b)(2) of this section.
44. Section 173.227 is revised to read as follows:
Materials poisonous by inhalation. Division 6.1, Packing Group I, Hazard Zone B.
(a) In packagings as authorized in § 173.226 and seamless and welded specification cylinders conforming to the requirements of § 173.40.
(b) 1A1, 1B1, 1N1 or 1H1 drum or 6HA1 composite further packed in a 1A2 or 1H2 drum. Both the inner and outer drums must conform to the performance test requirements of subpart M of part 178 of this subchapter at the Packing Group I performance level. The outer drum must have a minimum thickness of 1.35 mm (0.053 inches) for a 1A2 outer drum or 6.30 mm (0.248 inches) for a 1H2 outer drum. Outer 1A2 and 1H2 drums must withstand a hydrostatic test pressure of 100 kPa (15 psig). Capacity of the inner drum may not exceed 220 liters. In addition, the inner drum must conform to all of the following requirements:
(1) Satisfactorily withstand the leakproofness test in § 178.604 of this subchapter using an internal air pressure of at least two times the vapor pressure at 55 °C (131 °F) of the material to be packaged.
(2) Have screw closures that are—
(i) Closed and tightened to a torque prescribed by the closure manufacturer, using a properly calibrated device that is capable of measuring torque;
(ii) Physically held in place by any means capable of preventing back-off or loosening of the closure by impact or vibration during transportation; and
(iii) Provided with a cap seal that is properly applied in accordance with the cap seal manufacturer's recommendations and is capable of withstanding an internal pressure of at least 100 kPa (15 psig).
(3) Have a minimum thickness as follows:
(i) For a 1A1 drum, 0.69 mm (0.027 inch);
(ii) For a 1B1 drum, 2.79 mm (0.110 inch);
(iii) For a 1H1 drum, 1.14 mm (0.045 inch); or
(iv) For a 6HA1 drum, the plastic inner container shall be 1.58 mm (0.0625 inch), the outer steel drum shall be 0.70 mm (0.027 inch).
(4) Be isolated from the outer drum by a shock-mitigating, non-reactive material which completely surrounds the inner packaging on all sides.
( printed page 34846)
(5) Prior to reuse, all authorized inner drums must be leakproofness tested and marked in accordance with 173.28 using a minimum test pressure as indicated in paragraph (b)(1) of this section.
(c) 1A1, 1B1, 1H1, 1N1, 6HA1 or 6HH1 drums described in paragraph (b) of this section may be used without being further packed in a 1A2 or 1H2 drum if the shipper loads the material, blocks and braces the drums within the transport vehicle and seals the transport vehicle used. Drums may not be stacked (double decked) within the transport vehicle. Shipments must be from one origin to one destination only without any intermediate pickup or delivery.
45. In § 173.249, paragraph (c) is revised to read as follows:
(c) UN portable tanks conforming to tank code T22 (see § 172.102 of this subchapter) or specification IM 101 portable tanks conforming with paragraphs (d) through (f) of this section. The total quantity in one tank may not be less than 88% nor more than 92% of the volume of the tank.
* * * * *
46. In § 173.306, paragraphs (i) and (j) are removed and a new paragraph (i) is added to read as follows:
(i)
Aerosols with a capacity of less than 50 ml.
Aerosols, as defined in § 171.8 of this subchapter, with a capacity not exceeding 50 ml and with a pressure not exceeding 970 kPa (141 psig) at 55 °C (131 °F), containing no hazardous materials other than a Division 2.2 gas, are not subject to the requirements of this subchapter.
UN Portable Tank Table for Liquefied Compressed Gases.
The UN Portable Tank Table for Liquefied Compressed Gases is referenced in § 172.102(c)(7)(iii) of this subchapter for portable tanks that are used to transport liquefied compressed gases. The table applies to each liquefied compressed gas that is identified with Special Provision T50 in Column (7) of the § 172.101 Table. In addition to providing the UN identification number and proper shipping name, the table provides maximum allowable working pressures, bottom opening requirements, pressure relief device requirements, and degree of filling requirements for liquefied compressed gas permitted for transportation in a T50 portable tank. In the minimum test pressure column, “small” means a portable tank with a diameter of 1.5 meters or less when measured at the widest part of the shell, “sunshield” means a portable tank with a shield covering at least the upper third of the shell, “bare” means no sunshield or insulation is provided, and “insulated” means a complete cladding of sufficient thickness of insulating material necessary to provide a minimum conductance of not more than 0.67 w/m2
/k. In the pressure relief requirements column, the word “Normal” denotes that a frangible disc as specified in § 178.276(e)(3) of this subchapter is not required.
UN Portable Tank Table for Liquefied Compressed Gases
1-Chloro-1,2,2,2-tetrafluoroethane
or
Refrigerant gas R 124
10.3, 9.8, 7.9, 7.0
Allowed
Normal
1.2
1027
Cyclopropane
18.0, 16.0, 14.5, 13.0
Allowed
Normal
0.53
1028
Dichlorodifluoromethane
or
Refrigerant gas R 12
16.0, 15.0, 13.0, 11.5
Allowed
Normal
1.15
1029
Dichlorofluoromethane
or
Refrigerant gas R 21
7.0, 7.0, 7.0, 7.0
Allowed
Normal
1.23
1030
1,1-Difluoroethane
or
Refrigerant gas R 152a
16.0, 14.0, 12.4, 11.0
Allowed
Normal
0.79
1032
Dimethylamine, anhydrous
7.0, 7.0, 7.0, 7.0
Allowed
Normal
0.59
1033
Dimethyl ether
15.5, 13.8, 12.0, 10.6
Allowed
Normal
0.58
1036
Ethylamine
7.0, 7.0, 7.0, 7.0
Allowed
Normal
0.61
1037
Ethyl chloride
7.0, 7.0, 7.0, 7.0
Allowed
Normal
0.8
1040
Ethylene oxide
with nitrogen up to a total pressure of 1MPa (10 bar) at 50 °C
Only authorized in 10 bar insulated portable tanks—
Not Allowed
§ 178.276(e)(3)
0.78
1041
Ethylene oxide and carbon dioxide mixture
with more than 9% but not more than 87% ethylene oxide
See
MAWP definition in § 178.276(a)
Allowed
Normal
See
§ 173.32(f)
1055
Isobutylene
8.1, 7.0, 7.0. 7.0
Allowed
Normal
0.52
1060
Methyl acetylene and propadiene mixture, stabilized
28.0, 24.5, 22.0, 20.0
Allowed
Normal
0.43
1061
Methylamine, anhydrous
10.8, 9.6, 7.8, 7.0
Allowed
Normal
0.58
( printed page 34847)
1062
Methyl bromide
7.0, 7.0, 7.0, 7.0
Not Allowed
§ 178.276(e)(3)
1.51
1063
Methyl chloride
or
Refrigerant gas R 40
14.5, 12.7, 11.3, 10.0
Allowed
Normal
0.81
1064
Methyl mercaptan
7.0, 7.0, 7.0, 7.0
Not Allowed
§ 178.276(e)(3)
0.78
1067
Dinitrogen tetroxide
7.0, 7.0, 7.0, 7.0
Not Allowed
§ 178.276(e)(3)
1.3
1075
Petroleum gas, liquefied
See
MAWP definition in § 178.276(a)
Allowed
Normal
See
§ 173.32(f)
1077
Propylene
28.0, 24.5, 22.0, 20.0
Allowed
Normal
0.43
1078
Refrigerant gas, n.o.s
See
MAWP definition in § 178.276(a)
Allowed
Normal
See
§ 173.32(f)
1079
Sulphur dioxide
11.6, 10.3, 8.5, 7.6
Not Allowed
§ 178.276(e)(3)
1.23
1082
Trifluorochloroethylene, stabilized
or
Refrigerant gas R 1113
17.0, 15.0, 13.1, 11.6
Not Allowed
§ 178.276(e)(3)
1.13
1083
Trimethylamine, anhydrous
7.0, 7.0, 7.0, 7.0
Allowed
Normal
0.56
1085
Vinyl bromide, stabilized
7.0, 7.0, 7.0, 7.0
Allowed
Normal
1.37
1086
Vinyl chloride, stabilized
10.6, 9.3, 8.0, 7.0
Allowed
Normal
0.81
1087
Vinyl methyl ether, stabilized
7.0, 7.0, 7.0, 7.0
Allowed
Normal
0.67
1581
Chloropicrin and methyl bromide mixture
7.0, 7.0, 7.0, 7.0
Not Allowed
§ 178.276(e)(3)
1.51
1582
Chloropicrin and methyl chloride mixture
19.2, 16.9, 15.1, 13.1
Not Allowed
§ 178.276(e)(3)
0.81
1858
Hexafluoropropylene compressed
or
Refrigerant gas R 1216
19.2, 16.9, 15.1, 13.1
Allowed
Normal
1.11
1912
Methyl chloride and methylene cloride mixture
15.2, 13.0, 11.6, 10.1
Allowed
Normal
0.811954
NA 1954
Insecticide gases,
flammable,
n.o.s.
See
MAWP definition in § 178.276(a)
Allowed
Normal
§ 173.32(f)
1958
1, 2-Dichloro-1, 1, 2,2-tetrafluoroethane
or
Refrigerant
7.0, 7.0, 7.0, 7.0
Allowed
Normal
1.3
1965
Hydrocarbon gas, mixture liquefied, n.o.s
See
MAWP definition in § 178.276(a)
Allowed
Normal
See
§ 173.32(f)
1969
Isobutane
8.5, 7.5, 7.0, 7.0
Allowed
Normal
0.49
1973
Chlorodifluoromethane and chloropentafluoroethane mixture
with fixed boiling point, with approximately 49% chlorodifluoromethane or
Refrigerant gas R 502
28.3, 25.3, 22.8, 20.3
Allowed
Normal
1.05
1974
Chlorodifluorobromomethane
or
Refrigerant gas R 12B1
7.4, 7.0, 7.0, 7.0
Allowed
Normal
1.61
1976
Octafluorocyclobutane
or
Refrigerant gas RC 318
8.8, 7.8, 7.0, 7.0
Allowed
Normal
1.34
1978
Propane
22.5, 20.4, 18.0, 16.5
Allowed
Normal
0.42
1983
1-Chloro-2, 2, 2-trifluoroethane
or
Refrigerant gas R 133a
7.0, 7.0, 7.0, 7.0
Allowed
Normal
1.18
2035
1, 1, 1-Trifluoroethane compressed
or
Refrigerant gas R 143a
31.0, 27.5, 24.2, 21.8
Allowed
Normal
0.76
2424
Octafluoropropane
or
Refrigerant gas R 218
23.1, 20.8, 18.6, 16.6
Allowed
Normal
1.07
2517
1-Chloro-1, 1-difluoroethane
or
Refrigerant gas R 142b
8.9, 7.8, 7.0, 7.0
Allowed
Normal
0.99
2602
Dichlorodifluoromethane and difluoroethane azeotropic mixture
with approximately 74% dichlorodifluoromethane or
Refrigerant gas R 500
20.0, 18.0, 16.0, 14.5
Allowed
Normal
1.01
3057
Trifluoroacetyl chloride
14.6, 12.9, 11.3, 9.9
Not Allowed
§ 178.276(e)(3)
1.17
3070
Ethylene oxide and dichlorodifluoromethane mixture
with not more than 12.5% ethylene oxide
14.0, 12.0, 11.0, 9.0
Allowed
§ 178.276(e)(3)
1.09
3153
Pefluoro (methyl vinyl ether)
14.3, 13.4, 11.2, 10.2
Allowed
Normal
1.14
3159
1,1,1, 2-Tetrafluoroethane
or
Refrigerant gas R 134a
17.7, 15.7, 13.8, 12.1
Allowed
Normal
1.04
3161
Liquefied gas, flammable, n.o.s.
See MAWP definition in § 178.276(a)
Allowed
Normal
§ 173.32(f)
3163
Liquefied gas, n.o.s
See MAWP definition in § 178.276(a)
Allowed
Normal
§ 173.32(f)
3220
Pentafluoroethane
or
Refrigerant
34.4, 30.8, 27.5, 24.5
Allowed
Normal
0.95
( printed page 34848)
3252
Difluoromethane
or
Refrigerant gas R 32
43.0, 39.0, 34.4, 30.5
Allowed
Normal
0.78
3296
Heptafluoropropane
or
Refrigerant gas R 227
16.0, 14.0, 12.5, 11.0
Allowed
Normal
1.2
3297
Ethylene oxide and chlorotetrafluoroethane mixture,
with not more than 8.8% ethylene oxide
8.1, 7.0, 7.0, 7.0
Allowed
Normal
1.16
3298
Ethylene oxide and pentafluoroethane mixture,
with not more than 7.9% ethylene oxide
25.9, 23.4, 20.9, 18.6
Allowed
Normal
1.02
3299
Ethylene oxide and tetrafluoroethane mixture,
with not more than 5.6% ethylene oxide
16.7, 14.7, 12.9, 11.2
Allowed
Normal
1.03
3318
Ammonia solution,
relative density less than 0.880 at 15 °C in water, with more than 50% ammonia
See
MAWP definition in 178.276(a)
Allowed
§ 178.276(e)(3)
173.32(f)
3337
Refrigerant gas R 404A
31.6, 28.3, 25.3, 22.5
Allowed
Normal
0.84
3338
Refrigerant gas R 407A
31.3, 28.1, 25.1, 22.4
Allowed
Normal
0.95
3339
Refrigerant gas R 4078
33.0, 29.6, 26.5, 23.6
Allowed
Normal
0.95
3340
Refrigerant gas R 407C
29.9, 26.8, 23.9, 21.3
Allowed
Normal
0.95
49. In § 173.315, paragraph (a) introductory text is revised to read as follows:
Compressed gases in cargo tanks and portable tanks.
(a) Liquefied compressed gases that are transported in UN portable tanks must be loaded and offered for transportation in accordance with the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313. A liquefied compressed gas offered for transportation in a cargo tank motor vehicle or a portable tank must be prepared in accordance with this section, §§ 173.32 and 173.33 and subpart E or subpart G of part 180 of this subchapter, as applicable. For cryogenic liquids, see § 173.318. For marking requirements, see §§ 172.326 and 172.328 of this subchapter. Except for UN portable tanks, a liquefied compressed gas must be loaded and offered for transportation in accordance with the following table:
* * * * *
50. In § 173.323, paragraph (b) is revised to read as follows:
(b) Ethylene oxide must be packaged in one of the following:
(1) In hermetically sealed glass or metal inner packagings suitably cushioned in an outer package authorized by § 173.201(b). The maximum quantity permitted in any glass inner packaging is 100 g (3.5 ounces), and the maximum quantity permitted in any metal inner packaging is 340 g (12 ounces). After filling, each inner packaging shall be determined to be leak-tight by placing the inner packaging in a hot water bath at a temperature, and for a period of time, sufficient to ensure that an internal pressure equal to the vapour pressure of ethylene oxide at 55 °C is achieved. The total quantity in any outer packaging shall not exceed 2.5 kg. Each completed package must be capable of passing all Packing Group I performance tests.
(2) In specification cylinders, as authorized for any compressed gas except acetylene. Pressurizing valves and insulation are required for cylinders over 4 L (1 gallon) capacity. Eductor tubes must be provided for cylinders over 19 L (5 gallons) capacity. Cylinders must be seamless or welded steel (not brazed) with a nominal capacity of no more than 115 L (30 gallons) and may not be liquid full below 82 °C (180 °F). Before each refilling, each cylinder must be tested for leakage at no less than 103.4 kPa (15 psig) pressure. In addition, each cylinder must be equipped with a fusible type relief device with yield temperature of 69 °C to 77 °C (157 °F to 170 °F). The capacity of the relief device and the effectiveness of the insulation must be such that the charged cylinder will not explode when tested by the method described in CGA Pamphlet C-14 or other equivalent method.
(3) In 1A1 steel drums of no more than 231 L (61 gallons) and meeting Packing Group I performance standards. The drum must be lagged of all welded construction with the inner shell having a minimum thickness of 1.7 mm (0.068 inches) and the outer shell having a minimum thickness of 2.4 mm (0.095 inches). Drums must be capable of withstanding a hydrostatic test pressure of 690 kPa (100 psig). Lagging must be of sufficient thickness so that the drum, when filled with ethylene oxide and equipped with the required pressure relief device, will not rupture when exposed to fire. The drum may not be liquid full below 85 °C (185 °F), and must be marked “THIS END UP” on the top head. Before each refilling, each drum must be tested for leakage at no less than 103 kPa (15 psig) pressure. Each drum must be equipped with a fusible type relief device with yield temperature of 69 °C to 77 °C (157 °F to 170 °F), and the capacity of the relief device must be such that the filled drum is capable of passing, without rupture, the test method described in CGA Pamphlet C-14 or other equivalent method.
* * * * *
PART 175—CARRIAGE BY AIRCRAFT
51. The authority citation for part 175 continues to read as follows:
Authority:49 U.S.C. 5101-5127; 49 CFR 1.53.
( printed page 34849)
52. In § 175.10, paragraphs (a)(4)(i), (a)(4)(iii), and (a)(18) are revised to read as follows:
(i) Non-radioactive medicinal and toilet articles (including aerosols) may be carried in checked or carry-on baggage. Release devices on aerosols must be protected by a cap or other suitable means to prevent inadvertent release;
* * * * *
(iii) Other aerosols in Division 2.2 with no subsidiary risk may be carried in checked baggage only. Release devices on aerosols must be protected by a cap or other suitable means to prevent inadvertent release;
* * * * *
(18) Compressed gas cylinders of Division 2.2 worn by passengers for the operation of mechanical limbs and spare cylinders of a similar size for the same purpose in sufficient quantities to ensure an adequate supply for the duration of the journey.
* * * * *
53. Section 175.85 is revised by adding new paragraph (j) to read as follows:
(j) A package bearing a KEEP AWAY FROM HEAT handling marking must be protected from direct sunshine and stored in a cool and ventilated place, away from sources of heat.
PART 176—CARRIAGE BY VESSEL
54. The authority citation for part 176 continues to read as follows:
Authority:49 U.S.C. 5101-5127; 49 CFR 1.53. 55. In § 176.2, the following revisions are made: a. The definitions for “Explosive article”, “Explosive substance” and “Magazine” are revised. b. The term “Transport unit” is revised to read “Cargo transport unit”. c. In the definition “In containers or the like”, the term “transport unit” is removed and the term “cargo transport unit” is added in its place. The revisions and additions read as follows:
* * * * *
Cargo transport unit
means a transport vehicle, a freight container or a portable tank. A
closed cargo transport unit
means a cargo transport unit in which the contents are totally enclosed by permanent structures. An
open cargo transport unit
means a cargo transport unit that is not a closed cargo transport unit. Cargo transport units with fabric sides or tops are not closed cargo transport units for the purposes of this part.
* * * * *
Explosive article
means an article or device which contains one or more explosive substances. Individual explosive substances are identified in column 17 of the Dangerous Goods List in the IMDG Code.
* * * * *
Explosive substance
means a solid or liquid material, or a mixture of materials, which is in itself capable by chemical reaction of producing gas at such a temperature and pressure and at such a speed as to cause damage to its surroundings. Individual explosive substances are identified in column 17 of the Dangerous Goods List in the IMDG Code.
* * * * *
In containers or the like
means in any clean, substantial, weatherproof box structure which can be secured to the vessel's structure, including a portable magazine or a closed cargo transport unit. Whenever this stowage is specified, stowage in deckhouses, mast lockers and oversized weatherproof packages (overpacks) is also acceptable.
* * * * *
Magazine
means an enclosure designed to protect certain goods of Class 1 (explosive) materials from damage by other cargo and adverse weather conditions during loading, unloading, and when in transit; and to prevent unauthorized access. A magazine may be a fixed structure or compartment in the vessel, a closed freight container, a closed transport vehicle, or a portable magazine. Magazines may be positioned in any part of the ship conforming with the relevant provisions for Class 1 (explosive) materials contained in Subpart G of this part provided that magazines which are fixed structures are sited so that their doors, where fitted, are easily accessible.
(a) A carrier may not transport a hazardous material by vessel unless a certificate prepared in accordance with § 172.204 of this subchapter has been received.
(b) In the case of an import or export shipment of hazardous materials that will not be transported by rail, highway, or air, the shipper may certify on the bill of lading or other shipping paper that the hazardous material is properly classed, described, marked, packaged, and labeled according to part 172 of this subchapter or in accordance with the requirements of the IMDG Code (IBR,
see
§ 171.7 of this subchapter).
See
§ 171.12 of this subchapter.
(c)(1) A person responsible for packing or loading a freight container or transport vehicle with packages of hazardous materials for transportation by a manned vessel in ocean or coastwise service, must provide the vessel operator, at the time the shipment is offered for transportation by vessel, with a signed container packing certificate stating, at a minimum, that—
(i) The freight container or transport vehicle is serviceable for the materials loaded therein, contains no incompatible goods, and is properly marked, labeled or placarded, as applicable; and
(ii) When the freight container or transport vehicle contains packages, those packages have been inspected prior to loading, are properly marked, labeled or placarded, as applicable; are not damaged; and are properly secured.
(2) The certification may appear on a shipping paper or on a separate document as a statement, such as “It is declared that the packing of the container has been carried out in accordance with the applicable provisions [of 49 CFR], [of the IMDG Code], or [of 49 CFR and the IMDG Code].”
57. In § 176.63, paragraph (e) is revised to read as follows:
(e)
Closed cargo transport unit,
for the purpose of stowage of Class 1 (explosive) materials on board a vessel, means a unit which fully encloses the contents by permanent structures and can be secured to the ship's structure, and includes a magazine. Cargo transport units with fabric sides or tops are not closed cargo transport units. Where this stowage is specified, stowage in small compartments such as deck-houses and mast lockers are acceptable alternatives. The floor of any closed cargo transport unit or compartment shall either be constructed of wood, close-boarded or so arranged that goods are stowed on sparred gratings, wooden pallets or dunnage. Provided that the necessary additional specifications are met, a closed cargo transport unit may be used for type “A” or “C” class 1 stowage or as a magazine.”
* * * * *
58. In § 176.76, paragraphs (h) and (i) are revised to read as follows:
Transport vehicles, freight containers, and portable tanks containing hazardous materials.
* * * * *
(h) A fumigated cargo transport unit may only be transported on board a vessel subject to the following conditions and limitations:
(1) The fumigated cargo transport unit may be placed on board a vessel only if at least 24 hours have elapsed since the unit was last fumigated;
(2) The fumigated cargo transport unit is accompanied by a document showing the date of fumigation and the type and amount of fumigant used;
(3) Prior to loading, the master is informed of the intended placement of the fumigated cargo transport unit on board the vessel and the information provided on the accompanying document;
(4) Equipment that is capable of detecting the fumigant and instructions for the equipment's use is provided on the vessel;
(5) The fumigated cargo transport unit must be stowed at least 5 m from any opening to accommodation spaces;
(6) Fumigated cargo transport units may only be transported on deck on vessels carrying more than 25 passengers; and
(7) Fumigants may not be added to cargo transport units while on board a vessel.
(i) A cargo transport unit packed or loaded with flammable gas or flammable liquid having a flashpoint below +23 °C transported on deck must be stowed “away from” possible sources of ignition. In the case of container ships, a distance equivalent to one container space athwartships away from possible sources of ignition applied in any direction will satisfy this requirement.
59. In § 176.83:
a. Paragraphs (a)(5), (d), (e), (f)(1), (f)(3), (g)(1), (g)(2), (g)(3) and (l) are revised;
b. The headings to paragraphs (g) and (f) and the title to Table 176.83(g) are revised; and
(5) Whenever hazardous materials are stowed together, whether or not in a cargo transport unit, the segregation of such hazardous materials from others must always be in accordance with the most restrictive requirements for any of the hazardous materials concerned.
* * * * *
(d)
Segregation in cargo transport units:
Two hazardous materials for which any segregation is required may not be stowed in the same cargo transport unit.
(e)
Segregation of hazardous materials stowed as breakbulk cargo from those packed in cargo transport units:
(1) Hazardous materials stowed as breakbulk cargo must be segregated from materials packed in open cargo transport units in accordance with paragraph (c) of this section.
(2) Hazardous materials stowed as breakbulk cargo must be segregated from materials packed in closed cargo transport units in accordance with paragraph (c) of this section, except that:
(i) Where “away from” is required, no segregation between packages and the closed cargo transport units is required; and
(ii) Where “separated from” is required, the segregation between the packages and the closed cargo transport units may be the same as for “away from”.
(f)
Segregation of cargo transport units on board container vessels:
(1) Except for hatchless container ships, this paragraph applies to segregation of cargo transport units that are carried on board container vessels, or on other types of vessels, provided these cargo spaces are properly fitted for permanent stowage of containers during transport.
* * * * *
(3)
Segregation Table:
Table § 176.83(f) sets forth the general requirements for segregation between cargo transport units on board container vessels.
* * * * *
(g)
Segregation of cargo transport units on board trailerships and trainships:
(1) The requirements of this paragraph apply to the segregation of cargo transport units which are carried on board trailerships and trainships or in “roll-on/roll-off” cargo spaces.
(2) For trailerships and trainships which have spaces suitable for breakbulk cargo, containers, or any other method of stowage, the appropriate paragraph of this section applies to the relevant cargo space.
(3)
Segregation Table.
Table § 176.83(g) sets forth the general requirements for segregation between transport units on board trailerships and trainships.
TABLE 176.83(g).—SEGREGATION OF CARGO TRANSPORT UNITS ON BOARD TRAILERSHIPS AND TRAINSHIPS
* * * * *
(l)
Segregation of containers on board hatchless (open-top) container ships:
(1) This paragraph applies to the segregation of cargo transport units that are transported on board hatchless container ships provided that the cargo spaces are properly fitted to give permanent stowage of the cargo transport units during transport.
(2) For container ships that have both hatchless container spaces and other spaces suitable for breakbulk cargo, conventional container stowage, or any other method of stowage, the appropriate requirements of this section apply to the relevant cargo space.
(3)
Segregation Table:
Table § 176.83(l)(3) sets forth the general requirements for segregation of cargo transport units on board hatchless container ships.
(4) In Table § 176.83(l)(3), a container space means a distance of not less than 6 m (20 feet) fore and aft or not less than 2.5 m (8 feet) athwartship.
( printed page 34851)
( printed page 34852)
( printed page 34853)
(m)
Provisions for segregation groups:
(1) For the purpose of segregation, materials having certain similar chemical properties have been grouped together in segregation groups. The segregation groups ( such as “acids”, “chlorates”, “permanganates”) and the entries allocated to each of these groups include the substances identified in section 3.1.4 of the IMDG Code. When column (10B) of the § 172.101 Table refers to a numbered stowage provision set forth in § 176.84(b) such as “Stow “away from” acids”, that particular stowage/segregation requirement applies to all the materials allocated to the respective segregation group.
(2) Not all hazardous materials falling within a segregation group are listed by name in the regulations. These materials are shipped under “n.o.s.” entries. Although these “n.o.s.” entries are not listed themselves in the above groups, the shipper must decide whether allocation under a segregation group is appropriate. Mixtures, solutions or preparations containing hazardous materials falling within a segregation group and shipped under an “n.o.s.” entry are also considered to fall within that segregation group.
(3) The segregation groups described above do not address materials which fall outside the classification criteria of the hazardous materials regulations although it is recognized that some non-hazardous materials have certain chemical properties similar to hazardous materials listed in the segregation groups. A shipper or the person responsible for packing the materials into a cargo transport unit who does have knowledge of the chemical properties of such non-hazardous materials may identify a relevant segregation group and apply the segregation requirements for that segregation group.
60. In § 176.84, paragraph (a) is revised, in paragraph (b), Table of provisions, eleven new entries are added in appropriate numerical order and in paragraph (c)(2), three notes in the Provisions for the stowage of Class 1 (explosive) materials table are revised to read as follows:
Other requirements for stowage and segregation for cargo vessels and passenger vessels.
(a)
General.
When Column 10B of the § 172.101 Table refers to a numbered or alpha-numeric stowage provision for water shipments, the meaning and requirements of that provision are set forth in this section. Terms in quotation marks are defined in § 176.83. Other terms used in the table in this section such as “acids”, “chlorates” and “permanganates” indicate different chemical groups referred to here as segregation groups. Materials falling within a segregation group are considered to have certain similar chemical properties and, although not exhaustive in nature, the materials belonging to each group include those substances identified in section 3.1.4 of the IMDG Code as set forth in § 176.83(m).
(b) * * *
Code
Provisions
* * * * *
133
Stow “separated from” sulfur.
134
Stow “separated from” UN2716.
135
Stow “Separated from” mercury and mercury compounds.
136
Stow “Separated from” carbon tetrachloride.
137
For arsenic sulphides, Stow “separated from” acids.
138
Stow “Separated from” peroxides.
139
Stow “Separated from” mercury salts.
140
Stow “Separated from” UN3052 and UN3461.
141
Stow “away from” radioactive materials.
142
Packages in cargo transport units must be stowed so as to allow for adequate air circulation throughout the cargo.
143
Prohibited on any vessel carrying explosives (except explosives in Division 1.4, Compatibility group S).
* * * * *
* * * * *
(c) * * *
(2) * * *
Note
Provision
* * * * *
19E
“Away from” explosives containing chlorates or perchlorates.
* * * * *
22E
“Away from” ammonium compounds and explosives containing ammonium compounds or salts.
23E
“Separated from” Division 1.4 and “separated longitudinally by an intervening complete compartment or hold from” Division 1.1, 1.2, 1.3, 1.5, and 1.6 except from explosives of compatibility group J.
* * * * *
* * * * *
61. In § 176.116, paragraph (c) is revised and a new paragraph (f) is added to read as follows:
General stowage conditions for Class 1 (explosive) materials.
* * * * *
(c)
Security:
All compartments, magazines, and cargo transport units containing Class 1 (explosive) materials must be locked or suitably secured in order to prevent unauthorized access.
* * * * *
(f)
Under deck stowage of Class 1 (explosive) materials allocated stowage categories 09 and 10:
(1) These Class 1 (explosive) materials must not be stowed in the same compartment or hold with other cargo that is readily combustible (such as items packaged in straw).
(2) The position of stowage of these Class 1 (explosive) materials must be such as to maintain direct access to the hatchway by not overstowing with other cargo except for other Class 1 (explosive) materials.
(3) In all cases, all cargo within the compartment or hold, including Class 1 (explosive) materials stowed in cargo transport units, must be secured so as to eliminate the possibility of significant movement. Where an entire deck is used as a magazine, the stowage must be so arranged that the Class 1 (explosive) materials stowed therein must be removed from the ship before working any cargo in any decks above or below the space in the same hold.
Magazine stowage types “A”, “C” and Special Stowage.
(a) The stowage arrangements of Class 1 (explosive) substances and certain articles are subject to varying levels of containment, (except for compatibility group S substances), when stowed below deck. The levels are dependent on the hazard presented and the nature of the particular explosives involved. Columns (10A) and (10B) of the Hazardous Materials Table specify the stowage applicable to each substance or article. The different levels of containment are defined below as “A”, “C” and “Special”.
(b)
Magazine stowage type “A”.
Magazine stowage type A is required for those substances that must be kept clear of steelwork.
(c)
Magazine stowage type “C”.
Magazine stowage type C is required for those substances in compatibility group A.
(d)
Special Stowage.
Special Stowage is required for Explosive substances,
( printed page 34854)
n.o.s. in compatibility groups G or L, and for articles in compatibility groups G, H, L and K, which are particularly hazardous.
The construction requirements for magazine stowage type C are the same as for a closed cargo transport unit in § 176.63(e). In addition, the magazine must be located as near as practicable to the centerline of the vessel and must not be closer to the vessel's side than a distance equal to one-eighth of the vessel's beam or 2.4 m (8 feet), whichever is less.
67. Section 176.136 is revised to read as follows:
(a) Special stowage is required for certain articles presenting both explosive and chemical hazards, such as smoke or lachrymatory (compatibility group G or H), toxic (compatibility group K), or substances and articles which present a special risk (compatibility group L). Except as permitted in paragraph (c) of this section, Class 1 (explosive) materials requiring special stowage must be stowed on deck unless such stowage is impracticable and the COTP authorizes special stowage below deck. Where on deck stowage is recommended and an alternative stowage below deck is permitted by the COTP, the stowage must always be subject to special stowage.
(b) Class 1 (explosive) materials for which special stowage is required must be stowed as far away as practicable from living, accommodation, and working areas, and may not be overstowed. Closed cargo transport units in which such Class 1 (explosive) materials are stowed may not be located closer to the vessel's side than a distance equal to one-eighth of the vessel's beam or 2.4 m (8 feet), whichever is less.
(c) Class 1 (explosive) materials in compatibility groups G and H may be transported in steel magazines or in freight containers. If a freight container is used for this purpose, the floor of the freight container must be leakproof; for example, an all-metal container may be used and a fillet of cement or other material worked across the bottom of the door opening.
(d) Class 1 (explosive) materials stowed in one compartment may not be of more than one compatibility group, except the COTP may allow Class 1 (explosive) materials of compatibility groups G and H in separate steel magazines to be stowed in the same compartment, not less than 3 m (10 feet) apart.
(e) Class 1 (explosive) materials in compatibility groups K and L must be stowed in a steel magazine regardless of the stowage position in the vessel.
68. In § 176.138, paragraph (a) is revised to read as follows:
(a) Except as allowed by paragraph (b) of this section, certain hazardous materials of extreme flammability may not be transported in a vessel carrying Class 1 (explosive) materials. This prohibition applies to the following liquid hazardous materials:
(a) Except as provided in § 176.145 of this subchapter, stowage of Class 1 (explosive) materials within the same compartment, magazine, or cargo transport unit is subject to provisions contained in table 176.144(a).
Table 176.144(a).—Authorized Mixed Stowage for Explosives
[An “X” indicates that explosives in the two different compatibility groups reflected by the location of the “X” may not be stowed in the same compartment, magazine, or cargo transport unit]
Compatibility groups
A
B
C
D
E
F
G
H
J
K
L
N
S
A
X
X
X
X
X
X
X
X
X
X
X
X
B
X
X
X
X
X
X
X
X
X
X
X
C
X
X
X
1
X
X
X
X
D
X
X
X
1
X
X
X
X
E
X
X
X
1
X
X
X
X
F
X
X
X
X
X
X
X
X
X
X
X
G
X
X
1
1
1
X
X
X
X
X
X
H
X
X
X
X
X
X
X
X
X
X
X
J
X
X
X
X
X
X
X
X
X
X
X
K
X
X
X
X
X
X
X
X
X
X
X
L
X
X
X
X
X
X
X
X
X
X
2
X
X
N
X
X
X
X
X
X
X
X
X
( printed page 34855)
S
X
X
Notes:
1. Explosive articles in compatibility group G, other than fireworks and those requiring special stowage, may be stowed with articles of compatibility groups C, D, and E, provided no explosive substances are carried in the same compartment, magazine or cargo transport unit.
2. Explosives in compatibility group L may only be stowed in the same compartment, magazine or cargo transport unit with identical explosives within compatibility group L.
3. Different types of articles of Division 1.6, compatibility group N, may only be transported together when it is proven that there is no additional risk of sympathetic detonation between the articles. Otherwise they must be treated as division 1.1.
4. When articles of compatibility group N are transported with articles or substances of compatibility groups C, D or E, the goods of compatibility group N must be treated as compatibility group D.
5. When articles of compatibility group N are transported together with articles or substances of compatibility group S, the entire load must be treated as compatibility group N.
6. Any combination of articles in compatibility groups C, D and E must be treated as compatibility group E. Any combination of substances in compatibility groups C and D must be treated as the most appropriate compatibility group shown in Table 2 of § 173.52 taking into account the predominant characteristics of the combined load. This overall classification code must be displayed on any label or placard on a unit load or cargo transport unit as prescribed in subpart E (Labeling) and subpart F (Placarding).
(b) Where Class 1 (explosive) materials of different compatibility groups are allowed to be stowed in the same compartment, magazine, or cargo transport unit, the stowage arrangements must conform to the most stringent requirements for the entire load.
(c) Where a mixed load of Class 1 (explosive) materials of different hazard divisions and/or stowage arrangements is carried within a compartment, magazine, or cargo transport unit, the entire load must be treated as belonging to the hazard division having the greatest hazard. (For example, if a load of Division 1.1 (explosive) materials is mixed with Division 1.3 (explosive) materials, the load is treated as a Division 1.1 (explosive) material as defined in § 173.50(b) of this subchapter and the stowage must conform to the most stringent requirements for the entire load).
* * * * *
(e) Segregation on deck: When Class 1 (explosive) materials in different compatibility groups are carried on deck, they must be stored not less than 6 m (20 feet) apart unless they are allowed under Table 176.144(a) to be stowed in the same compartment, magazine, or cargo transport unit.
* * * * *
71. In § 176.146, paragraph (d)(1) is revised to read as follows:
(1) An explosive substance or article which has a secondary POISON hazard label must be stowed “separated from” all foodstuffs, except when such materials are stowed in separate closed cargo transport units, the requirements for “away from” segregation apply.
Transport of Class 1 (explosive) materials in freight containers.
* * * * *
(b) Freight containers loaded with Class 1 (explosive) materials, except for explosives in Division 1.4, must not be stowed in the outermost row of containers.
* * * * *
74. In § 176.174, paragraphs (a) and (b) are revised to read as follows:
Transport of Class 1 (explosive) materials in shipborne barges.
(a) Fixed magazines may be built within a shipboard barge. Freight containers may be used as magazines within a barge.
(b) Shipborne barges may be used for the carriage of all types of Class 1 (explosive) materials. When carrying Class 1 (explosive) materials requiring special stowage, the following requirements apply:
(1) Class 1 (explosive) materials in compatibility group G or H must be stowed in freight containers.
(2) Class 1 (explosive) materials in compatibility group K or L must be stowed in steel magazines.
75. In § 176.600, in paragraph (a), in the last sentence, the wording “closed transport units” is removed and the wording “closed cargo transport units” is added in its place.
PART 178—SPECIFICATIONS FOR PACKAGINGS
76. The authority citation for part 178 continues to read as follows:
(v) The rated flow capacity of the spring loaded pressure relief devices, frangible disc or fusible elements in standard cubic meters of air per second (m3
/s). For spring loaded pressure relief device the rated flow capacity shall be determined according to ISO 4126-1 (IBR,
see
§ 171.1 of this subchapter); and
* * * * *
78. In § 178.275, paragraph (i)(2) is revised to read as follows:
Specification for UN Portable Tanks intended for the transportation of liquid and solid hazardous materials.
* * * * *
(i) * * *
(2) The combined delivery capacity of the pressure relief system (taking into account the reduction of the flow when the portable tank is fitted with frangible-discs preceding spring-loaded pressure-relief devices or when the spring-loaded pressure-relief devices are provided with a device to prevent the passage of the flame), in condition of complete fire engulfment of the portable tank must be sufficient to limit the pressure in the shell to 20% above the start to discharge pressure limiting device (pressure relief device). The total required capacity of
( printed page 34856)
the relief devices may be determined using the formula in paragraph (i)(2)(i)(A) of this section or the table in paragraph (i)(2)(iii) of this section.
* * * * *
79. In § 178.276, paragraphs (a)(4)(ii)(A), (d), and (e)(3) are revised to read as follows:
Requirements for the design, construction, inspection and testing of portable tanks intended for the transportation of non-refrigerated liquefied compressed gases.
* * * * *
(a) * * *
(4) * * *
(ii) * * *
(A) Not less than the pressure specified for each liquefied compressed gas listed in the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313; and
* * * * *
(d)
Bottom openings.
Bottom openings are prohibited on portable tanks when the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313 of this subchapter indicates that bottom openings are not allowed. In this case, there may be no openings located below the liquid level of the shell when it is filled to its maximum permissible filling limit.
(e) * * *
(3) A portable tank intended for the transportation of certain liquefied compressed gases identified in the UN Portable Tank Table for Liquefied Compressed Gases in § 173.313 of this subchapter must have a pressure relief device which conforms to the requirements of this subchapter. Unless a portable tank, in dedicated service, is fitted with a relief device constructed of materials compatible with the hazardous material, the relief device must be comprised of a frangible disc preceded by a reclosing device. The space between the frangible disc and the device must be provided with a pressure gauge or a suitable tell-tale indicator. This arrangement must facilitate the detection of disc rupture, pinholing or leakage which could cause a malfunction of the pressure relief device. The frangible disc must rupture at a nominal pressure 10% above the start-to-discharge pressure of the relief device.
* * * * *
80. In § 178.602, paragraph (b) is revised to read as follows:
Preparation of packagings and packages for testing.
* * * * *
(b) For the drop and stacking test, inner and single-unit receptacles other than bags must be filled to not less than 95% of maximum capacity (see § 171.8 of this subchapter) in the case of solids and not less than 98% of maximum in the case of liquids. Bags shall be filled to the maximum mass at which they may be used. The material to be transported in the packagings may be replaced by a non-hazardous material, except for chemical compatibility testing or where this would invalidate the results of the tests.
* * * * *
81. In § 178.603, paragraphs (c)(1) and (e)(2) are revised to read as follows:
(c)
Special preparation of test samples for the drop test.
(1) Testing of plastic drums, plastic jerricans, plastic boxes other than expanded polystyrene boxes, composite packagings (plastic material), and combination packagings with plastic inner packagings other than plastic bags intended to contain solids or articles must be carried out when the temperature of the test sample and its contents has been reduced to -18 °C (0 °F) or lower. Test liquids must be kept in the liquid state, if necessary, by the addition of anti-freeze. Water/anti-freeze solutions with a minimum specific gravity of 0.95 for testing at -18 °C (0 °F) or lower are considered acceptable test liquids. Test samples prepared in this way are not required to be conditioned in accordance with § 178.602(d).
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(e) * * *
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(2) For liquids in single packagings and for inner packagings of combination packagings, if the test is performed with water:
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82. In § 178.810, paragraph (b)(3) is revised to read as follows:
(3) Rigid plastic IBCs and composite IBCs with plastic inner receptacles must be conditioned for testing by reducing the temperature of the packaging and its contents to -18 °C (0 °F) or lower. Test liquids must be kept in the liquid state, if necessary, by the addition of anti-freeze. Water/anti-freeze solutions with a minimum specific gravity of 0.95 for testing at -18 °C (0 °F) or lower are considered acceptable test liquids. IBCs conditioned in this way are not required to be conditioned in accordance with § 178.802.
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PART 180—CONTINUING QUALIFICATION AND MAINTENANCE OF PACKAGINGS
83. The authority citation for part 180 continues to read as follows:
(c) Routine maintenance of IBCs is the routine performance on:
(1) Metal, rigid plastic or composite IBCs of operations such as:
(i) Cleaning;
(ii) Removal and reinstallation or replacement of body closures (including associated gaskets), or of service equipment conforming to the original manufacturer's specifications provided that the leaktightness of the IBC is verified; or
(iii) Restoration of structural equipment not directly performing a hazardous material containment or discharge pressure retention function so as to conform to the design type (for example, the straightening of legs or lifting attachments), provided the containment function of the IBC is not affected.
(2) Plastics or textile flexible IBCs of operations, such as:
(i) Cleaning; or
(ii) Replacement of non-integral components, such as non-integral liners and closure ties, with components conforming to the original manufacturer's specification; provided that these operations do not adversely affect the containment function of the flexible IBC or alter the design type.
85. In § 180.352, paragraph (d)(1)(iv) is revised and a new paragraph (d)(1)(v) is added to read as follow:
(iv) Except for routine maintenance of metal, rigid plastics and composite IBCs performed by the owner of the IBC, whose State and name or authorized symbol is durably marked on the IBC, the party performing the routine maintenance shall durably mark the IBC near the manufacturer's UN design type marking to show the following:
(A) The County in which the routine maintenance was carried out; and
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(B) The name or authorized symbol of the party performing the routine maintenance.
(v) Retests and inspections performed in accordance with paragraphs (d)(1)(i) and (ii) of this section may be used to satisfy the requirements for the 2.5 and five year periodic tests and inspections required by paragraph (b) of this section, as applicable.
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Issued in Washington, DC on May 26, 2004, under authority delegated in 49 CFR part 106.
Frits Wybenga,
Deputy Associate Administrator for Hazardous Materials Safety.